Bicyclo[2.2.1]hept-5-en-2-ylmethyl benzoate | 100976-00-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bicyclo[2.2.1]hept-5-en-2-ylmethyl benzoate
• 英文别名: 2-bicyclo[2.2.1]hept-5-enylmethyl benzoate
• CAS: 100976-00-9
• 化学式: C₁₅H₁₆O₂
• 分子量: 228.291
• InChiKey: IVXACWABDOBWNU-UHFFFAOYSA-N

物化性质

• 沸点：
  126 °C(Press: 3 Torr)
• 密度：
  1.130±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Bicyclo[2.2.1]hept-5-en-2-ylmethyl benzoate 生成 5-降冰片烯-2-甲醇
  参考文献：
  名称：

  GUSEJNOV M. M.; KYAZIMOVA T. G.; BABAEV R. S.; ASLANOVA EH. G., MEHRUZEHLEHR. AZSSR ELMLEHR AKAD., DOKL. AN AZSSR, 1979, 35, HO 10, 45-48

  摘要：

  DOI：
• 作为产物：
  描述：

  5-降冰片烯-2-羧酸甲酯 在 lithium aluminium tetrahydride 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 Bicyclo[2.2.1]hept-5-en-2-ylmethyl benzoate
  参考文献：
  名称：

  Scavenge−ROMP−Filter:  A Facile Strategy for Soluble Scavenging via Norbornenyl Tagging of Electrophilic Reagents

  摘要：

  [GRAPHICS]A new "chemical tagging" method for homogeneous electrophilic scavenging is described. The method utilizes 5-norbornene-2-methanol to scavenge/tag a variety of electrophiles that are present in excess. Once tagging is complete, the crude reaction mixture is subjected to a rapid ROM polymerization event utilizing the second generation Grubbs catalyst. This process yields a polymer that can be precipitated with methanol or ether/hexane, leaving products in excellent yield and purity.

  DOI：

  10.1021/ol0257880

文献信息

• Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
  申请人：——

  公开号：US20020128408A1

  公开（公告）日：2002-09-12

  The present invention relates to a radiation sensitive photoresist composition comprising a photoacid initiator and a polycyclic polymer comprising repeating units that contain pendant acid labile groups. Upon exposure to an imaging radiation source the photoacid initiator generates an acid which cleaves the pendant acid labile groups effecting a polarity change in the polymer. The polymer is rendered soluble in an aqueous base in the areas exposed to the imaging source.

  本发明涉及一种辐射敏感的光阻组合物，包括光酸引发剂和聚环状聚合物，该聚合物包含含有侧链酸敏感基团的重复单元。在暴露于成像辐射源时，光酸引发剂生成酸，该酸会裂解侧链酸敏感基团，从而影响聚合物的极性变化。在成像源暴露的区域，聚合物变得可溶于水性碱。
• CYCLIC OLEFIN POLYMER, OPTICAL MATERIAL, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY
  申请人：WATANABE Saisuke

  公开号：US20080299329A1

  公开（公告）日：2008-12-04

  A cyclic olefin polymer is provided and includes a repeating unit represented by formula (1A) and a repeating unit represented by the formula (1B): R 1 and R 3 each independently represents a substituent, L 1 and L 2 each independently represents a single bond or a divalent linking group, m and p each independently represents an integer of 0 or 1, and n and q each independently represents an integer of 1 to 4; and A represents COOR 2 or OCOR 2 , and R 2 represents a linear alkyl group having a carbon number of 1 to 10. The cyclic olefin polymer has a copolymerization ratio of x and y satisfying 0.03≦y/(x+y)≦0.50, a number average molecular weight of from 70,000 to 300,000, and a weight average molecular weight of from 200,000 to 700,000.

  提供了一种环状烯烃聚合物，包括由公式（1A）表示的重复单元和由公式（1B）表示的重复单元：R1和R3各自独立地表示取代基，L1和L2各自独立地表示单键或二价连接基，m和p各自独立地表示0或1的整数，n和q各自独立地表示1到4的整数；A表示COOR2或OCOR2，R2表示具有1到10个碳原子的线性烷基。该环状烯烃聚合物具有x和y的共聚比满足0.03≦y/(x+y)≦0.50，数量平均分子量为70,000至300,000，重量平均分子量为200,000至700,000。
• Compositions curable by ring opening metathesis polymerarization at low temperatures and their application in the dental field
  申请人：3M Innovative Properties Company

  公开号：EP1942125A1

  公开（公告）日：2008-07-09

  The invention relates to a composition which is polymerizable by ring-opening metathesis polymerization (ROMP) comprising at least one monomer that is polymerizable by ROMP, at least one initiator of the Hoveyda-Grubbs type for initiating the ROMP and at least one retarder selected from the group consisting of heterocyclic a means having a ring with at least one N-atom and five or less atoms constituting the ring bearing the at least one N-atom. The invention further relates to a process for the preparation of a composition which is polymerizable by ROMP, a dental material obtainable by polymerizing a composition according to the invention and the use of a substance selected from the group consisting of heterocyclic amines having a ring with at least one N-atom and five or less atoms constituting the ring bearing the at least one N-atom or of a mixture of two or more of such substances as a retarder in ROMP.

  本发明涉及一种可通过开环偏聚聚合反应（ROMP）聚合的组合物，该组合物包含至少一种可通过ROMP聚合的单体、至少一种用于引发ROMP的Hoveyda-Grubbs型引发剂和至少一种选自具有至少一个N原子的环和五个或更少的原子构成具有至少一个N原子的环的杂环组成的组的缓凝剂。本发明还涉及一种可通过 ROMP 聚合的组合物的制备方法、一种可通过聚合根据本发明制备的组合物而获得的牙科材料，以及在 ROMP 中使用一种选自杂环胺的物质作为缓凝剂，该杂环胺具有至少一个 N 原子和五个或更少的原子组成的环，或两种或更多种此类物质的混合物。
• TAKAI, TOSHIHIRO;YAMADA, TOHRU;MUKAIYAMA, TERUAKI, CHEM. LETT.,(1990) N, C. 1657-1660
  作者：TAKAI, TOSHIHIRO、YAMADA, TOHRU、MUKAIYAMA, TERUAKI

  DOI：——

  日期：——
• PHOTORESIST COMPOSITIONS COMPRISING POLYCYCLIC POLYMERS WITH ACID LABILE PENDANT GROUPS
  申请人：THE B.F. GOODRICH COMPANY

  公开号：EP1021477A1

  公开（公告）日：2000-07-26