[Ru(cyclopentadienyl)(η(2)-bis(diphenylphosphino)methane)(η(1)-bis(diphenylphosphino)methane)]Cl

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ru(cyclopentadienyl)(η(2)-bis(diphenylphosphino)methane)(η(1)-bis(diphenylphosphino)methane)]Cl
• 英文别名: Chlororuthenium; cyclopentane; diphenylphosphanylmethyl(diphenyl)phosphane
• 化学式: C₅₅H₄₉P₄Ru*Cl
• 分子量: 970.412
• InChiKey: HRBFDXZUHKFKHA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  12.13
• 重原子数：
  61
• 可旋转键数：
  12
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 [Ru(cyclopentadienyl)(η(2)-bis(diphenylphosphino)methane)(η(1)-bis(diphenylphosphino)methane)]Cl 以 甲醇 为溶剂， 以75%的产率得到(η5-C5H5)(bis(diphenylphosphino)methane)(η1-bis(diphenylphosphino)methane)ruthenium(II) hexafluorophosphate
  参考文献：
  名称：

  Bruce, Michael I.; Humphrey, Mark G.; Patrick, Jennifer M., Australian Journal of Chemistry, 1983, vol. 36, # 10, p. 2065 - 2072

  摘要：

  DOI：
• 作为产物：
  描述：

  chloro(η5-cyclopentadienyl)(triphenylphosphine)(η1-bis(diphenylphosphino)methane)ruthenium(II) 、 双二苯基膦甲烷 以 苯 为溶剂， 以38%的产率得到[Ru(cyclopentadienyl)(η(2)-bis(diphenylphosphino)methane)(η(1)-bis(diphenylphosphino)methane)]Cl
  参考文献：
  名称：

  Bruce, Michael I.; Humphrey, Mark G.; Patrick, Jennifer M., Australian Journal of Chemistry, 1983, vol. 36, # 10, p. 2065 - 2072

  摘要：

  DOI：

文献信息

• Synthesis and Electrochemistry of Heterobimetallic Ruthenium/Platinum and Molybdenum/Platinum Complexes
  作者：Stephen D. Orth、Michael R. Terry、Khalil A. Abboud、Brian Dodson、Lisa McElwee-White

  DOI：10.1021/ic9510977

  日期：1996.1.1

  As starting materials for heterobimetallic complexes, [RuCp(PPh(3))CO(PPh(2)H)]PF6 and [RuCp(PPh(3))CO(eta(1)-dppm)]PF6 were prepared from RuCp(PPh(3))(CO)Cl. In the course of preparing [RuCp(eta(2)-dppm)(eta(1)-dppm)]Cl from RuCp(Ph(3)P)(eta(1)-dppm)Cl, the new monomer RuCpCl(eta(1)-dppm)(2) was isolated. The uncommon coordination mode of the two monodentate bis(phosphines) was confirmed by X-ray crystallography [a = 11.490(1) Angstrom, b = 14.869(2) Angstrom, c = 15.447(2) Angstrom, alpha = 84.63(1)degrees, beta = 70.55(1)degrees, gamma = 72.92(1)degrees, V = 2378.7(5) Angstrom(3), d(calc) = 1.355 g cm(-3) (298 K), triclinic, P (1) over bar, Z = 2]. The dppm-bridged bimetallic complexes RuCp(PPh(3))Cl(mu-dppm)PtCl2, RuCpCl(mu-dppm)(2)PtCl2, and [RuCp(PPh(3))CO(mu-dppm)PtCl2]PF6 each exhibit electrochemistry consistent with varying degrees of metal-metal interaction. The cationic heterobimetallic complexes [Mo(CO)3(mu-dppm)(2)Pt(H)]PF6 and [MoCp(Co)(2)(mu-PPh(2))(mu-H)Pt(PPh(3))(MeCN)]PF6 were prepared by chloride abstraction from the corresponding neutral bimetallic species and show electrochemical behavior similar to the analogous Ru/Pt complexes.
• Bruce, Michael I.; Humphrey, Mark G.; Patrick, Jennifer M., Australian Journal of Chemistry, 1983, vol. 36, # 10, p. 2065 - 2072
  作者：Bruce, Michael I.、Humphrey, Mark G.、Patrick, Jennifer M.、White, Allan H.

  DOI：——

  日期：——