n-Pentyl n-hexyl disulfide

• 分子结构分类: 有机化合物 - 有机硫化合物 - 有机二硫化物
• 英文名称: n-Pentyl n-hexyl disulfide
• 英文别名: 1-(pentyldisulfanyl)hexane
• 化学式: C₁₁H₂₄S₂
• 分子量: 220.4
• InChiKey: BBRSAOQUYAEPBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  13
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Production of linear alpha olefins from organic sulfides
  申请人：SAUDI ARABIAN OIL COMPANY

  公开号：US11046624B1

  公开（公告）日：2021-06-29

  Embodiments of the disclosure provide a system and method for producing a linear alpha olefin. A disulfide, a hydrogen donating compound, and water are combined to produce a mixture. The mixture is introduced to a reactor operated at a pressure equal to or greater than 22.06 MPa and a temperature equal to or greater than 374 deg. C. to produce an effluent stream. The effluent stream is separated to produce a product stream including the linear alpha olefin. The disulfide can be a compound of formula R—S—S—R′ where R is a first alkyl group having carbon atoms ranging from 1 to 12 and R′ is a second alkyl group having carbon atoms ranging from 5 to 12. The hydrogen donating compound can include a partially hydrogenated multi-ring aromatic compound.

  本公开的实施方案提供了一种生产线性α-烯烃的系统和方法。将二硫化物、氢捐赠化合物和水混合生成混合物。将该混合物引入反应器，反应器的压力等于或大于 22.06 兆帕，温度等于或大于 374 摄氏度。C. 的条件下运行，以产生流出液流。分离流出物，生成包括线性α-烯烃的产品流。二硫化物可以是式 R-S-S-R′ 的化合物，其中 R 是具有 1 至 12 个碳原子的第一烷基，R′ 是具有 5 至 12 个碳原子的第二烷基。供氢化合物可包括部分氢化的多环芳香化合物。
• PRODUCTION OF LINEAR ALPHA OLEFINS FROM ORGANIC SULFIDES
  申请人：SAUDI ARABIAN OIL COMPANY

  公开号：US20210179512A1

  公开（公告）日：2021-06-17

  Embodiments of the disclosure provide a system and method for producing a linear alpha olefin. A disulfide, a hydrogen donating compound, and water are combined to produce a mixture. The mixture is introduced to a reactor operated at a pressure equal to or greater than 22.06 MPa and a temperature equal to or greater than 374 deg. C to produce an effluent stream. The effluent stream is separated to produce a product stream including the linear alpha olefin. The disulfide can be a compound of formula R—S—S—R′ where R is a first alkyl group having carbon atoms ranging from 1 to 12 and R′ is a second alkyl group having carbon atoms ranging from 5 to 12. The hydrogen donating compound can include a partially hydrogenated multi-ring aromatic compound.
• US4067979A
  申请人：——

  公开号：US4067979A

  公开（公告）日：1978-01-10
• [EN] PRODUCTION OF LINEAR ALPHA OLEFINS FROM ORGANIC SULFIDES<br/>[FR] PRODUCTION D'ALPHA-OLÉFINES LINÉAIRES À PARTIR DE SULFURES ORGANIQUES
  申请人：SAUDI ARABIAN OIL CO

  公开号：WO2021119521A1

  公开（公告）日：2021-06-17

  Embodiments of the disclosure provide a system and method for producing a linear alpha olefin. A disulfide, a hydrogen donating compound, and water are combined to produce a mixture. The mixture is introduced to a reactor operated at a pressure equal to or greater than 22.06 MPa and a temperature equal to or greater than 374 deg. C to produce an effluent stream. The effluent stream is separated to produce a product stream including the linear alpha olefin. The disulfide can be a compound of formula RSSR where R is a first alkyl group having carbon atoms ranging from 1 to 12 and R is a second alkyl group having carbon atoms ranging from 5 to 12. The hydrogen donating compound can include a partially hydrogenated multi-ring aromatic compound.
• [EN] COMPOSITIONS AND METHODS FOR SILENCING VEGF-A EXPRESSION<br/>[FR] COMPOSITIONS ET PROCÉDÉS POUR LE SILENÇAGE DE L'EXPRESSION DE VEGF-A
  申请人：ALNYLAM PHARMACEUTICALS INC

  公开号：WO2021163066A1

  公开（公告）日：2021-08-19

  The disclosure relates to double-stranded ribonucleic acid (dsRNA) compositions targeting VEGF-A, and methods of using such dsRNA compositions to alter (e.g., inhibit) expression of VEGF-A.