1-Phenylmercapto-2-ethoxy-ethan | 19594-05-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1-Phenylmercapto-2-ethoxy-ethan
• 英文别名: 2-Ethoxy-1-phenylmercaptoethan；1-ethoxy-2-phenylsulfanyl-ethane；1-Aethoxy-2-phenylmercapto-aethan；[(2-Ethoxyethyl)sulfanyl]benzene；2-ethoxyethylsulfanylbenzene
• CAS: 19594-05-9
• 化学式: C₁₀H₁₄OS
• 分子量: 182.287
• InChiKey: NNMYRIQJNYKPLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  34.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  丙烯酰碘 、 1-Phenylmercapto-2-ethoxy-ethan 、 乙腈 以85%的产率得到
  参考文献：
  名称：

  YANO Y.; MATAYOSHI T.; MISU K.; TAGAKI W., PHOSPHORUS AND SULFUR, 1976, 1, NO 1, 25-36

  摘要：

  DOI：
• 作为产物：
  描述：

  2-溴乙基乙基醚 、 苯硫酚 生成 1-Phenylmercapto-2-ethoxy-ethan
  参考文献：
  名称：

  二价硫化物-XIII中的3d轨道共振：对位取代的β-苯基巯基氯化物与相应的氧类似物的E2反应

  摘要：

  在含有叔丁醇钾的叔丁醇和含有乙醇钠的乙醇中，已经确定了碱催化消除一系列对位取代的β-苯基巯基乙基氯和相应的氧类似物的速率。硫化合物的E2反应速率为10 2 –10 3两种介质中对应的氧类似物的两倍大。这些比率可以与Hammettσ值相关。在叔丁醇和乙醇中，硫化合物的ρ值分别为1·98和2·14，而氧类似物的ρ值分别为1·33和1·50。与含氧化合物相比，含硫化合物的更快的动力学速率和较高的Hammettρ值表明3d轨道共振在这些含硫化合物的E2消除反应中很重要。讨论了速率和取代基作用的其他含义。

  DOI：

  10.1016/s0040-4020(01)96302-1

文献信息

• Water-Promoted Highly Selective Anti-Markovnikov Addition of Thiols to Unactivated Alkenes
  作者：Brindaban Ranu、Tanmay Mandal

  DOI：10.1055/s-2007-973877

  日期：2007.4

  The highly selective anti-Markovnikov addition of thiols to unactivated alkenes is demonstrated in water at room temperature without any additive. This is a very simple and efficient method for the synthesis of linear thioethers.

  在室温下，无需任何添加剂，在水中实现了高度选择性的抗马尔科夫尼科夫反应，将硫醇添加到未活化的烯烃中。这是一种非常简单且高效的线性硫醚合成方法。
• Prileshaewa; Schostakowskii, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1958, p. 1104,1109; engl. Ausg. S. 1071, 1075
  作者：Prileshaewa、Schostakowskii

  DOI：——

  日期：——
• Highly selective anti-Markovnikov addition of thiols to vinyl ethers under solvent- and catalyst-free conditions
  作者：Feng-Wen Lou、Jian-Ming Xu、Bo-Kai Liu、Qi Wu、Qian Pan、Xian-Fu Lin

  DOI：10.1016/j.tetlet.2007.10.072

  日期：2007.12

  A simple and efficient protocol for the anti-Markovnikov addition of thiols to vinyl ethers under solvent-and catalyst-free conditions has been established. A series of thiol ethers containing oxygen atom were obtained with good to excellent yields. (C) 2007 Elsevier Ltd. All rights reserved.
• RESIST COMPOSITION AND METHOD FOR PRODUCING RESIST PATTERN
  申请人：ICHIKAWA Koji

  公开号：US20130022917A1

  公开（公告）日：2013-01-24

  A resist composition having a resin having a structural unit represented by the formula (I), a resin being insoluble or poorly soluble in alkali aqueous solution, but becoming soluble in an alkali aqueous solution by the action of an acid and not including the structural unit represented by the formula (I), and an acid generator represented by the formula (II), wherein R 1 , A 1 , R 2 , R II1 , R II2 , L II1 , Y II1 , R II3 , R II4 , R II5 , R II6 , R II7 , n, s and R II8 are defined in the specification.
• COMPOUND, RESIN, RESIST COMPOSITION AND METHOD FOR PRODUCING RESIST PATTERN
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20160131971A1

  公开（公告）日：2016-05-12

  A resist composition includes (A1) a resin having an acid-labile group, (A2) a resin which includes a structural unit represented by formula (I), and an acid generator: wherein R 1 represents a hydrogen atom, a halogen atom or a C 1 to C 6 alkyl group in which a hydrogen atom can be replaced by a halogen atom, R 2 represents a C 1 to C 12 fluorinated saturated hydrocarbon group, A 1 represents a C 2 to C 6 alkanediyl group or *-A 2 -X 1 -(A 3 -X 2 ) a -A 4 b -, * represents a binding site to an oxygen atom in —O—CO—, A 2 , A 3 and A 4 each independently represent a C 1 to C 6 alkanediyl group, X 1 and X 2 each independently represent —O—, —CO—O— or —O—CO—, and “a” represents 0 or 1.