5-methyl-5H-naphtho[2,3-c]carbazole | 100025-44-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 5-methyl-5H-naphtho[2,3-c]carbazole
• 英文别名: N-Methyl-naphtho<2',3'; 3,4>carbazol；5H-Naphtho[2,3-c]carbazole, 5-methyl-；5-methylnaphtho[2,3-c]carbazole
• CAS: 100025-44-3
• 化学式: C₂₁H₁₅N
• 分子量: 281.357
• InChiKey: MVAKSMHUTQEPIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  5-methyl-5H-naphtho[2,3-c]carbazole-8,13-dione 在 溶剂黄146 、 氢化铝 作用下， 以 乙醇 、 水 为溶剂， 以22 %的产率得到5-methyl-5H-naphtho[2,3-c]carbazole
  参考文献：
  名称：

  B(C6F5)3-催化的[4 + 2]环化策略：5H-萘并[2,3-c]咔唑-8,13-二酮衍生物的合成及光物理性质

  摘要：

  本文通过B(C 6 F 5 ) 3催化的[4 + 2]环化反应，高效地合成了一系列新型咔唑醌类化合物。该方案不仅操作简单、底物范围广、原子经济性高，而且催化剂负载量低，避免使用金属催化剂。此外，我们在不同的还原条件下构建了多种新型咔唑稠合化合物。光物理表征结果表明，咔唑稠合衍生物的结构对其荧光性质有显着影响。

  DOI：

  10.1021/acs.joc.2c02064

文献信息

• POLYMER COMPOUND, MATERIAL FOR ELECTRONIC ELEMENTS, MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENTS, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20150249215A1

  公开（公告）日：2015-09-03

  Provided are a polymer compound, which comprises a copolymer containing at least a unit B, and a unit A and/or a unit C referring to repeating units A, B and C, and which has a weight-average molecular weight of from 50,000 to 1,500,000; a material for electronic devices and a material for organic electroluminescent devices comprising the compound; an organic electroluminescent device having an anode, a cathode and an organic thin film layer, wherein at least one organic thin film layer contains the polymer compound; a coating liquid containing the polymer compound and a solvent; and a method for producing an organic electroluminescent device using the coating liquid. Also provided is a polymer compound suitable to a coating method; a material for electronic devices and a material for organic electroluminescent devices comprising the compound; and an organic EL device, a coating liquid and a method for producing an organic EL device using the compound.

  提供了一种聚合物化合物，包括至少含有一个单位B的共聚物，以及重复单元A、B和C所指的单位A和/或单位C，其重量平均分子量为50,000至1,500,000；一种用于电子器件的材料和一种用于有机电致发光器件的材料，包括该化合物；一种有阳极、阴极和有机薄膜层的有机电致发光器件，其中至少一个有机薄膜层含有该聚合物化合物；一种含有该聚合物化合物和溶剂的涂层液；以及使用该涂层液制备有机电致发光器件的方法。还提供了一种适用于涂层方法的聚合物化合物；一种包括该化合物的电子器件材料和有机电致发光器件材料；以及一种有机EL器件、涂层液和使用该化合物制备有机EL器件的方法。
• Polymer compound, material for electronic elements, material for organic electroluminescent elements, and organic electroluminescent element
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10038143B2

  公开（公告）日：2018-07-31

  Provided are a polymer compound, which comprises a copolymer containing at least a unit B, and a unit A and/or a unit C referring to repeating units A, B and C, and which has a weight-average molecular weight of from 50,000 to 1,500,000; a material for electronic devices and a material for organic electroluminescent devices comprising the compound; an organic electroluminescent device having an anode, a cathode and an organic thin film layer, wherein at least one organic thin film layer contains the polymer compound; a coating liquid containing the polymer compound and a solvent; and a method for producing an organic electroluminescent device using the coating liquid. Also provided is a polymer compound suitable to a coating method; a material for electronic devices and a material for organic electroluminescent devices comprising the compound; and an organic EL device, a coating liquid and a method for producing an organic EL device using the compound.

  本发明提供了一种聚合物化合物，它由至少含有一个单元 B 和一个单元 A 和/或一个单元 C 的共聚物组成，单元 A、B 和 C 的重量平均分子量在 50,000 至 1,500,000 之间；一种电子设备材料和一种有机电致发光器件材料，其中包含该化合物；具有阳极、阴极和有机薄膜层的有机电致发光器件，其中至少一个有机薄膜层含有该聚合物化合物；含有该聚合物化合物和溶剂的涂覆液；以及使用该涂覆液生产有机电致发光器件的方法。此外，还提供了适用于涂层方法的聚合物化合物；包含该化合物的电子器件材料和有机电致发光器件材料；以及有机电致发光器件、涂层液和使用该化合物生产有机电致发光器件的方法。
• Conjugated polymer and use thereof in organic electronic device
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US11161933B2

  公开（公告）日：2021-11-02

  A conjugated polymer comprises repeating units as represented by formula (I), A-Bp  (I) p is the number of the repeating units, and p is an integer more than or equal to 1; and A has a structure as represented by formula (II), and B has a structure as represented by formula (II) or formula (III). The described conjugated polymer has a higher triplet energy level and a higher charge transfer property.

  共轭聚合物由式 (I) 所代表的重复单元组成、 A-Bp (I) p 是重复单元的个数，且 p 是大于或等于 1 的整数；且 A 具有式（II）表示的结构，B 具有式（II）或式（III）表示的结构。 所述共轭聚合物具有更高的三重能级和更高的电荷转移特性。
• PHOTOELECTRIC CONVERSION DEVICE, PRODUCTION METHOD THEREOF, PHOTOSENSOR, IMAGING DEVICE AND THEIR DRIVE METHODS
  申请人：NOMURA Kimiatsu

  公开号：US20110063485A1

  公开（公告）日：2011-03-17

  A photoelectric conversion device comprising a transparent electrically conductive film, a photoelectric conversion film and an electrically conductive film in this order, wherein the photoelectric conversion film comprises a photoelectric conversion layer, and an electron blocking layer, wherein the electron blocking layer contains a compound represented by the specific formula.
• METHOD FOR PURIFYING ORGANIC MATERIAL, MATERIAL FOR ORGANIC ELECTRONICS, PHOTOELECTRIC CONVERSION DEVICE, OPTICAL SENSOR, IMAGING DEVICE, AND ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：FUJIFILM CORPORATION

  公开号：US20140042411A1

  公开（公告）日：2014-02-13

  Provided is a method for purifying an organic material having a 10% weight reduction temperature of 250° C. or more as measured by thermogravimetry at a vacuum degree of 1×10 −2 Pa or less, which may sublime and purify the organic material having high heat resistance at high sublimation temperature with high purity and high yield in a short period of time, in which the organic material is subjected sublimation purification after a concentration of inorganic impurities in the organic material is adjusted to 5,000 ppm or less.