3-cyclohexyl-1,2-dihydroxybenzene | 1133-62-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-cyclohexyl-1,2-dihydroxybenzene
• 英文别名: 3-cyclohexyl-1,2-benzenediol；3-cyclohexyl-pyrocatechol；3-Cyclohexyl-brenzcatechin；2.3-Dihydroxy-1-cyclohexyl-benzol；Cyclohexylbrenzkatechine；3-cyclohexylbenzene-1,2-diol
• CAS: 1133-62-6
• 化学式: C₁₂H₁₆O₂
• 分子量: 192.258
• InChiKey: XKCZQONRGGXTQN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  环己基苯 在 葡萄糖 作用下， 以 aq. phosphate buffer 为溶剂， 以1.2 g的产率得到3-cyclohexyl-1,2-dihydroxybenzene
  参考文献：
  名称：

  Medium-Scale Preparation of Useful Metabolites of Aromatic Compounds via Whole-Cell Fermentation with Recombinant Organisms

  摘要：

  The whole-cell fermentation of aromatic coumpounds with Escherichia coli JM109 (pDTG601) on a medium scale (10-15 L) produces enantiopure cyclohexadienediols. A detailed procedure for the fermentation is described, and yields for several metabolites are provided. A similar procedure using E. coli JM109 (pDTG602) affords catechols. The dienediols are useful for asymmetric synthesis, and several important targets originating from these metabolites are tabulated.

  DOI：

  10.1021/op020013s

文献信息

• Masterbatch comprising colorant particles and a polyol poly(hydroxy fatty acid) ester as dispersing agent
  申请人：EINAR A/S

  公开号：US10472471B2

  公开（公告）日：2019-11-12

  The present invention relates to a masterbatch comprising colorant particles, a polyol poly(hydroxy fatty acid) ester dispersing agent and a carrier resin. The masterbatch is used for coloring thermoplastic polymer compositions. The present invention also relates to a method for producing said masterbatch, a colored thermoplastic polymer composition comprising said masterbatch and colored thermoplastic products formed of said colored thermoplastic composition.

  本发明涉及一种母料，由着色剂颗粒、多元醇聚（羟基脂肪酸）酯分散剂和载体树脂组成。该母料用于热塑性聚合物组合物的着色。本发明还涉及一种生产所述母料、包含所述母料的有色热塑性聚合物组合物和由所述有色热塑性组合物形成的有色热塑性产品的方法。
• Method of alkylating phenols
  申请人：DOW CHEMICAL CO

  公开号：US02125310A1

  公开（公告）日：1938-08-02
• Synthesis of Cyclohexylphenols
  作者：M. V. Postnova、S. G. Koshel'、N. V. Lebedeva、E. A. Kuznetsova、G. N. Koshel'

  DOI：10.1023/b:rujo.0000010556.87182.43

  日期：2003.10

  Catalytic alkylation of phenols with cyclohexanol gives o- and p-cyclohexylphenols as the major products. The effect of temperature, catalyst nature, and reactant concentration on the reaction outcome was studied.
• Mono-cyclohexyl-1.2-dihydroxybenzenes
  申请人：DOW CHEMICAL CO

  公开号：US02044318A1

  公开（公告）日：1936-06-16
• Kozlikovskii, Ya. B.; Koshchii, V. A.; Butov, S. A., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, p. 746 - 749
  作者：Kozlikovskii, Ya. B.、Koshchii, V. A.、Butov, S. A.、Ovsiyuk, T. F.

  DOI：——

  日期：——