N,N-di(biphenyl-4-yl)-N-(9-phenyl-9H-carbazol-3-yl)amine | 1414937-45-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-di(biphenyl-4-yl)-N-(9-phenyl-9H-carbazol-3-yl)amine
• 英文别名: 9-phenyl-N,N-bis(4-phenylphenyl)carbazol-3-amine
• CAS: 1414937-45-3
• 化学式: C₄₂H₃₀N₂
• 分子量: 562.714
• InChiKey: JLNMCOJOKLEIQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  44
• 可旋转键数：
  6
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  二(4-联苯基)胺 、 3-碘-9苯基咔唑 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 xylene 为溶剂， 反应 4.5h， 以66%的产率得到N,N-di(biphenyl-4-yl)-N-(9-phenyl-9H-carbazol-3-yl)amine
  参考文献：
  名称：

  Carbazole Compound, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device

  摘要：

  提供一种由一般式（G1）表示的咔唑化合物。在该式中，α代表苯基，Ar1代表具有1至6个碳原子的烷基基团、取代或未取代的苯基、取代或未取代的萘基团或取代或未取代的菲基团，Ar2代表氢、取代或未取代的苯基、取代或未取代的萘基团或取代或未取代的菲基团，Ar3代表取代或未取代的苯基、取代或未取代的萘基团或取代或未取代的菲基团，R1代表氢、具有1至6个碳原子的烷基基团或取代或未取代的苯基。此外，n为0或1。

  公开号：

  US20120302762A1

文献信息

• ORGANIC LIGHT EMITTING DEVICE
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20170288147A1

  公开（公告）日：2017-10-05

  An organic light emitting device including an anode; a hole transport region on the anode; an emission layer on the hole transport region; an electron transport region on the emission layer; and a cathode on the electron transport region, wherein the hole transport region includes: a first hole transport layer including a first hole transport material represented by the following Formula 1 or a second hole transport material represented by the following Formula 2; and a second hole transport layer on the first hole transport layer, the second hole transport layer including a third hole transport material represented by the following Formula 3 or a fourth hole transport material represented by the following Formula 4:

  一种有机发光器件，包括：阳极；位于阳极上的空穴传输区域；位于空穴传输区域上的发射层；位于发射层上的电子传输区域；以及位于电子传输区域上的阴极，其中空穴传输区域包括：第一空穴传输层，包括由以下化学式1表示的第一空穴传输材料或由以下化学式2表示的第二空穴传输材料；以及位于第一空穴传输层上的第二空穴传输层，第二空穴传输层包括由以下化学式3表示的第三空穴传输材料或由以下化学式4表示的第四空穴传输材料：
• Organometallic complex, light-emitting element, light-emitting device, electronic appliance, and lighting device
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US10109806B2

  公开（公告）日：2018-10-23

  A light-emitting element including a phosphorescent organometallic complex is provided. The organometallic complex emits phosphorescence in the yellow green to orange wavelength range and has high emission efficiency and high reliability. Thus, the organometallic complex that exhibits phosphorescence is provided. The organometallic complex, in which nitrogen at the 3-position of a pyrimidine ring is coordinated to a metal, a carbazole skeleton is bonded to the 4-position of the pyrimidine ring, and the carbazole skeleton is bonded to the metal, is used as an emission center. The metal is preferably a Group 9 element or a Group 10 element, more preferably iridium.

  提供了一种包括磷光有机金属配合物的发光元件。该有机金属配合物在黄绿至橙色波长范围内发射磷光，并具有高发射效率和高可靠性。因此，提供了展现磷光的有机金属配合物。该有机金属配合物中，嘧啶环的3位氮原子与金属配位，咔唑骨架与嘧啶环的4位结合，并且咔唑骨架与金属结合，被用作发射中心。金属首选为第9族元素或第10族元素，更优选为铱。
• Light-Emitting Element, Light-Emitting Device, Electronic Device, Lighting Device, and Novel Organic Compound
  申请人：Takeda Kyoko

  公开号：US20130048964A1

  公开（公告）日：2013-02-28

  A light-emitting element includes an EL layer between a pair of electrodes. The EL layer contains a first compound and a second compound. The first compound is a phosphorescent iridium metal complex having a LUMO level of greater than or equal to −3.5 eV and less than or equal to −2.5 eV, and the second compound is an organic compound having a pyrimidine skeleton. The light-emitting element includes an EL layer between a pair of electrodes. The EL layer contains a first compound and a second compound. The first compound is a phosphorescent iridium metal complex having a diazine skeleton, and the second compound is an organic compound having a pyrimidine skeleton.

  一种发光元件包括两个电极之间的EL层。EL层包含第一化合物和第二化合物。第一化合物是一种具有大于或等于-3.5电子伏特且小于或等于-2.5电子伏特的荧光铱金属配合物，第二化合物是具有嘧啶骨架的有机化合物。发光元件包括两个电极之间的EL层。EL层包含第一化合物和第二化合物。第一化合物是具有嘧啶骨架的荧光铱金属配合物，第二化合物是具有嘧啶骨架的有机化合物。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20160118597A1

  公开（公告）日：2016-04-28

  A material for an organic electroluminescent device having high emission efficiency and long life and an organic electroluminescent device including the same. The material for an organic electroluminescent device is represented by the following Formula 5.

  一种具有高发光效率和长寿命的有机电致发光器件材料，以及包括该材料的有机电致发光器件。该有机电致发光器件材料由以下公式5表示。
• COMPOUND, LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20210061753A1

  公开（公告）日：2021-03-04

  A novel compound represented by formula (G1) is provided. In formula (G1), A represents a substituted or unsubstituted condensed aromatic ring having 10 to 30 carbon atoms or a substituted or unsubstituted condensed heteroaromatic ring having 10 to 30 carbon atoms, and Z 1 to Z 3 each independently have a structure represented by formula (Z-1) or (Z-2). In formula (Z-1), X 1 and X 2 each independently represent any one of an alkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a cycloalkyl group having a bridge structure and having 7 to 10 carbon atoms, and a trialkylsilyl group having 3 to 12 carbon atoms. In addition, Ar 1 to Ar 4 each independently represent a substituted or unsubstituted aromatic hydrocarbon group having 6 to 13 carbon atoms, and at least one of Ar 1 to Ar 4 has the same substituent as X 1 or X 2 .

  提供了一种由公式（G1）表示的新化合物。在公式（G1）中，A代表具有10到30个碳原子的取代或未取代的紧缩芳香环或具有10到30个碳原子的取代或未取代的紧缩杂环，Z1至Z3各自独立具有由公式（Z-1）或（Z-2）表示的结构。在公式（Z-1）中，X1和X2各自独立地表示具有3到10个碳原子的烷基，具有3到10个碳原子的取代或未取代的环烷基，具有7到10个碳原子的桥式环烷基和具有3到12个碳原子的三烷基硅基中的任何一种。此外，Ar1到Ar4各自独立地表示具有6到13个碳原子的取代或未取代的芳香烃基，并且Ar1到Ar4中至少有一个具有与X1或X2相同的取代基。