5-乙烯基双环<2.2.2>-2-辛烯 | 35125-14-5

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 中文名称: 5-乙烯基双环<2.2.2>-2-辛烯
• 英文名称: 5-Vinylbicyclo<2.2.2>-2-octene
• 英文别名: 5-vinylbicyclo[2.2.2]oct-2-ene；5-vinyl-bicyclo[2.2.2]oct-2-ene；5-Vinyl-bicyclo[2.2.2]oct-2-en；5-Vinyl-bicyclo<2.2.2>octen-(2)；5-Ethenylbicyclo[2.2.2]oct-2-ene
• CAS: 35125-14-5
• 化学式: C₁₀H₁₄
• 分子量: 134.221
• InChiKey: OVAIKAHGQOHGBD-UHFFFAOYSA-N

物化性质

• 沸点：
  73-74 °C(Press: 25 Torr)
• 密度：
  0.9115 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5-乙烯基双环<2.2.2>-2-辛烯 在 双氧水 、 溶剂黄146 作用下， 以 水 为溶剂， 反应 4.0h， 生成 C₁₀H₁₄O 、 C₁₀H₁₆O₂
  参考文献：
  名称：

  Oxidative dihydroxylation of alicyclic unsaturated hydrocarbons with vinyl- and norbornene fragments in pseudohomogenic system

  摘要：

  Oxidation of alicyclic unsaturated hydrocarbons (4-vinylcyclohexene, 5-vinylnorbornene, 5-cyclohexenylnorbornene, and 5-vinylbicyclooctene) with 30% hydrogen peroxide solutions and percarbamide is studied. Reaction was carried out at 40-70A degrees C in the presence of heterogenized peroxocomplex compounds of molybdenum and tungsten formed "in situ" in the reaction of metal oxohalides with H3PO4, nano-dimensional particles of carbon material, and hydrogen peroxide. Main oxidation products of alicyclic diene hydro-carbons are the corresponding unsaturated epoxides and diols. Depending on the reaction condition their ratio varies in a wide range.

  DOI：

  10.1134/s1070363213010118
• 作为产物：
  描述：

  5-(α-Hydroxyethyl)bicyclo<2.2.2>oct-2-ene 生成 5-乙烯基双环<2.2.2>-2-辛烯
  参考文献：
  名称：

  Petrow; Sopow, Zhurnal Obshchei Khimii, 1957, vol. 27, p. 1795,1797, 1804; engl. Ausg. S. 1862, 1864,1870

  摘要：

  DOI：

文献信息

• Petrow; Sopow, Zhurnal Obshchei Khimii, 1957, vol. 27, p. 1795,1797, 1804; engl. Ausg. S. 1862, 1864,1870
  作者：Petrow、Sopow

  DOI：——

  日期：——
• A Modified Synthesis of 5-Vinylbicyclo[2.2.1]-2-heptene and Related Systems
  作者：M. G. Veliev、M. M. Guseinov、S. A. Mamedov

  DOI：10.1055/s-1981-29469

  日期：——
• VELIEV M. G.; GUSEINOV M. M.; MAMEDOV S. A., SYNTHESIS, 1981, NO 5, 400
  作者：VELIEV M. G.、 GUSEINOV M. M.、 MAMEDOV S. A.

  DOI：——

  日期：——
• Oxidative dihydroxylation of alicyclic unsaturated hydrocarbons with vinyl- and norbornene fragments in pseudohomogenic system
  作者：Kh. M. Alimardanov、N. I. Garibov、M. Ya. Abdullaeva、O. A. Sadygov、A. D. Kuliev、E. G. Ismailov

  DOI：10.1134/s1070363213010118

  日期：2013.1

  Oxidation of alicyclic unsaturated hydrocarbons (4-vinylcyclohexene, 5-vinylnorbornene, 5-cyclohexenylnorbornene, and 5-vinylbicyclooctene) with 30% hydrogen peroxide solutions and percarbamide is studied. Reaction was carried out at 40-70A degrees C in the presence of heterogenized peroxocomplex compounds of molybdenum and tungsten formed "in situ" in the reaction of metal oxohalides with H3PO4, nano-dimensional particles of carbon material, and hydrogen peroxide. Main oxidation products of alicyclic diene hydro-carbons are the corresponding unsaturated epoxides and diols. Depending on the reaction condition their ratio varies in a wide range.
• LERMONTOV S. A.; BELIKOVA N. A.; SKORNYAKOVA T. G.; PEXK T. I.; LIPPMAA E+, ZH. ORGAN. XIMII, 1980, 16, HO 11, 2322-2329
  作者：LERMONTOV S. A.、 BELIKOVA N. A.、 SKORNYAKOVA T. G.、 PEXK T. I.、 LIPPMAA E+

  DOI：——

  日期：——