4-(9H-carbazol-9-yl)-4'-(9-phenyl-9H-carbazol-3-yl)triphenylamine | 1246637-79-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-(9H-carbazol-9-yl)-4'-(9-phenyl-9H-carbazol-3-yl)triphenylamine
• 英文别名: PCBACzP；N-(4-carbazol-9-ylphenyl)-N-phenyl-4-(9-phenylcarbazol-3-yl)aniline
• CAS: 1246637-79-5
• 化学式: C₄₈H₃₃N₃
• 分子量: 651.81
• InChiKey: WIAKUDDSHVPECX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  51
• 可旋转键数：
  6
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-苯基-4-(9-苯基-9H-咔唑-3-基)苯胺 、 9-(4-溴苯基)咔唑 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 5.0h， 以91%的产率得到4-(9H-carbazol-9-yl)-4'-(9-phenyl-9H-carbazol-3-yl)triphenylamine
  参考文献：
  名称：

  Carbazole derivative, light-emitting element material, light-emitting element, light-emitting device, electronic device, and lighting device

  摘要：

  提供了一种由通式（1）表示的咔唑衍生物。在该式中，Ar1表示一个有6到10个碳原子形成环的取代或未取代芳基；α和β独立地表示一个有6到12个碳原子形成环的取代或未取代芳烃基；R1表示一个有1到4个碳原子的烷基或一个有6到10个碳原子形成环的取代或未取代芳基；R11到R17和R21到R28独立地表示氢、一个有1到4个碳原子的烷基或一个有6到10个碳原子形成环的取代或未取代芳基。

  公开号：

  US08507695B2

文献信息

• Aromatic amine derivative, and organic electroluminescent element
  申请人：Kato Tomoki

  公开号：US10246441B2

  公开（公告）日：2019-04-02

  An aromatic amine derivative including a substituent A and a substituent B each represented by the formula (1) or (2) and having an arylene group bound to a carbazole structure, in which the substituent A and the substituent B include groups different from each other in the position at which the arylene group is bonded to the carbazole structure, and the substituent A and the substituent B are bonded to the same nitrogen atom or different nitrogen atoms in the molecule; an organic electroluminescent device including an organic thin-film layer formed of one or more layers including at least a light emitting layer, the organic thin-film layer being interposed between a cathode and a anode, in which at least one layer of the organic thin-film layer contains the aromatic amine derivative, and the molecules are rarely crystallized.

  一种芳香胺衍生物，包括各自由式(1)或(2)表示并具有与咔唑结构结合的芳基的取代基A和取代基B，其中取代基A和取代基B在芳基与咔唑结构结合的位置上包括彼此不同的基团，并且取代基A和取代基B与分子中的相同氮原子或不同氮原子结合；一种有机电致发光器件，包括由一层或多层形成的有机薄膜层，该有机薄膜层至少包括一个发光层，该有机薄膜层位于阴极和阳极之间，其中至少一层有机薄膜层含有芳香胺衍生物，且分子很少结晶。
• CARBAZOLE DERIVATIVE, LIGHT-EMITTING ELEMENT MATERIAL, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：NOMURA Hiroko

  公开号：US20100245217A1

  公开（公告）日：2010-09-30

  A carbazole derivative represented by the general formula (1) is provided. In the formula, Ar 1 represents a substituted or unsubstituted aryl group having 6 to 10 carbon atoms which form a ring; α and β independently represent a substituted or unsubstituted arylene group having 6 to 12 carbon atoms which form a ring; R 1 represents an alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aryl group having 6 to 10 carbon atoms which form a ring; and R 11 to R 17 and R 21 to R 28 independently represent hydrogen, an alkyl group having 1 to 4 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 10 carbon atoms which form a ring.
• AROMATIC AMINE DERIVATIVE, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：KATO Tomoki

  公开号：US20120292606A1

  公开（公告）日：2012-11-22

  An aromatic amine derivative including a substituent A and a substituent B each represented by the formula (1) or (2) and having an arylene group bound to a carbazole structure, in which the substituent A and the substituent B include groups different from each other in the position at which the arylene group is bonded to the carbazole structure, and the substituent A and the substituent B are bonded to the same nitrogen atom or different nitrogen atoms in the molecule; an organic electroluminescent device including an organic thin-film layer formed of one or more layers including at least a light emitting layer, the organic thin-film layer being interposed between a cathode and a anode, in which at least one layer of the organic thin-film layer contains the aromatic amine derivative, and the molecules are rarely crystallized.
• ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20200052212A1

  公开（公告）日：2020-02-13

  An organic electroluminescence device having a further improved lifetime, which comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises at least one dopant material selected from the compounds represented by formulae (D1) and (D2), at least one first compound selected from the compounds represented by formulae (19), (21), (22), and (23), and at least one second compound selected from the compounds represented by formulae (2a), (2b), and (2c) and an electronic device comprising the organic electroluminescence device are described.
• US8507695B2
  申请人：——

  公开号：US8507695B2

  公开（公告）日：2013-08-13