N,N-bis-(3-aminopropyl)-2-phenylethylamine | 144174-89-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-bis-(3-aminopropyl)-2-phenylethylamine
• 英文别名: N'-(3-aminopropyl)-N'-(2-phenylethyl)propane-1,3-diamine
• CAS: 144174-89-0
• 化学式: C₁₄H₂₅N₃
• 分子量: 235.373
• InChiKey: RGXAGAITGGRBKB-UHFFFAOYSA-N

物化性质

• 沸点：
  376.6±27.0 °C(Predicted)
• 密度：
  0.997±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  55.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N,N-bis-(3-aminopropyl)-2-phenylethylamine 、 3-(2-bromoacetyl)-4-hydroxyfuran-2(5H)-one 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 以37%的产率得到3,3',3",3‴-(2,2',2",2‴-{[(phenethylazanediyl)bis(propane-3,1-diyl)]bis(azanetriyl)}tetrakis[acetyl])tetrakis[4-hydroxyfuran-2(5H)-one]
  参考文献：
  名称：

  Synthesis and evaluation of 3-acyltetronic acid-containing metal complexing agents

  摘要：

  Potential metal chelators containing one or several acyltetronic acid moieties were prepared from cyclic or acyclic amines and polyamines, and from bis(phenols) by reaction with 1-4 equiv of 3-bromoacetyltetronic acid in the presence of potassium carbonate. The affinity constants of the chelating agents for toxic metallic cations Cd2+, Cs+, and Pb2+ and for dimethylarsinic acid were measured, at pH 7.5 and 9.3. Compound 4, an acyclic triamine containing four acyltetronic moieties, was found to complex efficiently all the tested species. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.10.087
• 作为产物：
  描述：

  在 C₂H₆*(x)H₂O 作用下， 以 乙醇 为溶剂， 以77%的产率得到N,N-bis-(3-aminopropyl)-2-phenylethylamine
  参考文献：
  名称：

  Synthesis and evaluation of 3-acyltetronic acid-containing metal complexing agents

  摘要：

  Potential metal chelators containing one or several acyltetronic acid moieties were prepared from cyclic or acyclic amines and polyamines, and from bis(phenols) by reaction with 1-4 equiv of 3-bromoacetyltetronic acid in the presence of potassium carbonate. The affinity constants of the chelating agents for toxic metallic cations Cd2+, Cs+, and Pb2+ and for dimethylarsinic acid were measured, at pH 7.5 and 9.3. Compound 4, an acyclic triamine containing four acyltetronic moieties, was found to complex efficiently all the tested species. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.10.087

文献信息

• Acyclic mononuclear and macrocyclic dinuclear silver(I) complexes of Schiff base ligands derived from N,N-bis(2-aminoalkyl)-2-phenylethylamines
  作者：David.E. Fenton、Paul C. Hellier

  DOI：10.1016/s0020-1693(00)92401-0

  日期：1992.8

  mononuclear and macrocyclic dinuclear silver(I) complexes of ligands derived from the Schiff base condensation of N, N-bis(2-aminoalkyl)-2-phenylethylamines with 2,6-diacetylpyridine are reported and discussed. It is noted that changing the 2-aminoalkyl groups of the alkylamines from ethyl to n-propyl provides a change from an acyclic mononuclear silver(I) compound to a macrocyclic dinuclear silver(I) compound

  摘要报道并讨论了N，N-双（2-氨基烷基）-2-苯基乙胺与2,6-二乙酰基吡啶的席夫碱缩合反应生成的配体的无环单核和大环双核银（I）配合物。注意，将烷基胺的2-氨基烷基基团从乙基改变为正丙基提供了从无环单核银（I）化合物到大环双核银（I）化合物的变化。
• Alkaline cleaning composition and methods for removing lipstick
  申请人：Ecolab USA Inc.

  公开号：US10954476B2

  公开（公告）日：2021-03-23

  Methods of cleaning waxy, oily and/or greasy soils, including lipsticks and lip gloss, are disclosed. Methods of removing lipstick and lip gloss stains in warewash and laundry applications are disclosed through application of cleaning compositions comprising long chain polyamines, namely C6-C20 polyamines having between 1 and 5 nitrogens. In some aspects alkaline cleaning compositions comprise sodium hydroxide detergents and a C6-C20 polyamines such as N1-(3-aminopropyl)-N3-dodecylpropane-1,3,diamine) and/or N1,N1,N3-tris(3-aminopropyl)-N3-dodecylpropane-1,3-diamine.

  本发明公开了包括口红和唇彩在内的蜡质、油性和/或油腻污垢的清洁方法。本发明公开了通过使用包含长链多胺（即具有 1 至 5 个硝基的 C6-C20 多胺）的清洁组合物来去除餐具洗涤和洗衣应用中的口红和唇彩污渍的方法。在某些方面，碱性清洁组合物包括氢氧化钠洗涤剂和 C6-C20 多胺，如 N1-(3-氨基丙基)-N3-十二烷基丙烷-1,3,二胺和/或 N1,N1,N3-三(3-氨基丙基)-N3-十二烷基丙烷-1,3-二胺。
• ALKALINE CLEANING COMPOSITION AND METHODS FOR REMOVING LIPSTICK
  申请人：Ecolab USA Inc.

  公开号：US20190136155A1

  公开（公告）日：2019-05-09

  Methods of cleaning waxy, oily and/or greasy soils, including lipsticks and lip gloss, are disclosed. Methods of removing lipstick and lip gloss stains in warewash and laundry applications are disclosed through application of cleaning compositions comprising long chain polyamines, namely C6-C20 polyamines having between 1 and 5 nitrogens. In some aspects alkaline cleaning compositions comprise sodium hydroxide detergents and a C6-C20 polyamines such as N1-(3-aminopropyl)-N3-dodecylpropane-1,3,diamine) and/or N1,N1,N3-tris(3-aminopropyl)-N3-dodecylpropane-1,3-diamine.