3,5,3',5'-tetra(p-pyridin-3-yl)phenyl-[1,1']biphenyl | 1009033-95-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5,3',5'-tetra(p-pyridin-3-yl)phenyl-[1,1']biphenyl
• 英文别名: 3-[4-[3-[3,5-Bis(4-pyridin-3-ylphenyl)phenyl]-5-(4-pyridin-3-ylphenyl)phenyl]phenyl]pyridine；3-[4-[3-[3,5-bis(4-pyridin-3-ylphenyl)phenyl]-5-(4-pyridin-3-ylphenyl)phenyl]phenyl]pyridine
• CAS: 1009033-95-7
• 化学式: C₅₆H₃₈N₄
• 分子量: 766.945
• InChiKey: NHSPIXBQVDWKHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.3
• 重原子数：
  60
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-(3-吡啶基)苯硼酸频哪醇酯 、 3,3′,5,5′-四溴-1,1′-联苯 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 24.0h， 以73%的产率得到3,5,3',5'-tetra(p-pyridin-3-yl)phenyl-[1,1']biphenyl
  参考文献：
  名称：

  新型的四吡啶苯武装的联苯作为磷光OLED的电子传输材料。

  摘要：

  设计并合成了一系列四吡啶基苯酚联苯衍生物，作为基于fac-tris（2-苯基吡啶）铱（Ir（PPy）3）的绿色磷光有机电子的电子输运和激子和空穴阻挡层发光器件（OLED），与三（8-羟基喹啉）铝（Alq3）的电子传输层和2,9-二甲基-4的激子和空穴阻挡层相比，效率得到了提高，7-二苯基菲咯啉（BCP）。

  DOI：

  10.1021/ol7030872

文献信息

• ORGANIC LIGHT-EMITTING APPARATUS
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3211681A1

  公开（公告）日：2017-08-30

  An organic light-emitting apparatus includes an organic light-emitting device and a magnetic field-applying member that applies a magnetic field to the organic light-emitting device. The organic light-emitting device includes a host and a dopant.

  一种有机发光装置包括一个有机发光器件和一个向有机发光器件施加磁场的磁场施加部件。有机发光器件包括主机和掺杂剂。
• Organic light-emitting device and method of operating the same
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US10366653B2

  公开（公告）日：2019-07-30

  An organic light-emitting device including a magnetoresistive element including a first magnetic layer, a second magnetic layer, and a separation layer disposed between the first magnetic layer and the second magnetic layer, an organic light-emitting element electrically connected to the magnetoresistive element, wherein the organic light-emitting element comprises a first electrode, a second electrode, and an organic light-emission layer disposed between the first electrode and the second electrode, a magnetic field applying unit configured to apply a magnetic field to at least the magnetoresistive element, and optionally, to the organic light-emitting element, a power source configured to supply a current between the magnetoresistive element and the organic light-emitting element, and a current source configured to apply a current between both terminals of the organic light-emitting element, wherein light-emission characteristics of the organic light-emitting device are changed depending on a direction and intensity of a current passing through the magnetoresistive element due to the power source and a direction and intensity of a current passing through the organic light-emitting element due to the power source and the current source.

  一种有机发光器件，包括磁阻元件，该磁阻元件包括第一磁层、第二磁层以及设置在第一磁层和第二磁层之间的分离层；与磁阻元件电连接的有机发光元件，其中有机发光元件包括第一电极、第二电极以及设置在第一电极和第二电极之间的有机发光层；磁场施加单元，该磁场施加单元被配置为至少向磁阻元件施加磁场，并且可选地、配置为在磁阻元件和有机发光元件之间提供电流的电源，以及配置为在有机发光元件的两个端子之间施加电流的电流源，其中有机发光器件的发光特性的改变取决于电源导致的通过磁阻元件的电流方向和强度，以及电源和电流源导致的通过有机发光元件的电流方向和强度。
• Organic light-emitting apparatus
  申请人：Samsung Electronics Co., Ltd.

  公开号：US10734585B2

  公开（公告）日：2020-08-04

  An organic light-emitting apparatus includes an organic light-emitting device and a magnetic field-applying member that applies a magnetic field to the organic light-emitting device. The organic light-emitting device includes a host and a dopant.

  一种有机发光装置包括一个有机发光器件和一个向有机发光器件施加磁场的磁场施加部件。有机发光器件包括主机和掺杂剂。
• ORGANIC LIGHT-EMITTING DEVICE AND METHOD OF OPERATING THE SAME
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20180114484A1

  公开（公告）日：2018-04-26

  An organic light-emitting device including a magnetoresistive element including a first magnetic layer, a second magnetic layer, and a separation layer disposed between the first magnetic layer and the second magnetic layer, an organic light-emitting element electrically connected to the magnetoresistive element, wherein the organic light-emitting element comprises a first electrode, a second electrode, and an organic light-emission layer disposed between the first electrode and the second electrode, a magnetic field applying unit configured to apply a magnetic field to at least the magnetoresistive element, and optionally, to the organic light-emitting element, a power source configured to supply a current between the magnetoresistive element and the organic light-emitting element, and a current source configured to apply a current between both terminals of the organic light-emitting element, wherein light-emission characteristics of the organic light-emitting device are changed depending on a direction and intensity of a current passing through the magnetoresistive element due to the power source and a direction and intensity of a current passing through the organic light-emitting element due to the power source and the current source.
• Novel Four-Pyridylbenzene-Armed Biphenyls as Electron-Transport Materials for Phosphorescent OLEDs
  作者：Shi-Jian Su、Daisaku Tanaka、Yan-Jun Li、Hisahiro Sasabe、Takashi Takeda、Junji Kido

  DOI：10.1021/ol7030872

  日期：2008.3.1

  four-pyridylbenzene-armed biphenyl derivatives were designed and synthesized as an electron-transport and exciton- and hole-block layer for the fac-tris(2-phenylpyridine)iridium (Ir(PPy)3)-based green phosphorescent organic light-emitting devices (OLEDs), giving improved efficiency in comparison to that with both the electron-transport layer of tris(8-hydroxyquinoline)aluminum (Alq3) and the exciton- and hole-block

  设计并合成了一系列四吡啶基苯酚联苯衍生物，作为基于fac-tris（2-苯基吡啶）铱（Ir（PPy）3）的绿色磷光有机电子的电子输运和激子和空穴阻挡层发光器件（OLED），与三（8-羟基喹啉）铝（Alq3）的电子传输层和2,9-二甲基-4的激子和空穴阻挡层相比，效率得到了提高，7-二苯基菲咯啉（BCP）。