((PhO)₂PS₂)₂Ni | 29776-92-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ((PhO)₂PS₂)₂Ni
• 英文别名: Ni diphenyldithiophosphate；diphenoxy-sulfanylidene-sulfido-λ5-phosphane;nickel(2+)
• CAS: 29776-92-9
• 化学式: C₂₄H₂₀NiO₄P₂S₄
• 分子量: 621.322
• InChiKey: IWWCTRGGDDPEBD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  9.13
• 重原子数：
  35.0
• 可旋转键数：
  8.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  36.92
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  ((PhO)₂PS₂)₂Ni 在 2,2'-bipyridyl 作用下， 以 丙酮 为溶剂， 生成 Ni(diphenylphosphorodithioate)2(2,2'-dipyridyl)
  参考文献：
  名称：

  有机硫磷配体的过渡金属配合物。III a双（二苯基磷酸二硫代镍）镍与芳族和杂环二胺的六配位加合物

  摘要：

  Ni [S 2 P（OC 6 H 5）2 ] 2（II）双（二苯基二硫代磷酸镍）与芳族伯二胺（o，o'-和p，p'diaminobiphenyl，2 ，7-二氨基芴，邻-和对苯二胺）和杂环二胺（邻菲咯啉，2,2'-联吡啶）。分离了Ni [S 2 P（OPh）2 ] 2 ·2o-PHDA的两个异构体。所有化合物均通过元素分析，电子和红外光谱以及磁矩进行了表征。在这些数据的基础上讨论了可能的结构。

  DOI：

  10.1016/s0020-1693(00)81949-0
• 作为产物：
  描述：

  nickel(II) bis(O,O-di-phenyl phosphorodithioate)*2THF 以 solid 为溶剂， 生成 ((PhO)₂PS₂)₂Ni
  参考文献：
  名称：

  McEwen, W. E.; Tien, J. H.; Kalbacher, B. J., Phosphorus and Sulfur and the Related Elements, 1984, vol. 19, p. 17 - 26

  摘要：

  DOI：

文献信息

• <i>O‐</i> Alkyldithiophosphate Nickel Complexes with dcpf Ligand as Efficient Electrocatalysts for Hydrogen Evolution
  作者：Dong‐Liang Zhang、Cheng‐Long Deng、Bin Xie、Yu‐Long Li、Chuan Lai、Wen‐Yu Mou、Lin‐Xin He、Xiao‐Xue Bai、Tao Li、Jia‐Xi Cao、Jun Wang

  DOI：10.1002/aoc.5261

  日期：2020.1

  Six new O‐alkyldithiophosphate nickel complexes with dcpf ligand, [(dcpf)Ni(S2PO}OR)] (dcpf = 1,1′‐bis (dicyclohexylphosphino)ferrocene, R = CH3 (1), CH3CH2 (2), Ph (3), 4‐MeC6H4 (4), PhCH2 (5) and PhCH2CH2 (6)), have been synthesized by the treatment of dcpf with ((RO)2PS2)2Ni in satisfactory yields. These complexes were characterized by elemental analysis, spectroscopy (FTIR, UV–vis, 1H, 13C, and

  六个具有dcpf配体[[dcpf）Ni（S 2 P O} OR）]的新O-烷基二硫代磷酸镍配合物（dcpf = 1,1'-双（二环己基膦基）二茂铁，R = CH 3（1），CH 3 CH 2（2），Ph（3），4-MeC 6 H 4（4），PhCH 2（5）和PhCH 2 CH 2（6））是通过用（（RO）2 PS 2）2镍的产率令人满意。这些配合物的特征在于元素分析，光谱（FTIR，UV-vis，1 H，13 C和31 P NMR），热重分析和单晶X射线衍射。在镍原子1，2 ·CH 2氯2，3 ·CH 2氯2，4 ·2CH 2氯2 ·THF，和2（5）·己烷采用稍微扭曲正方形平面配位环境由两个磷原子完成dcpf配体和O-的两个硫原子烷基二硫代磷酸酯配体。此外，用于复合物的电化学特性1 - 6也通过循环伏安法研究。通过加入120mM的三氟乙酸（TFA），周转频率（TOF）为值1 - 6估计为1243
• Synthesis, spectroscopic characterization and structural studies of nickel complexes of O,O′-diaryl(dibenzyl) dithiophosphates: Crystal structures of Ni[S2P(OC6H4CH3-o)2]2, Ni[S2P(OC6H4CH3-m)2]2 and Ni[S2P(OCH2Ph)2]2
  作者：Ann L. Bingham、John E. Drake、Mark E. Light、Manisha Nirwan、Raju Ratnani

  DOI：10.1016/j.poly.2005.10.022

  日期：2006.3

  Purple-coloured, tetra-coordinated Ni(II) complexes, Ni[S2P(OR)(2)](2) (R = o-, m-, p-OC6H4Me, Ph and CH2Ph) have been obtained by reaction of NiCl2 with salts of corresponding O,O'-diaryl(dibenzyl) dithiophosphates and have been characterized by elemental analysis, UV, IR, H-1, and P-31 NMR spectroscopy. Trends in the data are discussed. The crystal structures of Ni[S2P(OC6H4Me-o)(2)](2), Ni[S2P(OC6H4Me-m)(2)](2) and Ni[S2P(OCH2Ph)(2)](2) are also described. Ni[S2P(OC6H4Me-o)(2)](2) crystallizes as monoclinic in the space group P2(1)/n with cell parameters a = 9.069(2), b = 13.503(2), c = 23.735(4) angstrom, alpha = 90.00 degrees, beta = 90.11(1)degrees, gamma = 90.00 degrees, V = 2906.6(8) angstrom(-3) Z = 4, R = 0.0351, R-w = 0.0787, Ni[S2P(OC6H4CH3-m)(2)](2) as triclinic in the space group P (1) over bar with cell parameters a = 9,4675(4), b = 12.8568(5), c = 13.1174(6) angstrom, alpha = 88.810(4)degrees, beta = 83.416(5)degrees, gamma = 73.711(4)degrees, V = 1522.4(1) angstrom(-3), Z = 2, R = 0.0354, R-w = 0.0830, and Ni[S2P(OCH2Ph)(2)](2) as triclinic in the space group P (1) over bar with cell parameters a = 10.887(2), b = 14.081(3), c = 16.238(3) angstrom, alpha = 72.70(3)degrees, beta = 76.57(3)degrees, gamma = 72.76(3)degrees, V = 2241.4(8) angstrom(-3), Z = 2, R = 0.0365, R-w = 0.0785. Each of these has a distorted square-planar geometry around nickel with MS4 coordination environment. (c) 2005 Elsevier Ltd. All rights reserved.
• McEwen, W. E.; Tien, J. H.; Kalbacher, B. J., Phosphorus and Sulfur and the Related Elements, 1984, vol. 19, p. 17 - 26
  作者：McEwen, W. E.、Tien, J. H.、Kalbacher, B. J.

  DOI：——

  日期：——
• Transition Metal Complexes of Organothiophosphorus Ligands. IIIa Six-coordinate Adducts of Nickel(II)bis(Diphenylphosphorodithioate) with aromatic and Heterocyclic Diamines
  作者：R. Micu-Semeniuc、L. Silaghi-dumitrescu、I. Haiduc

  DOI：10.1016/s0020-1693(00)81949-0

  日期：1976.1

  Nickel(II)bis(diphenylphosphorodithioate), Ni[S2P (OC6H5)2]2, forms several types of six-coordinate adducts with aromatic primary diamines (o,o'- and p,p'diaminobiphenyl, 2,7-diaminofluorene, o- and p-phenylenediamine) and heterocyclic diamines (orthophenanthroline, 2,2'-bipyridyl). Two isomers of Ni[S2P (OPh)2]2 ·2o-PHDA were isolated. All compounds were characterized by elemental analysis, electronic

  Ni [S 2 P（OC 6 H 5）2 ] 2（II）双（二苯基二硫代磷酸镍）与芳族伯二胺（o，o'-和p，p'diaminobiphenyl，2 ，7-二氨基芴，邻-和对苯二胺）和杂环二胺（邻菲咯啉，2,2'-联吡啶）。分离了Ni [S 2 P（OPh）2 ] 2 ·2o-PHDA的两个异构体。所有化合物均通过元素分析，电子和红外光谱以及磁矩进行了表征。在这些数据的基础上讨论了可能的结构。