Pt(1,2-bis(dimethylphosphino)ethane) | 959904-73-5

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: Pt(1,2-bis(dimethylphosphino)ethane)
• 英文别名: (dmpe)Pt
• CAS: 959904-73-5
• 化学式: C₆H₁₆P₂Pt
• 分子量: 345.221
• InChiKey: DXGHGKDZOCXNOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.47
• 重原子数：
  9.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  1,2-双(二甲基瞵)乙烷 、 {PtCl2(1,2-bis(dimethylphosphino)ethane)} 在 LiBHEt₃ 作用下， 以 四氢呋喃 为溶剂， 生成 {Pt(η1-(1,2-bis(dimethylphosphino)ethane))2} 、 、 Pt(1,2-bis(dimethylphosphino)ethane)
  参考文献：
  名称：

  Mixed biphosphine complexes of palladium(0); the structure of “bis(diphenylphosphino)ethane”-“bis(dicyclohexylphosphino)ethane” palladium(0)

  摘要：

  A range of mixed biphosphine complexes of palladium(0) has been prepared and characterized by P-31 NMR spectroscopy. The complexes disproportionate in solution at rates which depend on the nature of the ligands. The structure of [Pd(dcpe)(dppe)] has been established in an X-ray diffraction study.

  DOI：

  10.1016/s0277-5387(00)81751-9

文献信息

• Mixed biphosphine complexes of palladium(0); the structure of “bis(diphenylphosphino)ethane”-“bis(dicyclohexylphosphino)ethane” palladium(0)
  作者：Gillian T.L. Broadwood-Strong、Penny A. Chaloner、Peter B. Hitchcock

  DOI：10.1016/s0277-5387(00)81751-9

  日期：1993.4

  A range of mixed biphosphine complexes of palladium(0) has been prepared and characterized by P-31 NMR spectroscopy. The complexes disproportionate in solution at rates which depend on the nature of the ligands. The structure of [Pd(dcpe)(dppe)] has been established in an X-ray diffraction study.