2,8,14,20-Tetrakis(3-methylphenyl)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3(28),4,6,9(27),10,12,15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octol | 1260217-99-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2,8,14,20-Tetrakis(3-methylphenyl)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3(28),4,6,9(27),10,12,15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octol
• CAS: 1260217-99-9
• 化学式: C₅₆H₄₈O₈
• 分子量: 848.992
• InChiKey: ZUYXIXDSPHLDIZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.1
• 重原子数：
  64
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  162
• 氢给体数：
  8
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  3-甲基苯甲醛 、 间苯二酚 反应 0.08h， 以96%的产率得到2,8,14,20-Tetrakis(3-methylphenyl)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3(28),4,6,9(27),10,12,15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octol
  参考文献：
  名称：

  Microwave-assisted synthesis of resorcin[4]arene and pyrogallol[4]arene macrocycles

  摘要：

  A series of resorcin[4]arene and pyrogallol[4]arene macrocycles have been synthesized efficiently within 5 min, affording crystalline products suitable for single crystal X-ray diffraction, utilising microwave irradiation in a 'one-pot' reaction whilst controlling the selective formation of the rccc cone stereoisomer. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.09.115

文献信息

• PROCESS FOR PRODUCING CARBON MATERIAL
  申请人：Suzuki Junji

  公开号：US20100298522A1

  公开（公告）日：2010-11-25

  A process for producing a carbon material comprising the following steps (A) and (B): Step (A): a step of reacting a compound represented by the formula (1): wherein R represents a hydrogen atom etc., R′ represents a hydrogen atom etc., and n represents 3, 5 or 7, with an aldehyde compound to obtain a polymer, Step (B): a step of heating the polymer obtained in Step (A) at 600 to 3000° C. under an inert gas atmosphere.
• [EN] PROCESS FOR PRODUCING CARBON MATERIAL<br/>[FR] PROCÉDÉ DE FABRICATION D'UNE MATIÈRE CARBONÉE
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2009101947A2

  公开（公告）日：2009-08-20

  A process for producing a carbon material comprising the following steps (A) and (B): Step (A): a step of reacting a compound represented by the formula (1): wherein R represents a hydrogen atom etc., R' represents a hydrogen atom etc., and n represents 3, 5 or 7, with an aldehyde compound to obtain a polymer, Step (B): a step of heating the polymer obtained in Step (A) at 600 to 3000oC under an inert gas atmosphere.
• Microwave-assisted synthesis of resorcin[4]arene and pyrogallol[4]arene macrocycles
  作者：Muriel Funck、Daniel P. Guest、Gareth W.V. Cave

  DOI：10.1016/j.tetlet.2010.09.115

  日期：2010.12

  A series of resorcin[4]arene and pyrogallol[4]arene macrocycles have been synthesized efficiently within 5 min, affording crystalline products suitable for single crystal X-ray diffraction, utilising microwave irradiation in a 'one-pot' reaction whilst controlling the selective formation of the rccc cone stereoisomer. (C) 2010 Elsevier Ltd. All rights reserved.