3,3,4,4,5,5,6,6,7,7,8,8 Dodecafluoro-1,10-diisocyanatodecane | 130869-07-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3,3,4,4,5,5,6,6,7,7,8,8 Dodecafluoro-1,10-diisocyanatodecane
• 英文别名: 1,10-diisocyanato-3,3,4,4,5,5,6,6,7,7,8,8-dodecafluorodecane；3,3,4,4,5,5,6,6,7,7,8,8-Dodecafluoro-1,10-diisocyanato-decane；3,3,4,4,5,5,6,6,7,7,8,8-dodecafluoro-1,10-diisocyanatodecane
• CAS: 130869-07-7
• 化学式: C₁₂H₈F₁₂N₂O₂
• 分子量: 440.189
• InChiKey: QFBZSTRKAXTDMJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  28
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  1,6-二碘代十二氟己烷 在 dicobalt octacarbonyl 氯化亚砜 、 十二羰基三铁 、 HN₃*Py 作用下， 以 水 为溶剂， 100.0 ℃ 、5.07 MPa 条件下， 反应 62.25h， 生成 3,3,4,4,5,5,6,6,7,7,8,8 Dodecafluoro-1,10-diisocyanatodecane
  参考文献：
  名称：

  A facile synthesis of .alpha.,.omega.-dicarboxylic acids containing perfluoroalkylene groups

  摘要：

  DOI：

  10.1021/jo00016a041

文献信息

• Fluorine-containing alpha,omega-bifunctional compounds and process for their production
  申请人：SAGAMI CHEMICAL RESEARCH CENTER

  公开号：EP0383141A2

  公开（公告）日：1990-08-22

  A fluorine-containina α,ω-bifunctional compound havina the formula: wherein each of R1 and R2 independently is a hydrogen atom, an alkyl group or an aralkyl group; X is -COOH, -COOR3, -COY or -NCO, wherein R3 is an alkyl group or an aralkyl group and Y is a halogen atom or N3; and n is an integer of at least 1 provided that when X is -COOH, n is an integer of at least 4.

  一种含氟α,ω-双官能团化合物，其式如下 其中 R1 和 R2 各自独立地为氢原子、烷基或芳烷基；X 为-COOH、-COOR3、-COY 或-NCO，其中 R3 为烷基或芳烷基，Y 为卤素原子或 N3；n 至少为 1 的整数，条件是当 X 为-COOH 时，n 至少为 4 的整数。
• Synthesis of fluorinated diisocyanates
  作者：A. A. Malik、D. Tzeng、P. Cheng、K. Baum

  DOI：10.1021/jo00009a021

  日期：1991.4

  Fluorinated diisocyanates of the general structure OCN(CH2)2(CF2)n(CH2)2NCO were prepared from alpha,omega-diiodoperfluoroalkanes by insertion of ethylene into the CF2-I bond, displacement of the iodo groups with azide, reduction of the resulting azide groups to amines, and phosgenation of the diamine.
• Fluorinated reactive compositions for golf balls
  申请人：Rajagopalan Murali

  公开号：US20060199937A1

  公开（公告）日：2006-09-07

  A golf ball is disclosued, comprising: a core, the core having a diameter of 1.5 inches to 1.65 inches and a first coefficient of restitution of 0.8 or greater at 125 ft/s; an intermediate layer disposed about the core, the intermediate layer having a first Shore D hardness of 20 to 80 and comprising a blend of two or more ionomers; and an outer cover layer disposed about the intermediate layer; the outer cover layer having a thickness of 0.005 inches to 0.05 inches and a second Shore D hardness of 30 to 70, the outer cover layer being composed of a castable material formed from reactants comprising at least one fluorinated polyfunctional compound, wherein the golf ball has a second coefficient of restitution of 0.8 or greater at 125 ft/s and a compression of 50 to 120.
• US4942164A
  申请人：——

  公开号：US4942164A

  公开（公告）日：1990-07-17
• US5151535A
  申请人：——

  公开号：US5151535A

  公开（公告）日：1992-09-29