Propan-2-yl 3-phenyl-2-propan-2-yloxybenzoate | 566162-84-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Propan-2-yl 3-phenyl-2-propan-2-yloxybenzoate
• CAS: 566162-84-3
• 化学式: C₁₉H₂₂O₃
• 分子量: 298.382
• InChiKey: GPUKJQNVYOHDSE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Propan-2-yl 3-phenyl-2-propan-2-yloxybenzoate 在 manganese(IV) oxide 、 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 12.0h， 生成 2-isopropoxybiphenyl-3-carbaldehyde
  参考文献：
  名称：

  A highly efficient olefin metathesis initiator: improved synthesis and reactivity studies

  摘要：

  The synthesis of ligand 8, required for the preparation of catalyst 4c has been optimised. Ligand exchange studies indicate that biphenyl-based alkylidene 4c initiates considerably faster than its unsubstituted analogue 4a. The performance of 4c in ring-opening cross metathesis reactions involving substrates containing unprotected chelating atoms is also reported. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)00346-0
• 作为产物：
  描述：

  sodium 2-biphenylate 在 potassium carbonate 作用下， 50.0~190.0 ℃ 、2.03 MPa 条件下， 反应 36.0h， 生成 Propan-2-yl 3-phenyl-2-propan-2-yloxybenzoate
  参考文献：
  名称：

  A highly efficient olefin metathesis initiator: improved synthesis and reactivity studies

  摘要：

  The synthesis of ligand 8, required for the preparation of catalyst 4c has been optimised. Ligand exchange studies indicate that biphenyl-based alkylidene 4c initiates considerably faster than its unsubstituted analogue 4a. The performance of 4c in ring-opening cross metathesis reactions involving substrates containing unprotected chelating atoms is also reported. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)00346-0