1-[[Bis(2-hydroxyethyl)amino]methyl]benzotriazole-4-carboxylic acid

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并三唑类
• 英文名称: 1-[[Bis(2-hydroxyethyl)amino]methyl]benzotriazole-4-carboxylic acid
• 英文别名: 1-[[bis(2-hydroxyethyl)amino]methyl]benzotriazole-4-carboxylic acid
• 化学式: C₁₂H₁₆N₄O₄
• 分子量: 280.28
• InChiKey: OILIWDRDPKUVBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.9
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  7

文献信息

• CURABLE SILICONE COMPOSITION, AND OPTICAL SEMICONDUCTOR DEVICE
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP3059285A1

  公开（公告）日：2016-08-24

  The present invention provides a curable silicone composition for forming a cured product which inhibits the discoloration of silver electrodes or a silver-plated substrate in an optical semiconductor device due to a sulfur-containing gas, the curable silicone composition comprising: (A) an organopolysiloxane having at least two silicon-bonded alkenyl groups per molecule; (B) an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms per molecule; (C) an organic compound having an organic value of at least 175 in an organic conceptual diagram and having a specific group; and (D) a hydrosilylation reaction catalyst. In addition, the present invention provides an optical semiconductor device in which silver electrodes or a silver-plated substrate of an optical semiconductor device is sealed or covered with a cured product of the composition described above, the optical semiconductor device having excellent reliability after a sulfur resistance test.

  本发明提供了一种可固化的有机硅组合物，用于形成一种固化产品，该固化产品可抑制光学半导体器件中的银电极或镀银基板因含硫气体而变色，该可固化的有机硅组合物包括：(A)有机聚硅氧烷，其每个分子至少具有两个硅键烯基；(B)有机氢聚硅氧烷，其每个分子至少具有两个硅键氢原子；(C)有机化合物，其有机值在有机概念图中至少为175，并具有特定基团；和(D)氢化硅反应催化剂。此外，本发明还提供了一种光半导体器件，在该器件中，光半导体器件的银电极或镀银基板被上述组合物的固化产物密封或覆盖，该光半导体器件在耐硫测试后具有极佳的可靠性。
• CURABLE SILICONE COMPOSITION, CURED OBJECT THEREOF, AND OPTICAL SEMICONDUCTOR DEVICE
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP3103843A1

  公开（公告）日：2016-12-14

  A curable silicone composition comprising: (A) an organopolysiloxane represented by the average unit formula: (R13SiO1/2)a(R22SiO2/2)b(R3SiO3/2)c (R1 are alkyl groups, alkenyl groups, aryl groups, or aralkyl groups; R2 are alkyl groups or alkenyl groups; R3 is an alkyl group, aryl group, or an aralkyl group, provided that, in a molecule, at least 0.5 mol% of R1 to R3 are the alkenyl groups, at least one of R3 is the aryl group or the aralkyl group; and a, b, and c are numbers satisfying: 0.01 ≤ a ≤ 0.5, 0.4 ≤ b ≤ 0.8, 0.01 ≤ c ≤ 0.5, and a + b + c = 1); (B) an organopolysiloxane that is different from component (A); (C) an organopolysiloxane having at least two silicon atom-bonded hydrogen atoms in a molecule; and (D) a hydrosilylation reaction catalyst. A cured product exhibiting excellent dispersibility of phosphor and having high strength and gas barrier properties is formed.

  一种可固化的有机硅组合物，包括： (A) 由平均单元式表示的有机聚硅氧烷：(R13SiO1/2)a(R22SiO2/2)b(R3SiO3/2)c(R1是烷基、烯基、芳基或芳烷基；R2是烷基或烯基；R3是烷基、芳基或芳烷基，条件是在一个分子中，至少0.5 mol%的R1至R3是烯基，R3中至少有一个是芳基或芳烷基；a、b和c是满足以下条件的数字：0.01≤a≤0.5，0.4≤b≤0.8，0.01≤c≤0.5，且a＋b＋c＝1）；(B)不同于组分(A)的有机聚硅氧烷；(C)分子中至少有两个硅原子键合氢原子的有机聚硅氧烷；以及(D)加氢硅烷化反应催化剂。这样就形成了一种具有优异的荧光粉分散性、高强度和气体阻隔性的固化产品。
• ORGANOSILOXANE, CURABLE SILICONE COMPOSITION, AND SEMICONDUCTOR DEVICE
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP3153517A1

  公开（公告）日：2017-04-12

  An organosiloxane represented by the following general formula; a curable silicone composition comprising: (A) an organopolysiloxane having at least two alkenyl groups in a molecule; (B) an organohydrogenpolysiloxane having at least two silicon atom-bonded hydrogen atoms in a molecule; (C) an adhesion promoter containing the organosiloxane; and (D) a catalyst for hydrosilylation reaction; and a semiconductor device in which a semiconductor element is encapsulated with a cured product of the composition. A novel organosiloxane, a curable silicone composition that contains the novel organosiloxane as an adhesion promoter and that forms a cured product having excellent adhesion to various base materials, and a semiconductor device that is formed by using the composition and that has excellent reliability are provided.

  一种由以下通式表示的有机硅氧烷；一种可固化的有机硅组合物，其中包括：(A)分子中至少有两个烯基的有机聚硅氧烷；(B)分子中至少有两个硅原子键合氢原子的有机氢聚硅氧烷；(C)含有该有机硅氧烷的附着力促进剂；以及(D)用于氢化硅烷化反应的催化剂；以及一种半导体器件，其中的半导体元件用该组合物的固化产物封装。本发明提供了一种新型有机硅氧烷、一种含有该新型有机硅氧烷作为附着力促进剂并能形成与各种基底材料具有优异附着力的固化产物的可固化硅氧烷组合物，以及一种通过使用该组合物形成并具有优异可靠性的半导体器件。
• ORGANIC SILICON COMPOUND, CURABLE SILICONE COMPOSITION, AND SEMICONDUCTOR DEVICE
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP3153516A1

  公开（公告）日：2017-04-12

  An organosilicon compound represented by the general formula, a hydrosilylation- curable silicone composition containing the compound as an adhesion promoter, and a semiconductor device having a semiconductor element sealed with a cured product of the composition. To provide a novel organosilicon compound, a curable silicone composition that contains the organosilicon compound as an adhesion promoter, has excellent initial adhesion and adhesion durability to a base material such as an organic resin, and forms a cured product having high light transmittance, and a highly reliable semiconductor device produced using this composition.

  一种由通式表示的有机硅化合物、一种含有该化合物作为附着力促进剂的水硅烷化固化型有机硅组合物，以及一种具有用该组合物的固化产物密封的半导体元件的半导体器件。提供一种新型有机硅化合物、一种含有该有机硅化合物作为附着力促进剂、与有机树脂等基体材料具有优异的初始附着力和附着耐久性并能形成具有高透光率的固化产物的可固化有机硅组合物，以及一种使用该组合物生产的高可靠性半导体器件。
• ADHESION PROMOTER, CURABLE SILICONE COMPOSITION, AND SEMICONDUCTOR DEVICE
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP3153544A1

  公开（公告）日：2017-04-12

  An adhesion promoter represented by the average formula; a curable silicone composition comprising: (A) an organopolysiloxane having at least two alkenyl groups in a molecule, (B) an organohydrogenpolysiloxane having at least two silicon atom-bonded hydrogen atoms in a molecule, (C) the adhesion promoter, and (D) a hydrosilylation reaction catalyst; and a semiconductor device in which a semiconductor element is encapsulated with a cured product of the curable silicone composition. A novel adhesion promoter, a curable silicone composition that contains the adhesion promoter and that forms a cured product having excellent adhesion to various base materials, and an optical semiconductor device that is formed from the curable silicone composition and that has excellent reliability are provided.

  一种由平均式表示的附着力促进剂；一种可固化的有机硅组合物，其中包含：(A) 分子中至少有两个烯基的有机聚硅氧烷，(B) 分子中至少有两个硅原子键合氢原子的有机氢聚硅氧烷，(C) 附着力促进剂，以及 (D) 水硅烷化反应催化剂；以及一种半导体器件，其中半导体元件用该可固化的有机硅组合物的固化产物封装。本发明提供了一种新型附着力促进剂、一种含有该附着力促进剂并能形成与各种基底材料具有优异附着力的固化产物的可固化有机硅组合物，以及一种由该可固化有机硅组合物形成并具有优异可靠性的光学半导体器件。