3-Methyl-1-phenyl-1,2-dihydrobenzimidazol-1-ium;iodide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 3-Methyl-1-phenyl-1,2-dihydrobenzimidazol-1-ium;iodide
• 英文别名: 3-methyl-1-phenyl-1,2-dihydrobenzimidazol-1-ium;iodide
• 化学式: C14H15IN2
• 分子量: 338.19
• InChiKey: VUHNGZYLQXBXRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.05
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  7.7
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• Carbene containing metal complexes as OLEDs
  申请人：Tsai Yui-Yi

  公开号：US20050258742A1

  公开（公告）日：2005-11-24

  A process for preparing a compound having the formula L 2 IrL′ is provided. The process comprises: combining and L′ in the presence of an organic solvent to form a mixture, wherein L is a suitable carbene ligand precursor coordinated to Ir; and L′ is a bidentate ligand or two monodentate ligands, and L is different from L′; Also provided is a process for preparing a compound having the formula The process comprises: (a) combining L, a carbene ligand precursor, with an organic solvent; (b) maintaining the mixture of step (a) at a temperature from about 175° C. to less than the boiling point of the organic solvent in (a). A process for preparing a compound with the formula L 3 Ir is also provided. This process comprises combining and L in the presence of alcohol and a base to form a mixture, wherein L is a bidentate ligand that may form a five-membered chelate ring.

  提供了一种制备具有公式L2IrL′的化合物的方法。该方法包括：在有机溶剂存在下结合L和L′以形成混合物，其中L是适当的卡宾配体前体与Ir配位；L′是双齿配体或两个单齿配体，且L与L′不同；还提供了一种制备具有公式的化合物的方法。该方法包括：(a)将L，卡宾配体前体与有机溶剂结合；(b)将步骤(a)的混合物保持在约175℃至有机溶剂沸点以下的温度下。还提供了一种制备具有公式L3Ir的化合物的方法。该方法包括在醇和碱的存在下结合L和L以形成混合物，其中L是可能形成五元螯合环的双齿配体。
• [EN] TRANSITION METAL COMPLEXES WITH CARBENE LIGANDS AND USE THEREOF IN OLEDS<br/>[FR] COMPLEXES DE MÉTAUX DE TRANSITION AVEC DES LIGANDS DE TYPE CARBÈNE ET LEUR UTILISATION DANS LES OLED
  申请人：BASF SE

  公开号：WO2014024131A1

  公开（公告）日：2014-02-13

  The palladium and platinum complexes with one bidentate carbene ligand have the general formula (I). The OLEDs (Organic Light-Emitting Diodes) comprise the said complexes. A device selected from the group consisting of illuminating elements, stationary units and mobile visual display units comprises the said OLEDs. The use of such a metal-carbene complex in OLEDs, for example as emitter, matrix material, charge transport material and/or charge or exciton blocker.

  钯和铂与一个双齿卡宾配体形成的配合物的通式为（I）。所述配合物用于构成有机发光二极管（OLED）。所述OLED可以用于发光元件、固定装置和移动视觉显示单元中的一种。此类金属卡宾配合物可用于OLED中，例如作为发射剂、基质材料、电荷传输材料和/或电荷或激子阻断剂。
• TRANSITION METAL COMPLEXES WITH CARBENE LIGANDS AND USE THEREOF IN OLEDS
  申请人：BASF SE

  公开号：EP2882766A1

  公开（公告）日：2015-06-17
• CARBENE CONTAINING METAL COMPLEXES AS OLEDS
  申请人：TSAI Jui-Yi

  公开号：US20090302754A1

  公开（公告）日：2009-12-10

  A process for preparing a compound having the formula L 2 IrL′ is provided. The process comprises: combining and L′ in the presence of an organic solvent to form a mixture, wherein L is a suitable carbene ligand precursor coordinated to Ir; and L′ is a bidentate ligand or two monodentate ligands, and L is different from L′; Also provided is a process for preparing a compound having the formula The process comprises: (a) combining L, a carbene ligand precursor, with an organic solvent; (b) maintaining the mixture of step (a) at a temperature from about 175° C. to less than the boiling point of the organic solvent in (a). A process for preparing a compound with the formula L 3 Ir is also provided. This process comprises combining and L in the presence of alcohol and a base to form a mixture, wherein L is a bidentate ligand that may form a five-membered chelate ring.
• TRANSITION METAL COMPLEXES WITH CARBENE LIGANDS AND THE USE THEREOF IN OLEDS
  申请人：BASF SE

  公开号：US20150243912A1

  公开（公告）日：2015-08-27

  The palladium and platinum complexes with one bidentate carbene ligand have the general formula (I). The OLEDs (Organic Light-Emitting Diodes) comprise the said complexes. A device selected from the group consisting of illuminating elements, stationary units and mobile visual display units comprises the said OLEDs. The use of such a metal-carbene complex in OLEDs, for example as emitter, matrix material, charge transport material and/or charge or exciton blocker.