Ethylxanthogensaeure-phenethylester | 3278-36-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ethylxanthogensaeure-phenethylester
• 英文别名: dithiocarbonic acid O-ethyl ester-S-phenethyl ester；Dithiokohlensaeure-O-aethylester-S-phenaethylester；Ethoxy-phenethylsulfanyl-methanethione；O-ethyl 2-phenylethylsulfanylmethanethioate
• CAS: 3278-36-2
• 化学式: C₁₁H₁₄OS₂
• 分子量: 226.364
• InChiKey: QFUAGRDNVOJONZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  66.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Ethylxanthogensaeure-phenethylester 在 lithium aluminium tetrahydride 、 乙醚 作用下， 生成 2-苯乙硫醇
  参考文献：
  名称：

  Studies in Organic Sulfur Compounds. VII.¹ Lithium Aluminum Hydride Reduction of Xanthates to Mercaptans. Synthesis of Substituted β-Mercaptoethanols

  摘要：

  DOI：

  10.1021/ja01608a015
• 作为产物：
  描述：

  2,4-Diphenyl-1-(2-phenylethyl)-5,6-dihydrobenzo[h]quinolin-1-ium;tetrafluoroborate 、 potassium ethyl xanthogenate 以80%的产率得到
  参考文献：
  名称：

  ELSHAFIE, S. M. M., ORG. PREP. AND PROCED. INT., 1983, 15, N 4, 225-231

  摘要：

  DOI：

文献信息

• Synthetic process for trans-aminocyclohexyl ether compounds
  申请人：Barrett G. M. Anthony

  公开号：US20050038256A1

  公开（公告）日：2005-02-17

  A method of stereoselectively making an aminocyclohexyl ether comprises, for example, reacting to form the aminocyclohexyl ether having the formula respectively, wherein independently at each occurrence, R 1 and R 2 are independently hydrogen, C 1 -C 8 alkyl, C 3 -C 8 alkoxyalkyl, C 1 -C 8 hydroxyalkyl, or C 7 -C 12 aralkyl; or R 1 and R 2 are independently C 3 -C 8 alkoxyalkyl, C 1 -C 8 hydroxyalkyl, and C 7 -C 12 aralkyl; or R 1 and R 2 , when taken together with the nitrogen atom to which they are directly attached in formula (57) or (75), form a ring denoted by formula (I): wherein the ring of formula (I) is formed from the nitrogen as shown as well as three to nine additional ring atoms independently carbon, nitrogen, oxygen, or sulfur; where any two adjacent ring atoms may be joined together by single or double bonds, and where any one or more of the additional carbon ring atoms may be substituted with one or two substituents selected from the group consisting of hydrogen, hydroxy, C 1 -C 3 hydroxyalkyl, oxo, C 2 -C 4 acyl, C 1 -C 3 alkyl, C 2 -C 4 alkylcarboxy, C 1 -C 3 alkoxy, and C 1 -C 20 alkanoyloxy, or may be substituted to form a spiro five- or six-membered heterocyclic ring containing one or two oxygen and/or sulfur heteroatoms; or any two adjacent additional carbon ring atoms may be fused to a C 3 -C 8 carbocyclic ring, and any one or more of the additional nitrogen ring atoms may be substituted with substituents selected from the group consisting of hydrogen, C 1 -C 6 alkyl, C 2 -C 4 acyl, C 2 -C 4 hydroxyalkyl and C 3 -C 8 alkoxyalkyl; or R 1 and R 2 , when taken together with the nitrogen atom to which they are directly attached in formula (I), may form a bicyclic ring system selected from the group consisting of 3-azabicyclo[3.2.2]nonan-3-yl, 2-azabicyclo[2.2.2]octan-2-yl, 3-azabicyclo[3.1.0]hexan-3-yl, and 3-azabicyclo[3.2.0]heptan-3-yl; and wherein R 3 , R 4 and R 5 are independently bromine, chlorine, fluorine, carboxy, hydrogen, hydroxy, hydroxymethyl, methanesulfonamido, nitro, cyano, sulfamyl, trifluoromethyl, C 2 -C 7 alkanoyloxy, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 2 -C 7 alkoxycarbonyl, C 1 -C 6 thioalkyl, aryl or N(R 6 ,R 7 ) where R 6 and R 7 are independently hydrogen, acetyl, methanesulfonyl or C 1 -C 6 alkyl; or R 3 , R 4 and R 5 are independently hydrogen, hydroxy or C 1 -C 6 alkoxy; with the proviso that R 3 , R 4 and R 5 cannot all be hydrogen; and wherein O-J is a leaving group. Methods of making intermediates are also disclosed.

  一种立体选择性制备氨基环己醚的方法，例如，反应生成具有以下式子的氨基环己醚，其中在每个出现的位置上，独立的R1和R2分别为氢、C1-C8烷基、C3-C8烷氧基烷基、C1-C8羟基烷基或C7-C12芳基烷基；或者独立的R1和R2为C3-C8烷氧基烷基、C1-C8羟基烷基和C7-C12芳基烷基；或者R1和R2与它们直接连接的氮原子一起形成由以下式子表示的环：其中式子（I）的环由氮原子形成，以及三到九个独立的环原子，包括碳、氮、氧或硫；任意相邻的两个环原子可以通过单键或双键连接在一起，任何一个或多个额外的碳环原子可以被氢、羟基、C1-C3羟基烷基、氧代、C2-C4酰基、C1-C3烷基、C2-C4烷基羧基、C1-C3烷氧基或C1-C20烷酰氧基中的一个或两个取代，或者被取代以形成一个螺五元或六元杂环环，其中包含一个或两个氧和/或硫杂原子；任意相邻的两个额外碳环原子可以融合到一个C3-C8碳环中，任何一个或多个额外的氮环原子可以被氢、C1-C6烷基、C2-C4酰基、C2-C4羟基烷基和C3-C8烷氧基烷基中的一个或多个取代；或者R1和R2与它们直接连接的氮原子一起形成从以下组中选择的双环系统：3-氮杂双环[3.2.2]壬烷-3-基、2-氮杂双环[2.2.2]辛烷-2-基、3-氮杂双环[3.1.0]己烷-3-基和3-氮杂双环[3.2.0]庚烷-3-基；其中R3、R4和R5独立地为溴、氯、氟、羧基、氢、羟基、羟甲基、甲磺酰胺基、硝基、氰基、磺酰胺基、三氟甲基、C2-C7烷酰氧基、C1-C6烷基、C1-C6烷氧基、C2-C7烷氧羰基、C1-C6硫代烷基、芳基或N（R6，R7），其中R6和R7独立地为氢、乙酰、甲磺酰或C1-C6烷基；或者R3、R4和R5独立地为氢、羟基或C1-C6烷氧基；但是R3、R4和R5不能都为氢；O-J是一个离去基团。还公开了制备中间体的方法。
• New Organic Compounds for Use in Insect Control
  作者：B. H. ALEXANDER、S. I. GERTLER、T. A. ODA、R. T. BROWN、R. W. IHNDRIS、M. BEROZA

  DOI：10.1021/jo01074a039

  日期：1960.4
• POLYMERIZATION PROCESS WITH LIVING CHARACTERISTICS AND POLYMERS MADE THEREFROM
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1054906A1

  公开（公告）日：2000-11-29
• LOW-POLYDISPERSITY PHOTOIMAGEABLE POLYMERS AND PHOTORESISTS AND PROCESSES FOR MICROLITHOGRAPHY
  申请人：E.I. DUPONT DE NEMOURS AND COMPANY

  公开号：EP1673662A1

  公开（公告）日：2006-06-28
• [EN] POLYMERIZATION PROCESS WITH LIVING CHARACTERISTICS AND POLYMERS MADE THEREFROM<br/>[FR] PROCEDE DE POLYMERISATION PRESENTANT DES CARACTERISTIQUES VIVANTES ET POLYMERES OBTENUS PAR CE PROCEDE
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：WO1999031144A1

  公开（公告）日：1999-06-24

  (EN) A free radical polymerization process suitable for synthesizing polymers is disclosed. The process utilizes novel sulfur based chain transfer agents and is widely compatible over a range of monomers and reaction conditions. Novel polymers having low polydispersity and predictable specific polymer architecture amd molecular weight are produced by the process. The polymers produced by the process are suitable for use as binders in automotive OEM and refinish coatings.(FR) L'invention concerne un procédé de polymérisation radicalaire destiné à la synthèse de polymères. Le procédé fait appel à de nouveaux agents de migration de chaîne à base de soufre et est largement compatible dans une gamme de monomères et de conditions de réaction. Le procédé permet d'obtenir de nouveaux polymères présentant une faible polydispersité, ainsi qu'une architecture polymère et un poids moléculaire à spécificité prévisible. Les polymères obtenus grâce au procédé sont indiqués comme liants dans le marché automobile d'équipement d'origine et pour les revêtements de remise en état.