N,N-bis(benzylthiomethyl)hydroxylamine | 72418-21-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-bis(benzylthiomethyl)hydroxylamine
• 英文别名: N,N-bis(benzylsulfanylmethyl)hydroxylamine
• CAS: 72418-21-4
• 化学式: C₁₆H₁₉NOS₂
• 分子量: 305.465
• InChiKey: IBCYFTYCUDZFQB-UHFFFAOYSA-N

物化性质

• 熔点：
  137-139 °C(Solv: ethyl acetate (141-78-6))
• 沸点：
  452.3±40.0 °C(Predicted)
• 密度：
  1.228±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  74.1
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 苄硫醇 生成 N,N-bis(benzylthiomethyl)hydroxylamine
  参考文献：
  名称：

  Preparation of N-alkylthiomethyl derivatives of hydroxylamines.

  摘要：

  新类型的亚甲基化合物，N-烷基硫甲基衍生物的N-烷基（或芳基）羟胺和N,N-双（烷基硫甲基）羟胺，通过使用硫醇、甲醛和羟胺的Mannich型缩合反应获得。

  DOI：

  10.1248/cpb.27.1691

文献信息

• Inhibition of pulp and paper yellowing using hydroxylamines and other coadditives
  申请人：——

  公开号：US20020174964A1

  公开（公告）日：2002-11-28

  Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a N,N-dialkylhydroxylamine, an ester, amide or thio item substituted N,N-dialkylhydroxylamine or N,N-dibenzylhydroxylamine or an amminium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents and metal chelating agents. Combinations of hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. N,N-Diethylhydroxylamine and N,N-dibenzylhydroxylamine and their acid salts are surprisingly effective for this purpose.

  含有木质素的纸浆或纸张，尤其是化学机械或热机械纸浆或纸张，如果它们含有有效稳定剂量的N,N-二烷基羟胺、酯、酰胺或硫代物取代的N,N-二烷基羟胺或N,N-二苄基羟胺或其铵盐，它们具有增强的抗黄变性能。当它们与紫外线吸收剂、聚合抑制剂、亚硝基化合物、荧光增白剂和金属螯合剂等共添加剂之一或多个存在时，这种性能通常会进一步增强。N,N-二乙基羟胺和N,N-二苄基羟胺及其酸盐对此具有惊人的有效性。羟胺或其盐、苯并三唑或苯并酚紫外线吸收剂和金属螯合剂的组合特别有效。
• Ink jet ink and recording material
  申请人：——

  公开号：US20040126510A1

  公开（公告）日：2004-07-01

  The present invention relates to an ink jet ink, an ink jet recording material or an ink jet system comprising at least one sterically hindered N-hydroxylamine strong acid salt, for example 1-hydroxy-2,2,6,6-tetramethyl-4-hydroxypiperidinium chloride or bis(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate dihydrochloride; or comprising at least one dialkyl N-hydroxylamine salt, for example chloride, bisulfate, sulfate, phosphate, nitrate, ascorbate, formate, acetate, benzoate, oxalate, citrate, a carboxylate of ethylenediaminetetraacetic acid or of diethylenetriaminepentaacetic acid or polyacrylate salts of N,N-diethylhydroxylamine, N,N-bis(2-hydroxypropyl)hydroxylamine, N,N-bis(3-hydroxypropyl)hydroxylamine, N,N-dibenzylhydroxylamine or the N,N-di(alkyl)hydroxylamine produced by the direct oxidation of N,N-di(hydrogenated tallow)amine.

  本发明涉及一种喷墨墨水、喷墨记录材料或喷墨系统，其包含至少一种立体位阻的N-羟胺强酸盐，例如1-羟基-2,2,6,6-四甲基-4-羟基哌啶盐酸盐或双(1-羟基-2,2,6,6-四甲基哌啶-4-基)癸二酸二盐酸盐；或包含至少一种双烷基N-羟胺盐，例如氯化物、硫酸氢盐、硫酸盐、磷酸盐、硝酸盐、抗坏血酸盐、甲酸盐、乙酸盐、苯甲酸盐、草酸盐、柠檬酸盐、乙二胺四乙酸或二乙三胺五乙酸的羧酸盐或N,N-二乙基羟胺、N,N-双(2-羟基丙基)羟胺、N,N-双(3-羟基丙基)羟胺、N,N-二苄基羟胺或通过N,N-二(氢化牛脂)胺的直接氧化产生的N,N-二(烷基)羟胺。
• INHIBITION OF PULP AND PAPER YELLOWING USING HYDROXYLAMINES AND OTHER COADDITIVES
  申请人：——

  公开号：US20020088574A1

  公开（公告）日：2002-07-11

  Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a N,N-dialkylhydroxylamine, an ester, amide or thio substituted N,N-dialkylhydroxylamine or N,N-dibenzylhydroxylamine or an amminium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents and metal chelating agents. Combinations of hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. N,N-Diethylhydroxylamine and N,N-dibenzylhydroxylamine and their acid salts are surprisingly effective for this purpose.

  含有木质素的纸浆或纸张，特别是化学机械或热机械纸浆或纸张，如果它们含有有效稳定量的N,N-二烷基羟胺，酯，酰胺或硫代取代的N,N-二烷基羟胺或N,N-二苄基羟胺或其铵盐，则具有增强的抗黄变性能。当其中还存在来自紫外线吸收剂，聚合抑制剂，亚硝基，荧光增白剂和金属螯合剂的一种或多种辅助剂时，这种性能通常会进一步增强。羟胺或其盐，苯并三唑或苯并酚紫外线吸收剂和金属螯合剂的组合特别有效。N,N-二乙基羟胺和N,N-二苄基羟胺及其酸盐出人意料地有效。
• Heterocyclische 3-Ringverbindungen und jodhaltige Verbindungen enthaltende Polymere
  申请人：LANXESS Deutschland GmbH

  公开号：EP2270087A1

  公开（公告）日：2011-01-05

  Polymer, enthaltend wenigstens eine heterocyclische 3-Ring-Verbindung und eine jodhaltige Verbindung.

  由至少一种杂环三环化合物和一种含碘化合物组成的聚合物。
• Formulierungen enthaltend stabilisierte iodhaltige Verbindungen
  申请人：LANXESS Deutschland GmbH

  公开号：EP2462805A1

  公开（公告）日：2012-06-13

  Die Erfindung betrifft Mittel enthaltend a) Mikrokapseln enthaltend zumindest ein iodhaltiges Biozid sowie b) zumindest ein Stickstoff enthaltendes anorganisches Trägermaterial, ein Verfahren zur Herstellung der erfindungsgemäßen Mittel sowie die Verwendung der vorgenannten Mittel zum Schutz technischer Materialien wie insbesondere Anstrichmitteln und die geschützten technischen Materialien selbst.

  本发明涉及 a) 含有至少一种含碘杀菌剂的微胶囊和 b) 至少一种含氮无机载体材料的制剂，根据本发明生产制剂的工艺，以及使用上述制剂保护技术材料，特别是涂料和受保护的技术材料本身。