[N,N-di-(4,4-diphenylbut-3-enyl)-2,6-(dibromo)]aniline | 649559-72-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [N,N-di-(4,4-diphenylbut-3-enyl)-2,6-(dibromo)]aniline
• 英文别名: Benzenamine, 2,6-dibromo-N,N-bis(4,4-diphenyl-3-butenyl)-；2,6-dibromo-N,N-bis(4,4-diphenylbut-3-enyl)aniline
• CAS: 649559-72-8
• 化学式: C₃₈H₃₃Br₂N
• 分子量: 663.495
• InChiKey: OSPWCHLSLJBISE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.4
• 重原子数：
  41
• 可旋转键数：
  11
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  diphenylmethylenecyclopropene 、 2,6-二溴苯胺 在 tin(II) trifluoromethanesulfonate 、 二氧化碳 作用下， 85.0 ℃ 、10.0 MPa 条件下， 反应 24.0h， 以81%的产率得到[N,N-di-(4,4-diphenylbut-3-enyl)-2,6-(dibromo)]aniline
  参考文献：
  名称：

  Lewis acids catalyzed ring-opening reactions of methylenecyclopropanes and epoxides in supercritical carbon dioxide or modified supercritical carbon dioxide with perfluorocarbon

  摘要：

  The reactions of methylenecyclopropanes (MCPs) and epoxides with alcohols and aromatic amines can be carried out in supercritical carbon dioxide (scCO(2)) or modified scCO(2) with perfluorocarbon which offer a way to synthesize various alcohols, amino-alcohols, homoallylic ethers, and amines under an environmentally benign condition. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(03)00083-6

文献信息

• Lewis acids catalyzed ring-opening reactions of methylenecyclopropanes and epoxides in supercritical carbon dioxide or modified supercritical carbon dioxide with perfluorocarbon
  作者：Min Shi、Yu Chen

  DOI：10.1016/s0022-1139(03)00083-6

  日期：2003.8

  The reactions of methylenecyclopropanes (MCPs) and epoxides with alcohols and aromatic amines can be carried out in supercritical carbon dioxide (scCO(2)) or modified scCO(2) with perfluorocarbon which offer a way to synthesize various alcohols, amino-alcohols, homoallylic ethers, and amines under an environmentally benign condition. (C) 2003 Elsevier Science B.V. All rights reserved.