Trimethyl-[oxo(phenyl)silyl]oxysilane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Trimethyl-[oxo(phenyl)silyl]oxysilane
• 英文别名: trimethyl-[oxo(phenyl)silyl]oxysilane
• 化学式: C₉H₁₄O₂Si₂
• 分子量: 210.38
• InChiKey: FVZQVDSHLXEGOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.66
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三甲基氯硅烷 、 alkaline earth salt of/the/ methylsulfuric acid 以 苯 为溶剂， 反应 0.33h， 生成 Trimethyl-[oxo(phenyl)silyl]oxysilane
  参考文献：
  名称：

  A new approach to the synthesis of cage-like metallasiloxanes

  摘要：

  A new approach to the synthesis of cage-like metallasiloxanes has been proposed. Copper-containing metallasiloxanes {Na-4[(RSiO2)(12)Cu-4](R'OH)(n)} (la, R = Ph, R' = n-Bu; Ib, R = Ph, R' = Me; 2, R = Vi, R' = Me) were prepared from Ph-Si(OR)(3).(R = n-BU, Me) and ViSi(OMe)(3), respectively. Compound 2 was characterized by X-ray single structure analysis. The structures of compounds la,b were deduced by their follow up reactions with Me3SiCl. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00825-0