bis(anilinomethyl)phenylphosphine | 72936-83-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(anilinomethyl)phenylphosphine
• 英文别名: di(phenylaminomethyl)phenylphosphine；bis(phenylaminomethyl)phenylphosphine；Di-(anilinomethyl)-phenylphosphin；N-[[anilinomethyl(phenyl)phosphanyl]methyl]aniline
• CAS: 72936-83-5
• 化学式: C₂₀H₂₁N₂P
• 分子量: 320.374
• InChiKey: KMAFUQNJOJDUDX-UHFFFAOYSA-N

物化性质

• 熔点：
  91-92 °C(Solv: acetonitrile (75-05-8))
• 沸点：
  533.0±35.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis(anilinomethyl)phenylphosphine 、 双(羟甲基)苯膦 以 乙腈 为溶剂， 以81%的产率得到1,3,5,7-tetraphenyl-1,5-diaza-3,7-diphosphacyclooctane
  参考文献：
  名称：

  1.5-Diaza-3.7-diphospha-cyclooctane

  摘要：

  DOI：

  10.1016/s0040-4039(00)92732-1
• 作为产物：
  描述：

  2,5-diphenyl-1,3,2,5-dioxaborataphosphorinane 以62%的产率得到
  参考文献：
  名称：

  ARBUZOV B. A.; ERASTOV O. A.; NIKONOV G. N., IZV. AN CCCP CEP. XIM., 1980, HO 4, 952-954

  摘要：

  DOI：

文献信息

• 1.2-Diaza-4-phospha-cyclopentane - 1.5-diaza-3.7-diphosphabicyclo-[3.3.0]octane N. N′-[bisphosphinomethylen]-N .N′-dimethylhydrazine 1.3-diaza-5-phospha-cyclohexane
  作者：G. Märkl、G.Yu Jin

  DOI：10.1016/0040-4039(81)80062-7

  日期：1981.1

  N.N′-Dialkylhydrazines and hydrazine itself react with hydroxymethylphosphines to give the title compounds, bis(anilinomethylen)-phosphines form the cyclohexane-derivatives with formaldehyde.

  NN'-二烷基肼和肼本身与羟甲基膦反应生成标题化合物，双（苯胺基亚甲基）膦与甲醛形成环己烷衍生物。
• Alkylation of aminomethyl derivatives of primary phosphines
  作者：O. A. Erastov、G. N. Nikonov、B. A. Arbuzov

  DOI：10.1007/bf00953167

  日期：1983.6
• Synthesis and structure of 1,5-diaza-3,7-diphosphacyclooctanes
  作者：B. A. Arbuzov、O. A. Erastov、G. N. Nikonov、R. P. Arshinova、I. P. Romanova、R. A. Kadyrov

  DOI：10.1007/bf00954289

  日期：1983.8
• Synthesis and properties of triethylammonium 2,2,5-triphenyl-1,3,2,5-dioxaborataphosphorinane
  作者：G. N. Nikonov、A. A. Karasik、B. A. Arbuzov

  DOI：10.1007/bf00866594

  日期：1992.6

  The reaction of bis(hydroxymethyl)phenylphosphine with isobutyl diphenylborate in the presence of triethylamine leads to the formation of triethylammonium 2,2,5-triphenyl-1,3,2,5-dioxaborataphosphorinane (1). The reaction of compound 1 with electrophilic reagents (O, S, Se, CH2O, RHal) leads to quaternization of the phosphorus atom, giving the corresponding phosphine oxides, sulfides, and selenides and PB-containing betaines. In the reactions of compound 1 with amines aminoniethylphosphines of the diazaphosphorinane and diazadiphosphacyclooctane series are formed. Ammonium 1,3,2,5-dioxaborataphosphorinanes dissociate in solutions and enter into ion exchange with phosphonium iodides, leading to phosphonium 1,3,2,5-dioxaborataphosphorinanes. The latter. in the case of the aminomethylphosphonium cation, undergo intramolecular rearrangement with the formation of PB-containing betaines and aminomethylphosphines.
• Antimicrobial activity of certain derivatives of phosphine and phenylphosphine
  作者：Zh. V. Molodykh、N. N. Anisimova、M. A. Kudrina、M. S. Loseva、G. N. Nikonov、O. A. Erastov

  DOI：10.1007/bf00765168

  日期：1983.3