N-methylacetoacetanilide semicarbazone | 355007-86-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-methylacetoacetanilide semicarbazone
• 英文别名: 3-(carbamoylhydrazinylidene)-N-methyl-N-phenylbutanamide
• CAS: 355007-86-2
• 化学式: C₁₂H₁₆N₄O₂
• 分子量: 248.285
• InChiKey: IGWNCAFBNSGNMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  87.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-methylacetoacetanilide semicarbazone 、 三氯化铁 以 甲醇 、 乙醇 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF METAL COMPLEXES OFN-METHYL- ANDN-ETHYLACETOACETANILIDE SEMICARBAZONES

  摘要：

  Fourteen new metal complexes of N-methyl-(H2L) and N-ethylacetoacetanilide (H2L ') semicarbazones, having the general formulae [M(LH)(2)], [ML/L ' (H2O)], [ML/L ' (H2O)(3)], and [FeLCl(H2O)](2), where M = Mn(II), Co(II), NI(II), Cu(II), Zn(II), Cd(II) or Hg(II), LH = tridentate monoanion of H2L and L/L ' = tridentate dianion of H2L or H2L ', were synthesized. Characterization of these compounds was mainly done by chemical analyses, molar conductance, magnetic susceptibility and electronic, infrared and H-1 NMR spectral studies. Thermogravimetric studies of Mn(II), Co(II), Ni(LI), and Cu(II) complexes of N-methylacetoacetanilide semicarbazone were also carried out.[GRAPHICS]

  DOI：

  10.1081/sim-100001931