4-[4-[8-(2-methylpropyl)-11-[4-[4-(N-phenylanilino)phenyl]phenyl]-3,7,8,9,13-pentazaheptacyclo[13.11.1.02,14.04,12.06,10.016,21.023,27]heptacosa-1(26),2,4,6,9,11,13,15(27),16,18,20,22,24-tridecaen-5-yl]phenyl]-N,N-diphenylaniline

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[4-[8-(2-methylpropyl)-11-[4-[4-(N-phenylanilino)phenyl]phenyl]-3,7,8,9,13-pentazaheptacyclo[13.11.1.02,14.04,12.06,10.016,21.023,27]heptacosa-1(26),2,4,6,9,11,13,15(27),16,18,20,22,24-tridecaen-5-yl]phenyl]-N,N-diphenylaniline
• 化学式: C₇₄H₅₃N₇
• 分子量: 1040.28
• InChiKey: MMJDXFZCYOHUOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.1
• 重原子数：
  81
• 可旋转键数：
  12
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  63
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,2-苯并苊醌 、 2-(2-methylpropyl)-4,7-bis[4-[4-(N-phenylanilino)phenyl]phenyl]benzotriazole-5,6-diamine 在 溶剂黄146 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 生成 4-[4-[8-(2-methylpropyl)-11-[4-[4-(N-phenylanilino)phenyl]phenyl]-3,7,8,9,13-pentazaheptacyclo[13.11.1.02,14.04,12.06,10.016,21.023,27]heptacosa-1(26),2,4,6,9,11,13,15(27),16,18,20,22,24-tridecaen-5-yl]phenyl]-N,N-diphenylaniline
  参考文献：
  名称：

  波長変換のための高蛍光性光安定性発色団

  摘要：

  This invention provides a highly fluorescent material containing a single (i=0) or a series of (i=1, 2, etc.) complex ring systems. This chromophore is particularly useful for the absorption and emission of photons in the visible light wavelength range and near-infrared wavelength range. This chromophore, highly luminescent with photostability, has various applications, such as in wavelength conversion films. Wavelength conversion films have the potential to significantly improve the concentration efficiency of solar light in photovoltaic devices or solar cells.

  公开号：

  JP2016509621A

文献信息

• HIGHLY-FLUORESCENT AND PHOTO-STABLE CHROMOPHORES FOR WAVELENGTH CONVERSION
  申请人：RACHWAL Mila

  公开号：US20150340519A1

  公开（公告）日：2015-11-26

  The invention provides highly fluorescent materials comprising a single (i=0) or a series (i=1, 2, etc.) of heterocyclic systems. The chromophores are particularly useful for absorption and emission of photons in the visible and near infrared wavelength range. The photo-stable highly luminescent chromophores are useful in various applications, including in wavelength conversion films. Wavelength conversion films have the potential to significantly enhance the solar harvesting efficiency of photovoltaic or solar cell devices.

  本发明提供了高度荧光材料，包括单个（i = 0）或一系列（i = 1、2等）杂环系统。这些色团特别适用于吸收和发射可见光和近红外波长范围内的光子。这些光稳定的高亮度色团在各种应用中非常有用，包括在波长转换膜中使用。波长转换膜有潜力显著提高光伏或太阳能电池器件的太阳能收集效率。
• Highly-fluorescent and photo-stable chromophores for wavelength conversion
  申请人：NITTO DENKO CORPORATION

  公开号：US10461201B2

  公开（公告）日：2019-10-29

  The invention provides highly fluorescent materials comprising a heterocyclic systems represented by formula (I): wherein i is 0 and Het is wherein X is selected from the group consisting of —N(A0)-. The chromophores are particularly useful for absorption and emission of photons in the visible and near infrared wavelength range. The photo-stable highly luminescent chromophores are useful in various applications, including in wavelength conversion films. Wavelength conversion films have the potential to significantly enhance the solar harvesting efficiency of photovoltaic or solar cell devices.

  本发明提供了由式 (I) 所代表的杂环系统组成的高荧光材料： 其中 i 为 0，Het 为 其中 X 选自 -N(A0)-。这些发色团特别适用于吸收和发射可见光和近红外波长范围内的光子。光稳定的高发光发色团可用于各种应用，包括波长转换薄膜。波长转换薄膜有可能显著提高光伏或太阳能电池装置的太阳能收集效率。
• US9960294B2
  申请人：——

  公开号：US9960294B2

  公开（公告）日：2018-05-01
• [EN] HIGHLY-FLUORESCENT AND PHOTO-STABLE CHROMOPHORES FOR WAVELENGTH CONVERSION<br/>[FR] CHROMOPHORES HAUTEMENT FLUORESCENTS ET PHOTO-STABLES POUR LA CONVERSION DE LONGUEUR D'ONDE
  申请人：NITTO DENKO CORP

  公开号：WO2014107606A2

  公开（公告）日：2014-07-10

  The invention provides highly fluorescent materials comprising a single (i = 0) or a series (i = 1, 2, etc.) of heterocyclic systems. The chromophores are particularly useful for absorption and emission of photons in the visible and near infrared wavelength range. The photo-stable highly luminescent chromophores are useful in various applications, including in wavelength conversion films. Wavelength conversion films have the potential to significantly enhance the solar harvesting efficiency of photovoltaic or solar cell devices.
• 波長変換のための高蛍光性光安定性発色団
  申请人：日東電工株式会社

  公开号：JP2016509621A

  公开（公告）日：2016-03-31

  本発明は、単一（ｉ＝０）または一連の（ｉ＝１、２など）の複素環式の系を含む高度に蛍光性の物質を提供する。この発色団は、可視光波長範囲および近赤外線波長範囲の光子の吸収および放射に特に有用である。光安定性で高度に発光性のこの発色団は種々の用途に、例えば波長変換膜に有用である。波長変換膜は、光起電力素子または太陽電池素子の太陽光の集光効率を有意に向上させる可能性を有する。

  This invention provides a highly fluorescent material containing a single (i=0) or a series of (i=1, 2, etc.) complex ring systems. This chromophore is particularly useful for the absorption and emission of photons in the visible light wavelength range and near-infrared wavelength range. This chromophore, highly luminescent with photostability, has various applications, such as in wavelength conversion films. Wavelength conversion films have the potential to significantly improve the concentration efficiency of solar light in photovoltaic devices or solar cells.