Allyl-triphenylphosphoniumiodid | 21433-41-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Allyl-triphenylphosphoniumiodid
• 英文别名: Triphenyl(prop-2-enyl)phosphanium;iodide
• CAS: 21433-41-0
• 化学式: C₂₁H₂₀P*I
• 分子量: 430.268
• InChiKey: RXMKUGPPBPXXAV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.17
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Allyl-triphenylphosphoniumiodid 在 三乙胺 作用下， 以 乙腈 为溶剂， 反应 24.0h， 以85%的产率得到1-Propenyltriphenylphosphonium iodide
  参考文献：
  名称：

  Reaction of allyltriphenylphosphonium iodide with amines

  摘要：

  DOI：

  10.1007/bf00955455
• 作为产物：
  描述：

  π-allyltricarbonyliron iodide 、 三苯基膦 以31%的产率得到Allyl-triphenylphosphoniumiodid
  参考文献：
  名称：

  关于π铁-烯丙基铁配合物的结构和化学的一些看法

  摘要：

  研究了烯丙基羰基铁配合物C 3 H 5 Fe（CO）3 X的结构和一些反应。结果表明，它们的衰变是通过或不向烯丙基中添加不断发展的一氧化碳而进行的。二甲基亚砜没有引起π-σ-重排，但完全取代了烯丙基配体。

  DOI：

  10.1016/s0022-328x(00)87678-0

文献信息

• Some views on the structure and chemistry of iron π-allyl complexes
  作者：A.N. Nesmeyanov、I.I. Kritskaya

  DOI：10.1016/s0022-328x(00)87678-0

  日期：1968.10

  The structure and some reactions of allylcarbonyliron complexes, C3H5Fe(CO)3X, have been studied. Their decay was shown to proceed through, or without, addition of evolving CO, to the allyl radical. Dimethyl sulfoxide caused no π-σ- rearrangement but it completely replaced the allyl ligand.

  研究了烯丙基羰基铁配合物C 3 H 5 Fe（CO）3 X的结构和一些反应。结果表明，它们的衰变是通过或不向烯丙基中添加不断发展的一氧化碳而进行的。二甲基亚砜没有引起π-σ-重排，但完全取代了烯丙基配体。
• beta-DIHYDROFURAN DERIVING COMPOUND, METHOD FOR PRODUCING beta-DIHYDROFURAN DERIVING COMPOUND OR beta-TETRAHYDROFURAN DERIVING COMPOUND, beta-GLYCOSIDE COMPOUND, METHOD FOR PRODUCING beta GLYCOSIDE COMPOUND, AND METHOD FOR PRODUCING 4'-ETHYNYL D4T AND ANALOGUE COMPOUNDS THEREOF
  申请人：Iriyama Yusuke

  公开号：US20120322995A1

  公开（公告）日：2012-12-20

  The invention provides a process for producing a β-dihydrofuran derivative represented by formula (1) or a β-tetrahydrofuran derivative represented by formula (4), characterized in that the process includes causing a dialkyl dicarbonate, a diaralkyl dicarbonate, or a halide to act on a diol compound represented by formula (2) or (3). The invention also provides a process for producing 4′-ethynyl-2′,3′-didehydro-3′-deoxythymidine or an analog thereof, the process including glycosylation and deprotection.

  该发明提供了一种生产由式（1）表示的β-二氢呋喃衍生物或由式（4）表示的β-四氢呋喃衍生物的过程，其特征在于该过程包括使二烷基二碳酸酯、二芳基二碳酸酯或卤化物作用于由式（2）或（3）表示的二醇化合物。该发明还提供了一种生产4'-乙炔基-2',3'-二去氢-3'-脱氧胸苷或其类似物的过程，包括糖基化和去保护。
• Process for producing indole compound
  申请人：Sakurai Yasuhiro

  公开号：US20070083053A1

  公开（公告）日：2007-04-12

  There is provided a novel process for producing an indole derivative which comprises cyclizing 2-nitrobenzylcarbony compound in the presence of a catalyst comprising a Group VIII metal of the Periodic Table, characterized by conducting the cyclization in a gas atmosphere containing carbon monoxide. The process enables an indole compound to be selectively produced in a high yield from 2-nitrobenzylcarbonyl compound, and hardly yields an indoline compound as a reduction by-product that has been a problem in the catalytic hydrogenation method employing a noble metal catalyst. The indole derivative produced by the present process is useful for various fine chemical intermediates including compounds and physiologically active substances such as pharmaceuticals and agrochemicals.

  提供了一种生产吲哚衍生物的新方法，包括在存在周期表第VIII族金属的催化剂的情况下，使2-硝基苄酰化合物环化，其特征在于在含有一氧化碳的气氛中进行环化。该方法使得可以从2-硝基苄酰化合物中选择性地高产率地生产吲哚化合物，并且几乎不产生吲哚啉化合物作为催化氢化方法中使用贵金属催化剂时的还原副产物，这一直是一个问题。由本方法生产的吲哚衍生物可用于各种精细化学中间体，包括药物和农药等化合物和生理活性物质。
• [EN] A PROCESS FOR THE SYNTHESIS OF AMINE ETHERS<br/>[FR] SYNTHESE D'ETHERS AMINES
  申请人：CIBA SC HOLDING AG

  公开号：WO2005090307A1

  公开（公告）日：2005-09-29

  A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C5-C18alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.

  一种制备立体位阻胺醚的方法，包括在有机过氧化物存在的情况下，将相应的立体位阻胺氧化物与C5-C18烯烃反应，可选地对所得产品及其混合物进行氢化处理，并将其用作稳定剂和阻燃剂。
• Cathodic electrocoating composition containing morpholine dione blocked polyisocyanate crosslinking agent
  申请人：——

  公开号：US20040003995A1

  公开（公告）日：2004-01-08

  An improved aqueous cathodic electrocoating composition having a binder of an epoxy-amine adduct and a polyisocyanate crosslinking agent; wherein the improvement is the use of a polyisocyanate crosslinking agent having at least one crosslinkable morpholine dione group per molecule. Electrodeposited finishes are formed that have reduced volatile emissions and film weight loss when heated to cure.

  一种改进的水性阴极电泳涂料配方，其粘合剂为环氧胺加合物和聚异氰酸酯交联剂；其中改进的是使用至少每个分子具有一个可交联吗啉二酮基团的聚异氰酸酯交联剂。电泳涂层在加热固化时，具有较低的挥发性排放和膜重量损失，形成电泳涂层。