5-苯基己-1-烯-2-基苯 | 32375-29-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 5-苯基己-1-烯-2-基苯
• 英文名称: 2,5-Diphenyl-hexen-(1)
• 英文别名: 2,5-Diphenyl-1-hexene；5-phenylhex-1-en-2-ylbenzene
• CAS: 32375-29-4
• 化学式: C₁₈H₂₀
• 分子量: 236.357
• InChiKey: MGHAVLCKKYUDMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2902909090

反应信息

• 作为产物：
  描述：

  4-苯基戊酸 在 lithium hydride 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 8.0h， 生成 5-苯基己-1-烯-2-基苯
  参考文献：
  名称：

  Charge distribution between formally identical fragments: The McLafferty rearrangement

  摘要：

  AbstractThe McLafferty rearrangement for 2,5‐diphenyl‐1‐hexene and its deuterium labelled analogues has been investigated. The α‐methylstyrene fragments originating from different parts of the molecular ion retain the charge with equal probability and afford identical metastable spectra. The geometry of the transition state is discussed.

  DOI：

  10.1002/oms.1210150105

文献信息

• Vinyl polymerization, 314 Polymerization of vinyl monomers photosensitized by 1,4‐bis(pentamethylene)‐2‐tetrazene
  作者：Kazuo Sugiyama、Tadao Nakaya、Minoru Imoto

  DOI：10.1002/macp.1974.021750511

  日期：1974.5

  The photopolymerization of vinyl monomers can be sensitized by 1,4‐bis(pentamethylene)‐2‐tetrazene (1). The kinetics of the photopolymerization was investigated in the case of styrene (St). The rate of polymerization was found to be proportional to the one half power of the concentration of 1 and to the first power of the concentration of St. A plausible mechanism proposed for the overall reaction is discussed in the light of the experimental results.

  摘要 1,4-双(五亚甲基)-2-四氮烯(1)可敏化乙烯基单体的光聚合反应。研究了苯乙烯（St）的光聚合动力学。聚合速率与 1 浓度的二分之一和 St 浓度的一倍成正比。
• 240. Some reactions of the dimethylamino radical, ·NMe₂
  作者：B. R. Cowley、William A. Waters

  DOI：10.1039/jr9610001228

  日期：——
• Charge distribution between formally identical fragments: The McLafferty rearrangement
  作者：F. Tureček、V. Hanuš

  DOI：10.1002/oms.1210150105

  日期：1980.1

  AbstractThe McLafferty rearrangement for 2,5‐diphenyl‐1‐hexene and its deuterium labelled analogues has been investigated. The α‐methylstyrene fragments originating from different parts of the molecular ion retain the charge with equal probability and afford identical metastable spectra. The geometry of the transition state is discussed.