2-methyl-4-phenylhexanoic acid | 132858-55-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-methyl-4-phenylhexanoic acid
• 英文别名: 2-Methyl-4-phenyl-hexansaeure
• CAS: 132858-55-0
• 化学式: C₁₃H₁₈O₂
• 分子量: 206.285
• InChiKey: ADLMQKUCLCUQKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methyl-4-phenylhexanoic acid 在 PPA 作用下， 以 乙醚 为溶剂， 生成 4-Ethyl-1,2,3,4-tetrahydro-1-hydroxy-1,2-dimethyl-naphthalin
  参考文献：
  名称：

  448.在芳构化反应中消除非角烷基。第四部分

  摘要：

  DOI：

  10.1039/jr9600002230
• 作为产物：
  描述：

  2-甲基-4-氧-4-苯基丁酸 在 镍 氢气 作用下， 以 甲醇 、 乙醚 为溶剂， 生成 2-methyl-4-phenylhexanoic acid
  参考文献：
  名称：

  448.在芳构化反应中消除非角烷基。第四部分

  摘要：

  DOI：

  10.1039/jr9600002230

文献信息

• Mechanistic Investigations of the Pd‐Catalyzed Hydrogenolysis of Ketene Heterodimer β‐Lactones
  作者：Manashi Panda、Mukulesh Mondal、Shi Chen、Ahmad A. Ibrahim、Dylan J. Twardy、Nessan J. Kerrigan

  DOI：10.1002/ejoc.202000976

  日期：2020.9.22

  Catalytic hydrogenolysis of the Z‐isomer of a series of aryl‐substituted ketene heterodimers facilitated access to deoxypropionate derivatives, favoring the anti‐isomer, and with excellent transfer of chirality. Anti‐β‐elimination and an anti‐selective hydrogenation of an E‐olefin intermediate are proposed to be key steps.

  一系列芳基取代的乙烯酮异二聚体的Z-异构体的催化氢解作用有利于获得脱氧丙酸酯衍生物，有利于抗异构体，并具有出色的手性转移能力。反-β-消除和抗一的-选择性加氢Ë烯烃中间提出是关键步骤。
• Stable Pigment Dispersions
  申请人：Louwet Frank

  公开号：US20080167411A1

  公开（公告）日：2008-07-10

  A pigment dispersion includes a pigment with at least one carboxylic acid group and a block copolymer including aromatic monomers having at least one carboxylic acid group or a salt thereof and aromatic monomers having at least one sulfonic acid group or a salt thereof. The pigment dispersions can be used for manufacturing inkjet inks and for the coating of colored layers.

  这段话的翻译如下： 一种颜料分散液包含至少一个羧酸基团的颜料和一个块状共聚物，该块状共聚物包括至少一个羧酸基团或其盐的芳香单体和至少一个磺酸基团或其盐的芳香单体。这种颜料分散液可用于制造喷墨墨水和涂覆彩色层。
• Hoshi, Nobuto; Sato, Kazuhiro; Uda, Hisashi, Journal of Chemical Research, Miniprint, 1984, # 12, p. 3501 - 3596
  作者：Hoshi, Nobuto、Sato, Kazuhiro、Uda, Hisashi、Hagiwara, Hisahiro

  DOI：——

  日期：——
• Asymmetric Synthesis of Deoxypropionate Derivatives via Catalytic Hydrogenolysis of Enantioenriched <i>Z</i>-Ketene Heterodimers
  作者：Shi Chen、Ahmad A. Ibrahim、Mukulesh Mondal、Anthony J. Magee、Adam J. Cruz、Kraig A. Wheeler、Nessan J. Kerrigan

  DOI：10.1021/acs.orglett.5b01391

  日期：2015.7.2

  A diagterosetective approach to deoxypropionate derivatives through Pd/C-catalyted hydrogenolysis of enantio enriched ketene heterodimers is described. Catalytic hydrogenolysis of the Z-isomer of ketene heterodimers facilitates access to, anti-deoxypropionate derivatives (10 examples With dr 7:1 to >20:1). Transfer of chirality from the Z-ketene heterodimer to an acid product was good to excellent in most as (78-99% ee for 12 examples).
• POLYMER RESIN BINDER, PIGMENT DISPERSIONS, AND INK-JET INK FOR COLOR FILTER
  申请人：KEE In-seo

  公开号：US20070155856A1

  公开（公告）日：2007-07-05

  Provided is a polymer resin binder included in an inkjet ink for a color filter which is manufactured by polymerizing multiple types of functional monomer including: a monomer having an affinity for the pigment; a monomer having high mechanical strength; or a monomer having an affinity for a solvent, and contains an amine based organic material. Accordingly, the polymer resin, binder for forming inkjet ink for a color filter can improve a dispersion property and dispersion stability and an ejection property and ejection stability of inkjet ink.