(6-Me-Py-3-O)2PN(Me)N(Me)P(6-Me-Py-3-O)2 | 1227927-91-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (6-Me-Py-3-O)2PN(Me)N(Me)P(6-Me-Py-3-O)2
• 英文别名: 1,2-Bis[bis[(6-methylpyridin-3-yl)oxy]phosphanyl]-1,2-dimethylhydrazine；1,2-bis[bis[(6-methylpyridin-3-yl)oxy]phosphanyl]-1,2-dimethylhydrazine
• CAS: 1227927-91-4
• 化学式: C₂₆H₃₀N₆O₄P₂
• 分子量: 552.51
• InChiKey: VLOCZOWTAHXJLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  38
• 可旋转键数：
  11
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  95
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  dichlorobis(dimethylsulfide)platinum(II) 、 (6-Me-Py-3-O)2PN(Me)N(Me)P(6-Me-Py-3-O)2 以 二氯甲烷 为溶剂， 以76%的产率得到cis-Pt((6-Me-Py-3-O)2PN(Me)N(Me)(6-Me-Py-3-O)2)Cl2
  参考文献：
  名称：

  Syntheses and crystal structures of a series of palladium(II) and platinum(II) complexes bearing new hydrazine-based bisphosphinite ligands equipped with pyridyl arms

  摘要：

  This paper reports the synthesis of the hydrazine-based bisphosphinito ligands (RO)(2)PN(Me)N(Me)P(OR)(2) (R = 2-hydroxy-6-methyl-pyridyl or 3-hydroxy-6-methyl-pyridyl) and their palladium and platinum complexes whose structures were unequivocally determined by X-ray crystallography. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.02.011

文献信息

• Syntheses and crystal structures of a series of palladium(II) and platinum(II) complexes bearing new hydrazine-based bisphosphinite ligands equipped with pyridyl arms
  作者：Douglas J. Schaffer、Andrei S. Batsanov、Craig M. Jensen、Satoshi Takara

  DOI：10.1016/j.poly.2010.02.011

  日期：2010.4

  This paper reports the synthesis of the hydrazine-based bisphosphinito ligands (RO)(2)PN(Me)N(Me)P(OR)(2) (R = 2-hydroxy-6-methyl-pyridyl or 3-hydroxy-6-methyl-pyridyl) and their palladium and platinum complexes whose structures were unequivocally determined by X-ray crystallography. (C) 2010 Elsevier Ltd. All rights reserved.