Bis(benzylidene)acenaphthene | 143493-94-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: Bis(benzylidene)acenaphthene
• 英文别名: (1E,2Z)-1,2-dibenzylideneacenaphthylene
• CAS: 143493-94-1
• 化学式: C₂₆H₁₈
• 分子量: 330.429
• InChiKey: DXECKAFICITZEV-KGOJTIBSSA-N

物化性质

• 沸点：
  554.1±50.0 °C(Predicted)
• 密度：
  1?+-.0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Bis(benzylidene)acenaphthene 在 四丁基高氯酸铵 作用下， 以 乙腈 为溶剂， 生成 7-Phenyl-benzofluoranthen
  参考文献：
  名称：

  Spectrofluorimetric hydrodynamic voltammetry: theory and practice

  摘要：

  A flow cell for simultaneous spectrofluorimetric voltammetry is described. The relevant theory is presented and the sensitivity of the technique evaluated. Experiments involving (a) the photooxidation of bis(benzylidene)acenaphthene and (b) the oxidation of p-phenylenediamine are shown to be in good agreement with theory. It is demonstrated that the technique can reveal the existence of trace quantities of electrode reaction intermediates and products and show previously unsuspected species participating in the electrode process.

  DOI：

  10.1021/j100199a061

文献信息

• Spectrofluorimetric hydrodynamic voltammetry: theory and practice
  作者：R. G. Compton、A. C. Fisher、R. G. Wellington、J. Winkler

  DOI：10.1021/j100199a061

  日期：1992.10

  A flow cell for simultaneous spectrofluorimetric voltammetry is described. The relevant theory is presented and the sensitivity of the technique evaluated. Experiments involving (a) the photooxidation of bis(benzylidene)acenaphthene and (b) the oxidation of p-phenylenediamine are shown to be in good agreement with theory. It is demonstrated that the technique can reveal the existence of trace quantities of electrode reaction intermediates and products and show previously unsuspected species participating in the electrode process.
• Compton, Richard G.; Fisher, Adrian C.; Wellington, Robert G., Journal of the Chemical Society. Perkin transactions II, 1992, # 8, p. 1359 - 1362
  作者：Compton, Richard G.、Fisher, Adrian C.、Wellington, Robert G.、Winkler, Jacob、Bethell, Donald、Lederer, Pavel

  DOI：——

  日期：——