α-Methylamino-benzal-phenylhydrazin | 22080-72-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: α-Methylamino-benzal-phenylhydrazin
• 英文别名: N-anilino-N'-methylbenzenecarboximidamide
• CAS: 22080-72-4
• 化学式: C₁₄H₁₅N₃
• 分子量: 225.293
• InChiKey: NFJMARSXFCOQPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  36.4
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  二氯二苯甲烷 、 α-Methylamino-benzal-phenylhydrazin 在 barium dihydroxide 、 barium(II) oxide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以72%的产率得到4,5-dihydro-4-methyl-1,3,5,5-tetraphenyl-1H-1,2,4-triazole
  参考文献：
  名称：

  2,5-Dihydro-1H-1,2,4-triazol-2-yl radicals: Syntheses and properties

  摘要：

  A range of 2,5-dihydro-1H-1,2,4-triazol-2-yl radicals 2b-p has been prepared by dehydrogenation of the corresponding 4,5-dihydro-1H-1,2,4-triazoles 5b-p which have been synthesized using various methods. EPR, ENDOR and NMR studies have led to a complete analysis and full assignment of all hyperfine coupling constants. The pi-SOMO, having a node at the C(3) methine carbon, is mainly confined to the nitrogens of the five-membered ring, particularly to those of the hydrazyl moiety.

  DOI：

  10.1016/0040-4020(95)00730-v
• 作为产物：
  描述：

  N-苯基苯羰基亚肼酰氯 、 甲胺 生成 α-Methylamino-benzal-phenylhydrazin
  参考文献：
  名称：

  Fusco,R.; Dalla Croce,P., Gazzetta Chimica Italiana, 1969, vol. 99, p. 69 - 85

  摘要：

  DOI：

文献信息

• Fusco,R.; Dalla Croce,P., Gazzetta Chimica Italiana, 1969, vol. 99, p. 69 - 85
  作者：Fusco,R.、Dalla Croce,P.

  DOI：——

  日期：——
• Combined Formose/Transfer Hydrogenation Process for Ethylene Glycol Synthesis
  申请人：Grubbs Robert H.

  公开号：US20100305368A1

  公开（公告）日：2010-12-02

  The present invention provides a process for the production of a glycol via tandem self condensation of formaldehyde via formoin condensation and transfer hydrogenation of the reaction products of the formoin condensation. In some aspects, synthetic processes of the present invention utilize a combination of a N-heterocyclic carbene catalyst and a transition metal hydrogen-transfer catalyst providing enhanced selectivity and increased yields for the production of ethylene glycol relative to conventional synthetic approaches based on formoin condensation.
• 2,5-Dihydro-1H-1,2,4-triazol-2-yl radicals: Syntheses and properties
  作者：Franz A. Neugebauer、Hans Fischer

  DOI：10.1016/0040-4020(95)00730-v

  日期：1995.11

  A range of 2,5-dihydro-1H-1,2,4-triazol-2-yl radicals 2b-p has been prepared by dehydrogenation of the corresponding 4,5-dihydro-1H-1,2,4-triazoles 5b-p which have been synthesized using various methods. EPR, ENDOR and NMR studies have led to a complete analysis and full assignment of all hyperfine coupling constants. The pi-SOMO, having a node at the C(3) methine carbon, is mainly confined to the nitrogens of the five-membered ring, particularly to those of the hydrazyl moiety.
• Perronnet,J.; Girault,P., Bulletin de la Societe Chimique de France, 1973, p. 2843 - 2847
  作者：Perronnet,J.、Girault,P.

  DOI：——

  日期：——