6-对甲基苯胺羰基-2-吡啶羧酸 | 556010-96-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 6-对甲基苯胺羰基-2-吡啶羧酸
• 英文名称: 6-paramethylaniline carbonyl 2-pyridine carboxylic acid
• 英文别名: 6-[(4-Methylphenyl)carbamoyl]pyridine-2-carboxylic acid
• CAS: 556010-96-9
• 化学式: C₁₄H₁₂N₂O₃
• mdl: MFCD12585017
• 分子量: 256.261
• InChiKey: SXBYFYTWVFBFPS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.071
• 拓扑面积：
  79.3
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6-对甲基苯胺羰基-2-吡啶羧酸 、 氯化铕(III) 以 乙醇 、 水 为溶剂， 生成 tris(6-paramethylaniline carbonyl 2-pyridine carboxylato)europium(III)
  参考文献：
  名称：

  Synthesis and luminescence of a novel conjugated europium complex with 6-paramethylaniline carbonyl 2-pyridine carboxylate

  摘要：

  A novel organic ligand, 6-paramethylaniline carbonyl 2-pyridine carboxylic acid (Hp-MAP), and the corresponding europium complex, tris(6-paramethylaniline carbonyl 2-pyridine carboxylato) europium(III) (Ealpha-p-MAP) have been designed and synthesized. The results showed that Eu-p-MAP was a conjugated complex, emitting remarkably strong red luminescence. The lifetimes of D-5(O) of Eu3+ in the complex were examined using time-resolved spectroscopic analysis; the lifetime values were 0.72+/-0.01 ms for 1.0 X 10(-5) mol l(-1) Eu(p-MAP)(3) ethanol solution and 1.16+/-0.01 ms for solid of Eu(p-MAP)(3), respectively. Thermogravimetric analysis showed the europium complex had good thermal stability. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0925-8388(02)01118-0