4,4'-dibromo-2,2'-dimethyl-1,1'-binaphthyl | 797035-61-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-dibromo-2,2'-dimethyl-1,1'-binaphthyl
• 英文别名: 4,4'-Dibromo-2,2'-dimethyl-1,1'-binaphthalene；4-bromo-1-(4-bromo-2-methylnaphthalen-1-yl)-2-methylnaphthalene
• CAS: 797035-61-1
• 化学式: C₂₂H₁₆Br₂
• 分子量: 440.177
• InChiKey: MQKQUWVPXLDMBX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  24
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  4-(1-萘基)苯硼酸 、 4,4'-dibromo-2,2'-dimethyl-1,1'-binaphthyl 在 四(三苯基膦)钯 甲基三辛基氯化铵 、 sodium carbonate 作用下， 以 甲苯 为溶剂， 反应 0.33h， 以38%的产率得到2-Methyl-1-[2-methyl-4-(4-naphthalen-1-ylphenyl)naphthalen-1-yl]-4-(4-naphthalen-1-ylphenyl)naphthalene
  参考文献：
  名称：

  [EN] ELECTROACTIVE COMPOUND AND COMPOSITION AND ELECTRONIC DEVICE MADE WITH THE COMPOSITION
  [FR] COMPOSÉ ÉLECTROACTIF ET COMPOSITION ET DISPOSITIF ÉLECTRONIQUE FABRIQUÉ AVEC LA COMPOSITION

  摘要：

  公开号：

  WO2012021315A3

文献信息

• N-type conjugated materials based on 2-vinyl-4,5-dicyanoimidazoles and their use in organic photovoltaics
  申请人：Sellinger Alan

  公开号：US20090032106A1

  公开（公告）日：2009-02-05

  There is provided novel n-type conjugated compounds based on 2-vinyl-4,5-dicyanoimidazole moieties conjugated via the vinyl group to an aromatic moiety. Also provided are thin films and photovoltaics comprising the novel compounds, as well as methods of synthesizing the compounds.

  提供了基于2-乙烯基-4,5-二氰基咪唑基团的新型n-型共轭化合物，通过乙烯基与芳香基团共轭连接。还提供了包含这些新型化合物的薄膜和光伏器件，以及合成这些化合物的方法。
• ELECTROLUMINESCENT POLYMERS AND USE THEREOF
  申请人：Büsing Arne

  公开号：US20100108989A1

  公开（公告）日：2010-05-06

  The present invention relates to polymers which contain novel structural units of the formula (1). The inventive materials exhibit better solubility and improved efficiency when used in a polymeric organic light-emitting diode.

  本发明涉及包含新颖结构单元（1）的聚合物。这种创新材料在聚合有机发光二极管中使用时表现出更好的溶解性和改善的效率。
• Electron-Accepting Conjugated Materials Based on 2-Vinyl-4,5-dicyanoimidazoles for Application in Organic Electronics
  作者：Richard Y. C. Shin、Prashant Sonar、Pei Sann Siew、Zhi-Kuan Chen、Alan Sellinger

  DOI：10.1021/jo802720m

  日期：2009.5.1

  We report the Heck coupling of 2-vinyl-4,5-dicyanoimidazole (vinazene) with selected di- and trihalo aromatics in an effort to prepare linear and branched electron-accepting conjugated materials for application in organic electronics. By selecting the suitable halo-aromatic moiety, it is possible to tune the HOMO-LUMO energy levels, absorption, and emission properties for a specific application. In this regard, materials with strong photoluminescence from blue -> green -> red are reported that may have potential application in organic light-emitting diodes (OLEDs). Furthermore, derivatives with strong absorption in the-visible spectrum, coupled with favorable HOMO-LUMO levels, have been used to prepare promising organic photovoltaic devices (OPVs) when combined with commercially available semiconducting donor polymers.
• ELEKTROLUMINESZIERENDE POLYMERE UND DEREN VERWENDUNG
  申请人：Merck Patent GmbH

  公开号：EP1831326B1

  公开（公告）日：2017-03-01
• US7906724B2
  申请人：——

  公开号：US7906724B2

  公开（公告）日：2011-03-15