Methyl 1,6-dimethylpyridin-1-ium-3-carboxylate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Methyl 1,6-dimethylpyridin-1-ium-3-carboxylate
• 化学式: C₉H₁₂NO₂
• 分子量: 166.2
• InChiKey: BJISBXNHQXQHPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  30.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5'-(dibutylamino)-2,2'-bithiophene-5-carboxaldehyde 、 Methyl 1,6-dimethylpyridin-1-ium-3-carboxylate 在 哌啶 作用下， 以 甲醇 为溶剂， 反应 6.0h， 生成
  参考文献：
  名称：

  Metal-free synthesis of bisthiophene-core donor acceptor organic photosensitizers for dye-sensitized solar cells

  摘要：

  Three novel donor-it-acceptor molecules with a bis-thiophene core have been synthesized through a simple and versatile metal-free synthetic procedure. Study of their optical and electrochemical properties, and a preliminary evaluation of their use as dyes in dye sensitized solar cells (DSSC) are presented. The proposed synthetic protocol results in a drastic reduction of the size and complexity of the sensitizer molecule, possibly enabling cost decrease by overall yield improvement and easy scalability. Particular attention has been paid to limit the environmental impact by reducing the number of synthetic steps and especially avoiding the use of organometallic reactions. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2015.03.100

文献信息

• DYE SENSITISED SOLAR CELL
  申请人：Tanabe Junichi

  公开号：US20120145238A1

  公开（公告）日：2012-06-14

  The present invention pertains to an electrode layer comprising a porous film made of oxide semiconductor fine particles sensitized with certain methin dyes. Moreover the present invention pertains to a photoelectric conversion device comprising said electrode layer, a dye sensitized solar cell comprising said photoelectric conversion device and to novel methin dyes.
• US8709299B2
  申请人：——

  公开号：US8709299B2

  公开（公告）日：2014-04-29