noladin ether | 22598-17-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: noladin ether
• 英文别名: 2-O-n-Propylglycerol；2-monopropyl glycerol；2-Propoxy-propan-diol-(1,3)；2-Propyloxy-1,3-dihydroxy-propan；2-propoxy-propane-1,3-diol；2-propoxy-1,3-propanediol；2-n-propylglycerol；2-propyl glycerol；2-Propoxypropane-1,3-diol
• CAS: 22598-17-0
• 化学式: C₆H₁₄O₃
• 分子量: 134.175
• InChiKey: WQQGNQADDWFKSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,3-双(苄氧基)-2-丙醇 、 alkaline earth salt of/the/ methylsulfuric acid 生成 noladin ether
  参考文献：
  名称：

  Berecoechea,J.; Anatol,J., Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1969, vol. 268, p. 434 - 437

  摘要：

  DOI：

文献信息

• Regioselective Ring‐Opening of Glycidol to Monoalkyl Glyceryl Ethers Promoted by an [OSSO]‐Fe ^III Triflate Complex
  作者：Francesco Della Monica、Maria Ricciardi、Antonio Proto、Raffaele Cucciniello、Carmine Capacchione

  DOI：10.1002/cssc.201901329

  日期：2019.8.8

  bis‐thioether‐di‐phenolate [OSSO]‐type ligand, was discovered to promote the ring‐opening of glycidol with alcohols under mild reaction conditions (0.05 mol % catalyst and 80 °C). The reaction proceeded with high activity (initial turnover frequency of 1680 h−1 for EtOH) and selectivity (>95 %) toward the formation of twelve monoalkyl glyceryl ethers (MAGEs) in a regioselective fashion (84–96 % yield of the non‐symmetric

  发现具有三硫醚醚-二酚盐[OSSO]型配体的三价铁三价铁配合物可在温和的反应条件（0.05 mol％催化剂和80°C）下促进缩水甘油与醇的开环。反应以高活性（EtOH的初始周转频率为1680 h -1）进行，并以区域选择性方式（十二烷基单烷基甘油醚（MAGEs）形成）的选择性（> 95％）（非-的收率为84–96％）对称区域异构体）。这种合成方法可通过使用富含地壳的金属基催化剂将甘油衍生的平台分子（即缩水甘油）转化为高附加值的产品。
• PROCESS FOR MAKING POLYOL ETHERS
  申请人：Olken Michael M.

  公开号：US20110207969A1

  公开（公告）日：2011-08-25

  The present invention generally relates to a process for making polyol ethers by reacting a polyol and a carbonyl compound together in the presence of hydrogen gas and a palladium hydrogenation catalyst on an acidic mesoporous carbon support.

  本发明通常涉及一种通过在酸性介孔碳负载的钯氢化催化剂存在下，将聚醇和羰基化合物一起在氢气存在下反应制备聚醚醇的方法。
• [EN] INTEGRATED PROCESS FOR THE PRODUCTION OF FUEL COMPONENTS FROM GLYCERIN<br/>[FR] PROCÉDÉ INTÉGRÉ POUR LA PRODUCTION DE CONSTITUANTS COMBUSTIBLES À PARTIR DE GLYCÉRINE
  申请人：ENI SPA

  公开号：WO2018178130A1

  公开（公告）日：2018-10-04

  The present invention relates to a versatile process for the simultaneous production of biocomponents for fuels such as gasoline and diesel, essentially starting from glycerol of biological origin only, comprising a multiplicity of interconnected steps related to hydrogenation, condensation and etherification.

  本发明涉及一种多功能工艺，用于同时生产用于燃料如汽油和柴油的生物组分，其基本上仅从生物来源的甘油开始，包括与氢化，缩合和醚化相关的多个互相连接的步骤。
• GLYCEROL DERIVATIVES AND METHODS OF MAKING SAME
  申请人：Kodali Dharma R.

  公开号：US20080293602A1

  公开（公告）日：2008-11-27

  Symmetrical polyols, polyol esters, polyesters, polyurethanes, triazoles, and polyvinylethers derived from glycerol and methods of making the symmetrical polyols, polyesters, polyurethanes, polyhydroxyvinylethers and triazoles are discussed. Also provided is a method of making serinol.

  本文讨论了从甘油衍生出的对称聚醇、聚醚醇、聚酯、聚氨酯、三唑和聚乙烯醚，以及制备这些对称聚醇、聚酯、聚氨酯、聚羟基乙烯醚和三唑的方法。此外，还提供了一种制备丝氨醇的方法。
• [EN] PROCESS FOR THE PREPARATION OF CYCLIC ACETALS THAT CAN BE USED AS COMPONENTS FOR DIESEL FUELS<br/>[FR] PROCÉDÉ DE PRÉPARATION D'ACÉTALS CYCLIQUES UTILISABLES EN TANT QUE COMPOSANTS POUR CARBURANTS DIESEL
  申请人：ENI SPA

  公开号：WO2018116207A1

  公开（公告）日：2018-06-28

  The present invention relates to a process for preparing cyclic acetals that can be used as components for diesel fuel. More specifically, the present invention relates to a process for preparing cyclic acetals having an ethereal function that can be used as diesel fuel components preferably starting from precursors of a biological origin such as, for example, starting from glycerol of a biological origin. With the process of the present invention, it is possible, for example, to prepare etherified cyclic acetals having a 1,3-dioxolane and 1,3-dioxane structure, that can be used as diesel fuel components, starting from non-etherified cyclic acetals having a 1,3-dioxolane structure, which in turn can be obtained from glycerol derivatives, in particular glycerol of a biological origin, such as 1,2-diols, for example, 1,2-propanediol.

  本发明涉及一种制备环状缩醛的方法，该缩醛可用作柴油燃料的组分。更具体地说，本发明涉及一种制备具有以太功能的环状缩醛的方法，该缩醛可用作柴油燃料的组分，最好是从生物起源的前体开始制备，例如从生物起源的甘油开始制备。使用本发明的方法，例如可以从具有1,3-二氧兰结构的非醚化环状缩醛开始制备具有1,3-二氧兰和1,3-二氧杂环结构的醚化环状缩醛，这些醚化环状缩醛可用作柴油燃料的组分，而非醚化环状缩醛则可以从甘油衍生物中获得，特别是从生物起源的甘油中获得，例如1,2-二醇，例如1,2-丙二醇。