propyl 2-chloro-4-formylmethylbenzoate | 869663-27-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: propyl 2-chloro-4-formylmethylbenzoate
• 英文别名: Propyl 2-chloro-4-(2-oxoethyl)benzoate；propyl 2-chloro-4-(2-oxoethyl)benzoate
• CAS: 869663-27-4
• 化学式: C₁₂H₁₃ClO₃
• 分子量: 240.686
• InChiKey: KTWIQWLTFZMKDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-[(4-bromo-3-chlorophenyl)methyl]-1,3-dioxolane 在 盐酸 、 正丁基锂 作用下， 以 四氢呋喃 、 DMF (N,N-dimethyl-formamide) 、 正己烷 、 水 为溶剂， 反应 44.08h， 生成 propyl 2-chloro-4-formylmethylbenzoate
  参考文献：
  名称：

  [EN] INSECTICIDAL DIAZOLE AND TRIAZOLE DERIVATIVES
  [FR] DERIVES DE DIAZOLE ET DE TRIAZOLE INSECTICIDES

  摘要：

  已经发现了某些新型二唑和三唑衍生物具有意想不到的杀虫活性。这些化合物由式(I)表示。首选的是式(I)中M和Q为碳；R为甲基；R1和R2一起取-CH=CHCH=CH-, -C(Cl)=CHCH=CH-, -C(F)=CHCH=CH-或-C(CH3)=CHCH=CH-；X为直链或支链烷基；Y为苯基；R4为一个或多个氢、卤素、烷基、卤代烷基、烷氧基、卤代烷氧基、氰基、氨基或-(O)t-(CH2)v-Z-R6，其中Z为-C(R7)=C(R8)-，-C≡C-或-C(R7)=NO-；而R6、R7和R8独立地为氢、卤素或烷基。此外，还公开了包含至少一种式(I)化合物的杀虫有效量和可选地至少一种第二化合物的有效量，以及至少一种杀虫载体的组合物；以及涉及将这些组合物施用于存在或预计存在昆虫的作物生长地点以控制昆虫的方法。

  公开号：

  WO2005108374A1

文献信息

• Gas Barrier Laminated Film and Process for Producing the Same
  申请人：Fujii Hitoshi

  公开号：US20070269664A1

  公开（公告）日：2007-11-22

  There are provided a gas barrier laminated film, which is transparent while possessing excellent gas barrier properties and, at the same time, has excellent impact resistance, and a process for producing the same. The gas barrier laminated film comprises a base material, a vapor deposited film of an inorganic oxide provided on the base material, and a gas barrier coating film provided on the vapor deposited film. The gas barrier laminated film is characterized in that the base material on its side where the vapor deposited film is provided, has been subjected to pretreatment or primer coating treatment, and the gas barrier coating film has been formed by coating a gas barrier coating liquid onto the inorganic oxide film and then heating the coating.

  提供了一种气体阻隔层压膜，它在具有优异气体阻隔性能的同时，具有优异的抗冲击性，且透明。同时提供了制备该压膜的方法。该气体阻隔层压膜包括基材、沉积在基材上的无机氧化物蒸发膜和涂覆在蒸发膜上的气体阻隔涂层膜。该气体阻隔层压膜的特点在于，在蒸发膜所在的基材侧经过预处理或底漆涂层处理，并且气体阻隔涂层膜是通过将气体阻隔涂层液体涂覆在无机氧化物膜上并加热涂覆形成的。
• [EN] INSECTICIDAL DIAZOLE AND TRIAZOLE DERIVATIVES<br/>[FR] DERIVES DE DIAZOLE ET DE TRIAZOLE INSECTICIDES
  申请人：FMC CORP

  公开号：WO2005108374A1

  公开（公告）日：2005-11-17

  It has now been found that certain novel diazole and triazole derivatives have provided unexpected insecticidal activity. These compounds are represented by formula (I). Preferred are those compounds of formula (I) where M and Q are carbon; R is methyl; R1 and R2 taken together are -CH=CHCH=CH-, -C(Cl)=CHCH=CH-, -C(F)=CHCH=CH-, or -C(CH3)=CHCH=CH-; X is straight or branched chain alkylenyl; Y is phenyl; and R4 is one or more hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, cyano, amino, or -(O)t-(CH2)v-Z-R6, where Z is -C(R7)=C(R8)-, -C≡C-, or -C(R7)=NO-; and, R6, R7 and R8 are indepdently hydrogen, halogen, or alky. In addition, compositions comprising an insecticidally effective amount of at least one compound of formula (I), and optionally, an effective amount of at least one of a second compound, with at least one insecticidally compatible carrier are also disclosed; along with methods of controlling insects comprising applying said compositions to the locus of crops where insects are present or are expected to be present.

  已经发现了某些新型二唑和三唑衍生物具有意想不到的杀虫活性。这些化合物由式(I)表示。首选的是式(I)中M和Q为碳；R为甲基；R1和R2一起取-CH=CHCH=CH-, -C(Cl)=CHCH=CH-, -C(F)=CHCH=CH-或-C(CH3)=CHCH=CH-；X为直链或支链烷基；Y为苯基；R4为一个或多个氢、卤素、烷基、卤代烷基、烷氧基、卤代烷氧基、氰基、氨基或-(O)t-(CH2)v-Z-R6，其中Z为-C(R7)=C(R8)-，-C≡C-或-C(R7)=NO-；而R6、R7和R8独立地为氢、卤素或烷基。此外，还公开了包含至少一种式(I)化合物的杀虫有效量和可选地至少一种第二化合物的有效量，以及至少一种杀虫载体的组合物；以及涉及将这些组合物施用于存在或预计存在昆虫的作物生长地点以控制昆虫的方法。