(2-amino-phenyl)-(3-amino-phenyl)-ether | 99739-88-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-amino-phenyl)-(3-amino-phenyl)-ether
• 英文别名: (2-Amino-phenyl)-(3-amino-phenyl)-aether；2-(3-Aminophenoxy)aniline
• CAS: 99739-88-5
• 化学式: C₁₂H₁₂N₂O
• mdl: MFCD24392017
• 分子量: 200.24
• InChiKey: RONZMCPXGUADIF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-(3-nitrophenoxy)aniline 在 一水合肼 作用下， 生成 (2-amino-phenyl)-(3-amino-phenyl)-ether
  参考文献：
  名称：

  Expression of human hepatitis C virus core antigen in tobacco plants by tobacco mosaic virus-based vector system

  摘要：

  Tobacco mosaic virus (TMV) has the potential to highly express foreign gene. A novel TMV-based in trans expression system was constructed. A TMV mutant TSHc had its coat protein replaced with hepatitis C virus (HCV) core antigen gene. Another TMV mutant TSBD was replicase-detective. Coinfection of the two mutants could cause systemic infection in tobacco plants by in trans complementation of their functions. TSHc could effectively replicate and assemble to viral particles, which were a little longer than that of wild-type TMV. HCV core antigen was expressed in whole tobacco plants. A similar expression lever of HCV core antigen was detected on serial passages, which suggested that this viral expression system be stable.

  DOI：

  10.1007/bf02884901

文献信息

• NOVEL DIAMINE, POLYAMIC ACID, AND POLYIMIDE
  申请人：NISSAN CHEMICAL INDUSTRIES. LTD.

  公开号：US20160264520A1

  公开（公告）日：2016-09-15

  To provide a novel diamine, and a polyimide precursor and a polyimide using it. A diamine represented by the formula (1): wherein each of X 1 and X 5 which are independent of each other, is a single bond or the like; each of X 2 and X 4 which are independent of each other, is —CH 2 — or the like; X 3 is a C 1-6 alkylene or the like; each of Y 1 and Y 2 which are independent of each other, is a single bond or the like; R is a C 1-20 linear, branched or cyclic hydrocarbon group; and a is 0 or 1).

  提供一种新颖的二胺，以及使用它的聚酰亚胺前体和聚酰亚胺。一种由式（1）表示的二胺：其中X1和X5中的每一个独立的，是单键或类似物；X2和X4中的每一个独立的，是—CH2—或类似物；X3是C1-6烷基或类似物；Y1和Y2中的每一个独立的，是单键或类似物；R是C1-20线性、支链或环烃基；a为0或1。
• Asymmetric Diamine Compounds Containing Two Functional Groups and Polymers Therefrom
  申请人：KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20150045481A1

  公开（公告）日：2015-02-12

  The present invention relates to a novel diamine compound, wherein two substituents R and R′ are introduced asymmetrically, and a polymer thereof. The polymer may have excellent solubility in the organic solvent and allows for easy processibility after imidization, thus giving proper film maintaining superior properties, such as thermal, mechanical, and optical properties for applications in electrical, electronic, or optical materials.

  本发明涉及一种新型二胺化合物，其中引入了两个不对称的取代基R和R'，以及其聚合物。该聚合物在有机溶剂中具有出色的溶解性，并在酰亚胺化后易于加工，从而形成具有优越热性能、机械性能和光学性能的适用于电气、电子或光学材料的适当薄膜。
• NOVEL POLYAMIDEIMIDE HAVING LOW THERMAL EXPANSION COEFFICIENT
  申请人：KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20160194449A1

  公开（公告）日：2016-07-07

  The present invention relates to a polyamideimide comprising an asymmetric dicarboxylic acid derivative wherein, from among a cyclic group A and a cyclic group B, two substitutents groups R and R′ are bonded only to the cyclic group A on one side. A polymer produced by means of the present invention can have adequate solubility with respect to organic solvents, high thermal stability, a high glass transition temperature, high transparency and a low thermal expansion coefficient, and is able not only to satisfy requirements for core substrate materials of flexible displays but also to be used as a material for various soft electronic data devices.

  本发明涉及一种聚酰胺酰亚胺，其包括一种不对称二羧酸衍生物，其中，从环状基团A和环状基团B中选择，两个取代基R和R'仅在一侧与环状基团A相结合。通过本发明手段生产的聚合物可以在有机溶剂中具有足够的溶解性，具有高热稳定性，高玻璃化转变温度，高透明度和低热膨胀系数，并且不仅能够满足柔性显示器的核心基板材料的要求，还可以用作各种软性电子数据设备的材料。
• Thermally stable polyimide and preparation process of polyimide
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0488630A2

  公开（公告）日：1992-06-03

  Disclosed are a thermally stable polyimide which is blocked at the polymer terminal with a dicarboxylic acid anhydride represented by the formula (III) : wherein Z is a divalent radical selected from the group consisting of a monoaromatic radical which is substantially unsubstituted or substituted with a radical having no reactivity with amine or dicarboxylic acid anhydride and has from 6 to 15 carbon atoms, a condensed polyaromatic radical or a noncondensed aromatic radical connected each other with a direct bond or a bridge member, and has a fundamental skeleton represented by recurring structural units of the formula (IV) : ; and preparation process of the polyimide.

  本发明公开了一种热稳定聚酰亚胺，该聚酰亚胺在聚合物末端用式 (III) 所代表的二羧酸酐封端： 其中 Z 是二价自由基，选自由下列自由基组：基本未被取代或被与胺或二羧酸酐无 反应性的自由基取代的单芳香族自由基，具有 6 至 15 个碳原子；缩合多芳香族自由基或彼此以直 接键或桥件连接的非缩合芳香族自由基；具有由式 (IV) 重复结构单元表示的基本骨架： 以及聚酰亚胺的制备工艺。
• Readily processable polyimide, preparation process of polyimide, and resin composition of polyimide
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0488604A2

  公开（公告）日：1992-06-03

  Disclosed are a readily processable polyimide being blocked at the terminal of a polymer molecule with a divalent radical derived from dicarboxylic acid anhydride represented by the formula (IV) : wherein Z is a divalent radical selected from the group consisting of a monoaromatic radical which is substantially unsubstituted or substituted with a radical having no reactivity with amine or carboxylic acid anhydride and has from 5 to 15 carbons atoms, condensed polyaromatic radical or noncondensed aromatic radical connected each other with a direct bond or a bridge member, and having a fundamental skeleton represented by recurring structural units of the formula (III) : wherein X and Y are -O- or -CO- and differ each other; preparation process of the polyimide ; and resin composition containing the polyimide and fibrous reinforcement.

  本发明公开了一种易于加工的聚酰亚胺，该聚酰亚胺在聚合物分子的末端被二价基封堵，该二价基来源于式（IV）所代表的二羧酸酐： 其中 Z 是二价基，选自以下组别：基本未被取代或被与胺或羧酸酐无反应活性的基取代的单芳香基，具有 5 至 15 个碳原子；通过直接键或桥接构件相互连接的缩合多芳香基或非缩合芳香基；具有由式 (III) 重复结构单元表示的基本骨架；以及 Z 是二价基，选自以下组别：基本未被取代或被与胺或羧酸酐无反应活性的基取代的单芳香基，具有 5 至 15 个碳原子；通过直接键或桥接构件相互连接的缩合多芳香基或非缩合芳香基；具有由式 (III) 重复结构单元表示的基本骨架： 其中 X 和 Y 为-O-或-CO-且彼此不同；聚酰亚胺的制备工艺；以及含有聚酰亚胺和纤维增强材料的树脂组合物。