N-phenyl-4-acetyl-1,8-naphthalenedicarboxylic acid imide | 78759-60-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: N-phenyl-4-acetyl-1,8-naphthalenedicarboxylic acid imide
• 英文别名: 4-acetylnaphthalic acid N-phenylimide；6-acetyl-2-phenyl-1H-benzo[de]isoquinoline-1,3(2H)-dione；6-acetyl-2-phenylbenzo[de]isoquinoline-1,3-dione
• CAS: 78759-60-1
• 化学式: C₂₀H₁₃NO₃
• mdl: MFCD00389021
• 分子量: 315.328
• InChiKey: HPGFDKXGQGPAJM-UHFFFAOYSA-N

物化性质

• 沸点：
  573.4±42.0 °C(Predicted)
• 密度：
  1.356±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  54.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-phenyl-4-acetyl-1,8-naphthalenedicarboxylic acid imide 生成 potassium;7-acetyl-1-hydroxy-3-oxo-2-phenylbenzo[de]isoquinolin-1-olate
  参考文献：
  名称：

  VOROZHTSOV, G. N.;STOROZHENKO, V. G., AZOTSODERZH. GETEROTSIKLY, NOVOSIBIRSK,(1987) 219

  摘要：

  DOI：
• 作为产物：
  描述：

  苊 在 aluminum (III) chloride 、 sodium dichromate dihydrate 、 溶剂黄146 作用下， 以 二氯甲烷 为溶剂， 反应 72.0h， 生成 N-phenyl-4-acetyl-1,8-naphthalenedicarboxylic acid imide
  参考文献：
  名称：

  A white light emitting reconfigurable pyrazoline-naphthalimide logic gate with magnesium, sodium and proton inputs

  摘要：

  一种 3-吡唑啉基萘二甲酰亚胺被证明是一种波长可重新配置的双输出逻辑门，它在与 Na+ 结合时发出橙色光，在与 Mg2+ 结合时发出白色光。

  DOI：

  10.1039/d2cc06049c

文献信息

• On the Development of Sensor Molecules that Display Fe^III-amplified Fluorescence
  作者：Julia L. Bricks、Anton Kovalchuk、Christian Trieflinger、Marianne Nofz、Michael Büschel、Alexei I. Tolmachev、Jörg Daub、Knut Rurack

  DOI：10.1021/ja050652t

  日期：2005.10.1

  Incorporation of a tailor-made size-restricted dithia-aza-oxa macrocycle, 1-oxa-4,10-dithia-7aza-cyclocloclecane, via a phenyl linker into two fluorescent sensor molecules with electronically decoupled, rigidly fixed, and sterically preoriented architectures, a 1,3,5-triaryl-Delta(2)-pyrazoline and a meso-substituted boron-dipyrromethene (BDP), yields amplified fluorescence in the red-visible spectral range upon binding of Fe-III ions. The response to Fe-III and potentially interfering metal ions is studied in highly polar aprotic and protic solvents for both probes as well as in neat and buffered aqueous solution for one of the sensor molecules, the BDP derivative. In organic solvents, the fluorescence of both indicators is quenched by an intramolecular charge or electron transfer in the excited state and coordination of Fe-III leads to a revival of their fluorescence without pronounced spectral shifts. Most remarkably, the unbound BDP derivative shows dual emission in water and can be employed for the selective ratiometric signaling of Fe-III in buffered aqueous solutions.
• Organic luminophores of the pyrazoline series with two unconjugated fluorophores
  作者：B. M. Krasovitskii、T. P. Zubanova、Yu. M. Vinetskaya

  DOI：10.1007/bf00513443

  日期：1982.9
• KRASOVITSKIJ, B. M.;ZUBANOVA, T. P.;VINETSKAYA, YU. M., XIMIYA GETEROTSIKL. SOEDIN., 1982, N 9, 1248-1250
  作者：KRASOVITSKIJ, B. M.、ZUBANOVA, T. P.、VINETSKAYA, YU. M.

  DOI：——

  日期：——
• VOROZHTSOV, G. N.;STOROZHENKO, V. G., AZOTSODERZH. GETEROTSIKLY, NOVOSIBIRSK,(1987) 219
  作者：VOROZHTSOV, G. N.、STOROZHENKO, V. G.

  DOI：——

  日期：——
• A white light emitting reconfigurable pyrazoline-naphthalimide logic gate with magnesium, sodium and proton inputs
  作者：David C. Magri、Anthony A. Camilleri

  DOI：10.1039/d2cc06049c

  日期：——

  A 3-pyrazolinyl-naphthalimide is demonstrated as a wavelength-reconfigurable dual-output logic gate that emits orange light on binding Na⁺ and white light on binding Mg²⁺.

  一种 3-吡唑啉基萘二甲酰亚胺被证明是一种波长可重新配置的双输出逻辑门，它在与 Na+ 结合时发出橙色光，在与 Mg2+ 结合时发出白色光。