cis-[Pd(C6F5)2(acetimine)2] | 476362-54-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-[Pd(C6F5)2(acetimine)2]
• 英文别名: Palladium(2+);1,2,3,4,5-pentafluorobenzene-6-ide;propan-2-imine
• CAS: 476362-54-6
• 化学式: C₁₈H₁₄F₁₀N₂Pd
• 分子量: 554.727
• InChiKey: FIZLCJBJLDKRCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.45
• 重原子数：
  31
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  47.7
• 氢给体数：
  2
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  cis-[Pd(pentafluorophenyl)2(PhCN)2] 、 氨 、 丙酮 以 氨 、 丙酮 为溶剂， 以76%的产率得到cis-[Pd(C6F5)2(acetimine)2]
  参考文献：
  名称：

  Acetimine and 2-Methyl-2-amino-4-iminopentane Complexes of Palladium(II)

  摘要：

  By reaction between the labile complex cis-[Pd(C6F5)(2)(PhCN)(2)] and aqueous ammonia-acetone solutions the palladium complexes [Pd(C6F5)(2)L-2] [L = NH3 (1), NHCMe2 (2) and L-2 = NHC(Me)CH2C(Me-2)NH2 (3)] are obtained. The reaction product depends on the experimental conditions used. The cationic complexes [Pd(dmba)L-2]ClO4 [L = NH3 (5), NHCMe2 (6) and L-2 = NH C(Me)CH2C(Me-2)NH2 (7)] with the N,C-chelating 2-(dimethyl-aminomethyl)phenyl (dmba) ligand have been obtained by treating [(dmba)Pd(mu-Cl)(2)Pd-(dmba)] with AgClO4 in aqueous ammonia-acetone solution. The mono(acetimine) complex [Pd(dmba)(PPh3)(NHCMe2)]ClO4 (8) is obtained by a similar procedure starting from [Pd-(dmba)(PPh3)Cl]. The crystal structures of 1-3 and 6 and 7 have been determined; there is extensive hydrogen bonding (N-H...F-C or N-H...OClO3) in all the compounds.

  DOI：

  10.1021/om020434y

文献信息

• Acetimine and 2-Methyl-2-amino-4-iminopentane Complexes of Palladium(II)
  作者：José Ruiz、Venancio Rodríguez、Natalia Cutillas、Gregorio López、José Pérez

  DOI：10.1021/om020434y

  日期：2002.11.1

  By reaction between the labile complex cis-[Pd(C6F5)(2)(PhCN)(2)] and aqueous ammonia-acetone solutions the palladium complexes [Pd(C6F5)(2)L-2] [L = NH3 (1), NHCMe2 (2) and L-2 = NHC(Me)CH2C(Me-2)NH2 (3)] are obtained. The reaction product depends on the experimental conditions used. The cationic complexes [Pd(dmba)L-2]ClO4 [L = NH3 (5), NHCMe2 (6) and L-2 = NH C(Me)CH2C(Me-2)NH2 (7)] with the N,C-chelating 2-(dimethyl-aminomethyl)phenyl (dmba) ligand have been obtained by treating [(dmba)Pd(mu-Cl)(2)Pd-(dmba)] with AgClO4 in aqueous ammonia-acetone solution. The mono(acetimine) complex [Pd(dmba)(PPh3)(NHCMe2)]ClO4 (8) is obtained by a similar procedure starting from [Pd-(dmba)(PPh3)Cl]. The crystal structures of 1-3 and 6 and 7 have been determined; there is extensive hydrogen bonding (N-H...F-C or N-H...OClO3) in all the compounds.