4-(trifluorovinyloxy)benzenesulfonyl chloride | 297765-09-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(trifluorovinyloxy)benzenesulfonyl chloride
• 英文别名: 4-(1,2,2-Trifluoroethenoxy)benzenesulfonyl chloride
• CAS: 297765-09-4
• 化学式: C₈H₄ClF₃O₃S
• 分子量: 272.632
• InChiKey: JAPZWILHNSWLIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4-(trifluorovinyloxy)benzenesulfonyl chloride 在 氨 、 N,N-二异丙基乙胺 作用下， 以 乙腈 为溶剂， 反应 24.0h， 生成 1,1'-bis[4-(trifluorovinyl)oxyphenylsulfonyl]-1,4-(disulfonyloctafluorobutyl)diimide
  参考文献：
  名称：

  Perfluorocyclobutyl (PFCB) aromatic polyethers: Synthesis and characterization of new sulfonimide containing monomers and fluoropolymers

  摘要：

  The synthesis and thermal cyclopolymerization of aryl trifluorovinyl ether monomers containing novel sulfonimide acid functionalities are described. The monomers are prepared starting from commercially available 4-bromophenol in five steps. These novel polymers explore a new versatile class of partially fluorinated polymers for potential use in fuel cells and other electrochemical applications. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2005.02.007
• 作为产物：
  描述：

  1-bromo-4-(trifluorovinyloxy)benzene 在 叔丁基锂 、 氯氟磺酰 作用下， 以 乙醚 为溶剂， 反应 2.17h， 以65%的产率得到4-(trifluorovinyloxy)benzenesulfonyl chloride
  参考文献：
  名称：

  Perfluorocyclobutyl (PFCB) aromatic polyethers: Synthesis and characterization of new sulfonimide containing monomers and fluoropolymers

  摘要：

  The synthesis and thermal cyclopolymerization of aryl trifluorovinyl ether monomers containing novel sulfonimide acid functionalities are described. The monomers are prepared starting from commercially available 4-bromophenol in five steps. These novel polymers explore a new versatile class of partially fluorinated polymers for potential use in fuel cells and other electrochemical applications. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2005.02.007

文献信息

• Sulfonated perfluorovinyl functional monomers
  申请人：3M Innovative Properties Company

  公开号：US20020007083A1

  公开（公告）日：2002-01-17

  The present invention provides a monomer having the formula A-B, wherein A is represented by Formula I: 1 wherein B is selected from —OCF=CF 2 and —A; wherein, when B is—OCF=CF 2 , the orientation of B is meta or para to the trifluorovinyloxy group of A; wherein, when B is A, the bond joining the A groups is para to the trifluorovinyloxy group of each A; and wherein each Z is independently selected from —SO 2 F, —SO 2 Cl, —SO 3 H, —SO 2 —N(M)—SO 2 CF 3 , and —SO 2 —N(M)—SO 2 Rf; wherein M is any suitable cation and Rf is a Cl to CIO fluorocarbon or fluorinated ether group. The present invention also provides a monomer according to Formula II: 2 wherein X is F, Cl, or N(M)SO 2 Rf, wherein M is any suitable cation and R f is a C1 to C10 fluorocarbon or fluorinated ether group.

  本发明提供了一种具有A-B式的单体，其中A由式I表示：1，其中B选自—OCF=CF2和—A；其中，当B为—OCF=CF2时，B的取向为与A的三氟乙烯氧基相对的间位或对位；当B为A时，连接A基团的键为与每个A的三氟乙烯氧基对位；且其中每个Z独立地选自—SO2F、—SO2Cl、—SO3H、—SO2—N(M)—SO2CF3和—SO2—N(M)—SO2Rf，其中M是任何合适的阳离子，Rf是Cl到CIO的氟碳化合物或氟化醚基团。本发明还提供了一种根据式II的单体：2，其中X为F、Cl或N(M)SO2Rf，其中M是任何合适的阳离子，Rf为C1到C10的氟碳化合物或氟化醚基团。
• SULFONATED PERFLUOROVINYL FUNCTIONAL MONOMERS
  申请人：3M Innovative Properties Company

  公开号：EP1286961B1

  公开（公告）日：2004-05-19
• US6268532B1
  申请人：——

  公开号：US6268532B1

  公开（公告）日：2001-07-31
• US6384167B2
  申请人：——

  公开号：US6384167B2

  公开（公告）日：2002-05-07
• [EN] SULFONATED PERFLUOROVINYL FUNCTIONAL MONOMERS<br/>[FR] MONOMERES FONCTIONNELS DE PERFLUOROVINYLE SULFONE
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2001094305A1

  公开（公告）日：2001-12-13

  The present invention provides a monomer having the formula A-B, wherein A is represented by Formula I:wherein B is selected from -OCF=CF2 and -A; wherein, when B is -OCF=CF2, the orientation of B is meta or para to the trifluorovinyloxy group of A; wherein, when B is A, the bond joining the A groups is para to the trifluorovinyloxy group of each A; and wherein each Z is independently selected from -SO2F, -SO2Cl, -SO3H, -SO2-N(M)-SO2CF3, and -SO2-N(M)-SO2Rf ; wherein M is any suitable cation and Rf is a C1 to C10 fluorocarbon or fluorinated ether group. The present invention also provides a monomer according to Formula II:wherein X is F, Cl, or N(M)SO2Rf; wherein M is any suitable cation and Rf is a C1 to C10 fluorocarbon or fluorinated ether group.