lithium anthranilate | 60613-06-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: lithium anthranilate
• 英文别名: lithium 2-aminobenzoate；o-aminobenzoic acid lithium salt；lithium o-aminobenzoate；lithium;2-aminobenzoate
• CAS: 60613-06-1
• 化学式: C₇H₆NO₂*Li
• 分子量: 143.071
• InChiKey: LYPDAJMEKQFULB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.36
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  66.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  bis(8-hydroxy-5-quinolyl)methane 、 lithium anthranilate 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Prakash, Dharm; Singh, Shankar Prasad, Journal of the Indian Chemical Society, 1984, vol. 61, # 6, p. 471 - 473

  摘要：

  DOI：

文献信息

• Structures and properties of anthranilato- and N-phenylanthranilato-rhodium(I) complexes containing triphenylphosphine ligands
  作者：Andrzej F. Borowski、David J. Cole-Hamilton

  DOI：10.1016/s0277-5387(00)84609-4

  日期：1993.7

  coordinated to each rhodium atom is proposed for N-phenylanthranilate ( 2 ). On treatment with hydrogen both complexes give cis -dihydrides, but variable temperature 1 H and 31 P NMR studies of the product derived from 1 reveal that a temperature-dependent equilibrium involving dissociation of PPh 3 occurs. Complexes 1 and 2 are stable under hydrogenation conditions and enable slow hydrogenation of 1-alkenes

  摘要描述了两种三苯膦铑（I）与邻氨基苯甲酸和N-苯基邻氨基苯甲酸的配合物的结构，这些配合物在某些烯烃，二烯，芳族和杂芳族化合物的加氢生成反应中具有活性。假定威尔金森催化剂的单体氨基羧酸盐类似物用于邻氨基苯甲酸酯络合物（1），并且提出了具有羧酸盐桥的二聚结构，并且提出了与每个铑原子配位的两个顺式-三苯基膦分子用于N-苯基邻氨基苯甲酸酯（2）。在用氢处理时，两种络合物均生成顺式-二氢化物，但对1衍生的产物进行1 H变温和31 P NMR研究表明，发生了取决于温度的平衡，涉及到PPh 3的解离。配合物1和2在氢化条件下是稳定的，并能使1-烯烃和环己二烯缓慢氢化。对于环己二烯，观察到对环己烯形成的某些选择性，尤其是在DMF中。尽管1和2对芳烃和杂芳族化合物的氢化的活性通常非常低，但是吡啶可以在很大程度上被氢化为哌啶。
• METHOD FOR ELECTROPHORETICALLY DETERMINE THE COMPOSITION OF MULTICOMPONENT SOLUTIONS AND A DEVICE FOR CARRYING OUT SAID METHOD
  申请人：Zinchenko, Mikhail Ivanovich

  公开号：EP1998170A1

  公开（公告）日：2008-12-03

  The present invention relates to analytical chemistry, more particularly, to methods of electrophoretic analysis, and can be utilized to analysis of multicomponent solutions. The invention is aimed at elimination of effect of uncontrolled scatter of electroosmotic flow rates on reproducibility of electrophoretic separation. The method is claimed of electrophoretic separation of multicomponent solutions, including capillary washing with electrolytic solution, injection of sample into capillary, electrophoretic separation of sample components in capillary effected by voltage applied between the capillary ends, detection and measurement of retention times of separated sample components, wherein during capillary washing by electrolytic solution the streaming potential magnitude being determined by measuring potential difference between capillary ends at definite pressure difference between said capillary ends, and identification of sample components is made subject to the measured streaming potential magnitude and values of measured retention times of sample components. The device is claimed comprising of vials for electrolyte and samples, capillary, means for installation of capillary made for putting capillary ends to the mentioned vials for electrolyte and samples, means for generation of electrolyte flow through capillary, pneumatically connected with means for installation of capillary, means for applying voltage between capillary ends, detector connected with capillary, system of signal management and processing, as well as means for streaming potential measurement, providing closing of electric measurement circuit in process of washing, including electrolyte in vials and capillary, and to open it in process of electrophoretic separation. Reproducibility is increased sufficiently and productivity of analysis is increased in process of electrophoretic analysis of multicomponent solutions. 6 Figs.

  本发明涉及分析化学，特别是电泳分析方法，可用于分析多组分溶液。 本发明旨在消除不受控制的电渗流率散射对电泳分离重现性的影响。 该方法用于多组分溶液的电泳分离，包括用电解溶液洗涤毛细管、将样品注入毛细管、通过在毛细管两端施加电压实现毛细管中样品组分的电泳分离、检测和测量分离样品组分的保留时间、其中，在用电解溶液清洗毛细管的过程中，通过测量毛细管两端之间的电位差来确定所述毛细管两端之间的确定压差下的流电位大小，并根据测得的流电位大小和测得的样品组分的保留时间值来识别样品组分。 该装置包括电解液和样品瓶、毛细管、毛细管安装装置（用于将毛细管末端安装到上述电解液和样品瓶上）、电解液流经毛细管的装置（与毛细管安装装置气动连接）、在毛细管两端之间施加电压的装置，与毛细管相连的检测器，信号管理和处理系统，以及流电势测量装置，在清洗过程中关闭电测量电路，将电解液注入样品瓶和毛细管，并在电泳分离过程中打开电测量电路。 在对多组分溶液进行电泳分析时，可充分提高可重复性，并提高分析效率。6 图
• Banerjee, A. K.; Prasad, Dharmbir; Roy, S. K., Journal of the Indian Chemical Society, 1982, vol. 59, # 11/12, p. 1303 - 1305
  作者：Banerjee, A. K.、Prasad, Dharmbir、Roy, S. K.

  DOI：——

  日期：——
• FUEL COMPOSITIONS EMPLOYING CATALYST COMBUSTION STRUCTURE
  申请人：ORR, William C.

  公开号：EP1051461A2

  公开（公告）日：2000-11-15
• METHODS OF PREPARING LIPID NANOPARTICLES
  申请人：Modernatx, Inc.

  公开号：EP3917503A1

  公开（公告）日：2021-12-08