1,2-bis(2,4,6-trimethylanilide)-1,2-bis(duryl)diborane(4) | 1226758-28-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis(2,4,6-trimethylanilide)-1,2-bis(duryl)diborane(4)
• 英文别名: 2,4,6-trimethyl-N-[(2,3,5,6-tetramethylphenyl)-[(2,3,5,6-tetramethylphenyl)-(2,4,6-trimethylanilino)boranyl]boranyl]aniline
• CAS: 1226758-28-6
• 化学式: C₃₈H₅₀B₂N₂
• 分子量: 556.45
• InChiKey: ZOYHVKLGTXSQBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  42
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,4,6-三甲基苯胺 、 1,2-dichloro-1,2-diduryldiborane 在 正丁基锂 作用下， 以 乙醚 、 正己烷 、 正戊烷 为溶剂， 反应 4.0h， 以79%的产率得到1,2-bis(2,4,6-trimethylanilide)-1,2-bis(duryl)diborane(4)
  参考文献：
  名称：

  Synthesis and characterization of new air stable primary amido substituted diborane(4) derivatives

  摘要：

  Three new diborane(4) derivatives, 1,2-bis(2,4,6-trimethylanilide)-1,2-bis(dimethyamido)diborane(4) (1), 1,2-bis(2,4,6-trimethylanilide)-1,2-bis(duryl)diborane(4) (2) and 1,2-bis(anilide)-1,2-bis(duryl)diborane(4) (3), have been synthesized and characterized by means of elemental analysis, IR, H-1, DC and B-11 NMR spectroscopy. Additionally, the structures of compounds 1 and 2 have been determined by the single crystal X-ray diffraction technique. The compounds 1 and 2 crystallize in the monoclinic P21/c space group. All of the compounds were found to be air stable. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.01.031

文献信息

• Synthesis and characterization of new air stable primary amido substituted diborane(4) derivatives
  作者：Erkan Fırıncı、H. Can Söyleyici、Emrah Giziroğlu、Ersin Temel、Orhan Büyükgüngör、Yüksel Şahin

  DOI：10.1016/j.poly.2010.01.031

  日期：2010.3

  Three new diborane(4) derivatives, 1,2-bis(2,4,6-trimethylanilide)-1,2-bis(dimethyamido)diborane(4) (1), 1,2-bis(2,4,6-trimethylanilide)-1,2-bis(duryl)diborane(4) (2) and 1,2-bis(anilide)-1,2-bis(duryl)diborane(4) (3), have been synthesized and characterized by means of elemental analysis, IR, H-1, DC and B-11 NMR spectroscopy. Additionally, the structures of compounds 1 and 2 have been determined by the single crystal X-ray diffraction technique. The compounds 1 and 2 crystallize in the monoclinic P21/c space group. All of the compounds were found to be air stable. (C) 2010 Elsevier Ltd. All rights reserved.