9-isopropoxyanthracene | 57502-70-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9-isopropoxyanthracene
• 英文别名: 9-[(Propan-2-yl)oxy]anthracene；9-propan-2-yloxyanthracene
• CAS: 57502-70-2
• 化学式: C₁₇H₁₆O
• 分子量: 236.313
• InChiKey: ISXKEBSCLMXOIL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  蒽酮 、 三异丙基亚磷酸酯 以38%的产率得到
  参考文献：
  名称：

  TAMANO, MICHIKO;IKEDA, TOSHIYUKI;KOKETSU, JUGO, J. CHEM. SOC. JAP., CHEM. AND IND. CHEM., 1984, N 7, 1158-1163

  摘要：

  DOI：

文献信息

• Synthesis of 9-Anthryl Ethers from trans-9,10-Dihydro-9,10-dimethoxy­anthracene by Acid-Catalyzed Transetherification
  作者：Dae Chi、Keun Jang、Hee Shin

  DOI：10.1055/s-0028-1088073

  日期：2009.5

  Ar) to anthracene, anthryl ethers at the C9-position of anthracene were obtained as the major products when trans-9,10-dihydro-9,10-dimethoxyanthracene was reacted (10 minutes at 75 ˚C) with various alcohols. 9-Anthryl ethers with primary, secondary, cyclic alcohols, and polyethylene glycol (PEG) were isolated in 47-73% yields under optimized conditions. It is hoped that the devised method offers a

  在对蒽的亲电芳族加成反应（Ad E Ar）的研究中，当反式-9,10-二氢-9,10-二甲氧基蒽反应（10分钟）时，蒽C9位的蒽醚是主要产物。在75℃下）与各种酒精混合。在优化的条件下，以47-73％的收率分离出带有伯，仲，环状醇和聚乙二醇（PEG）的9-蒽醚。希望所设计的方法为通过将反式-9，10-二氢-9，10-二甲氧基蒽与各种醇进行酸催化的反式醚化提供一种新的合成路线来制备蒽醚。 互醚化-蒽醚-反式-9,10-二氢-9,10-二甲氧基蒽
• Sulphonium Salt Initiators
  申请人：Wolf Jean-Pierre

  公开号：US20090208872A1

  公开（公告）日：2009-08-20

  Compounds of the formula (I), (II), (III), (IV) and wherein, R is hydrogen, C 1 -C 20 alkyl; C 2 -C 20 alkyl interrupted by one or more O; is -L-X—R 2 or -L-R 2 ; R 1 has for example one of the meanings as given for R; R 2 is a monovalent sensitizer or photoinitiator moiety; Ar 1 and Ar 2 for example independently of one another are phenyl substituted by C 1 -C 20 alkyl, halogen or OR 3 ; or are unsubstituted naphthyl, anthryl, phenanthryl or biphenylyl; or are naphthyl, anthryl, phenanthryl or biphenylyl substituted by C 1 -C 20 alkyl, OH or OR 3 ; or are —Ar 4 -A-Ar 3 ; Ar 3 is unsubstituted phenyl naphthyl, anthryl, phenanthryl or biphenylyl; or is phenyl, naphthyl, anthryl, phenanthryl or biphenylyl substituted by C 1 -C 20 alkyl, OR 3 or benzoyl; Ar 4 is phenylene, naphthylene, anthrylene or phenanthrylene; A is a direct bond, S, O or C 1 -C 20 alkylene; X is CO, C(O)O, OC(O), O, S or NR 3 ; L is C 1 -C 20 alkylene or C 2 -C 20 alkylene interrupted by one or more O; R 3 is C 1 -C 20 alkyl or C 1 -C 20 hydroxyalkyl; and Y is an anion, are suitable as photolatent acid generators.

  公式（I），（II），（III），（IV）的化合物，其中R是氢，C1-C20烷基; C2-C20烷基中断一个或多个O;为-L-X—R2或-L-R2; R1例如具有给定为R的含义之一; R2是单价敏化剂或光引发剂基团; Ar1和Ar2例如独立地是被C1-C20烷基，卤素或OR3取代的苯基;或未取代的萘基，蒽基，菲基或联苯基;或被C1-C20烷基，OH或OR3取代的萘基，蒽基，菲基或联苯基;或是-Ar4-A-Ar3; Ar3是未取代的苯基，萘基，蒽基，菲基或联苯基;或是被C1-C20烷基，OR3或苯甲酰取代的苯基，萘基，蒽基，菲基或联苯基; Ar4是苯撑，萘撑，蒽撑或菲撑; A是直接键，S，O或C1-C20烷基; X是CO，C（O）O，OC（O），O，S或NR3; L是C1-C20烷基或C2-C20烷基中断一个或多个O; R3是C1-C20烷基或C1-C20羟基烷基; Y是阴离子，适用作光潜酸发生剂。
• RADICAL POLYMERIZATION CONTROL AGENT AND RADICAL POLYMERIZATION CONTROL METHOD
  申请人：Kawasaki Kasei Chemicals Ltd.

  公开号：US20210122692A1

  公开（公告）日：2021-04-29

  A conventional polymerization inhibitor is for example an agent to scavenge radicals generated during storage of a radical polymerizable compound and used to stably handle the radical polymerizable compound, but is unnecessary when the radical polymerizable compound is to be subjected to radical polymerization reaction, and is preferably removed at the time of the radical polymerization reaction. The object of the present invention is to obviate inconvenience of removing the polymerization inhibitor at the time of radical polymerization. The radical polymerization control agent contained in a radical polymerizable composition of the present invention functions as a radical polymerization inhibitor for example stored in a dark place, but loses its radical polymerization inhibiting effect when polymerization is initiated while being irradiated with light at a certain specific wavelength at the time of polymerization. Thus, radical polymerization of the radical polymerizable compound is easily initiated without increasing the amount of a radical polymerization initiator. That is, the radical polymerization control agent of the present invention is a radical polymerization control agent which is a corn pound having an effect to inhibit radical polymerization of a radical polymerizable compound and which loses the radical polymerization inhibiting effect under irradiation with light rays containing light within a wavelength range of from 300 nm to 500 nm.
• US4845201A
  申请人：——

  公开号：US4845201A

  公开（公告）日：1989-07-04
• US7901867B2
  申请人：——

  公开号：US7901867B2

  公开（公告）日：2011-03-08