N-Hydroxy-1,4,5,6,7,7-hexachlorbicyclo<2.2.1>hept-5-en-2,3-dicarboximid | 16626-06-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: N-Hydroxy-1,4,5,6,7,7-hexachlorbicyclo<2.2.1>hept-5-en-2,3-dicarboximid
• 英文别名: N-hydroxychlorendimide；1,7,8,9,10,10-Hexachloro-4-HO-4-aza-tricyclo(5.2.1.0(2,6))dec-8-ene-3,5-dione；1,7,8,9,10,10-hexachloro-4-hydroxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
• CAS: 16626-06-5
• 化学式: C₉H₃Cl₆NO₃
• 分子量: 385.846
• InChiKey: YFZWZOUTJIYJIP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  57.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-Hydroxy-1,4,5,6,7,7-hexachlorbicyclo<2.2.1>hept-5-en-2,3-dicarboximid 在 bis-triphenylphosphine-palladium(II) chloride 、 N-溴代丁二酰亚胺(NBS) 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 、 DPTS 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  低带隙发色团的超分子聚合物中的长寿命光电荷。

  摘要：

  π共轭分子的超分子聚集体中的光诱导电荷分离是基本的光物理过程，也是开发高级有机电子材料的关键标准。在这里，由于分子间氢键的作用，低带隙发色团自组装成螺旋一维聚集体。局限在这些超分子聚合物中的发色团表现出强烈的激子耦合相互作用，并产生电荷分离态，具有长达数小时的异常长寿命，并且在白光照射后的电荷密度高达5 mol％。两触点设备具有更高的光电导性，甚至可以表现出欧姆行为。

  DOI：

  10.1002/chem.201904561

文献信息

• METHOD FOR PRODUCING OXIDE
  申请人：DAICEL CORPORATION

  公开号：US20160159722A1

  公开（公告）日：2016-06-09

  Provided is a method of oxidizing a substrate with excellent oxidizing power to yield a corresponding oxide. The method can employ a commercially available imide compound as intact as a catalyst and can produce the oxide in a high yield under mild conditions. A method for producing an oxide according to the present invention includes performing oxidation of a substrate in the presence of oxygen and ozone under catalysis of an imide compound to yield a corresponding oxide. The imide compound has a cyclic imide skeleton represented by Formula (I). In the formula, n is selected from 0 and 1; and X is selected from an oxygen atom and an —OR group, where R is selected from hydrogen and a hydroxy-protecting group.

  提供了一种氧化底物以产生相应氧化物的方法，该方法可以利用商业可获得的亚酰胺化合物作为催化剂，并在温和条件下高产率地产生氧化物。根据本发明的一种制备氧化物的方法包括在氧气和臭氧的存在下，在亚酰胺化合物的催化下对底物进行氧化，以产生相应的氧化物。该亚酰胺化合物具有由式（I）表示的环状亚酰胺骨架。在该式中，n选择自0和1；X选择自氧原子和—OR基团，其中R选择自氢和羟基保护基团。
• METHOD FOR PRODUCING ESTER OR LACTONE
  申请人：Ishii Yasutaka

  公开号：US20100029956A1

  公开（公告）日：2010-02-04

  Disclosed is a method for producing an ester or lactone in which a secondary alcohol represented by following Formula (1) (wherein R a and R b each represent an organic group, or R a and R b may be combined to form a ring together with the adjacent carbon atom) is oxidized by molecular oxygen in the presence of a nitrogen-containing cyclic compound containing a structure represented by following Formula (I) [wherein X represents an oxygen atom or an —OR group (wherein R represents a hydrogen atom or hydroxyl-protecting group)] as a constituent of its ring, and at least one of a fluorine-containing alcohol and a fluorinated sulfonic acid, and thereby yields a compound represented by following Formula (2):

  本发明公开了一种制备酯或内酯的方法，其中在含有下式（1）所表示的二级醇（其中Ra和Rb各自表示一个有机基团，或者Ra和Rb可以与相邻的碳原子一起形成环）的分子氧存在下，通过含有下式（I）所表示的结构的含氮环状化合物作为其环中成分，其中X表示氧原子或—OR基团（其中R表示氢原子或羟基保护基团），以及至少一种含氟醇和含氟磺酸之一，从而得到下式（2）所表示的化合物的氧化反应方法。
• OXIDATION REACTOR AND PRODUCTION METHOD FOR OXIDE
  申请人：Daicel Corporation

  公开号：EP3187480A1

  公开（公告）日：2017-07-05

  Provided is an oxidation reactor capable of oxidizing hydrocarbons with both good reaction efficiency and good energy efficiency. This oxidation reactor includes a liquid inlet channel, a gas inlet channel, a gas-liquid mixing unit, and a flow reactor. Through the liquid inlet channel, a liquid containing a reaction substrate hydrocarbon is introduced. Through the gas inlet channel, a gas containing oxygen and ozone is introduced. The gas-liquid mixing unit mixes the liquid introduced from the liquid inlet channel with the gas introduced from the gas inlet channel. In the flow reactor, an oxidation catalyst is immobilized or packed. In the oxidation reactor, the flow reactor includes a monolith support and the oxidation catalyst immobilized to or packed in the monolith support. In addition or alternatively, the gas-liquid mixing unit includes a microbubble generator.

  本发明提供了一种能够氧化碳氢化合物的氧化反应器，它具有良好的反应效率和能效。该氧化反应器包括一个液体入口通道、一个气体入口通道、一个气液混合装置和一个流动反应器。通过液体入口通道，引入含有反应底物碳氢化合物的液体。通过气体入口通道，引入含有氧气和臭氧的气体。气液混合装置将从液体入口通道引入的液体与从气体入口通道引入的气体混合。在流动反应器中，固定或装入氧化催化剂。在氧化反应器中，流动反应器包括一个整体支架和固定在整体支架上或装在整体支架上的氧化催化剂。此外，气液混合装置还包括一个微气泡发生器。
• OXIDATION REACTOR AND PROCESS FOR PRODUCING OXIDE
  申请人：Osaka Prefecture University Public Corporation

  公开号：EP3187479A1

  公开（公告）日：2017-07-05

  Provided is an oxidation reactor capable of oxidizing hydrocarbons with both reaction efficiency and energy efficiency. The oxidation reactor according to the present invention includes a liquid inlet channel, a gas inlet channel, a gas-liquid mixing unit, and a flow reactor. Through the liquid inlet channel, a liquid containing a reaction substrate hydrocarbon is introduced. Through the gas inlet channel, a gas containing oxygen and ozone is introduced. The gas-liquid mixing unit mixes the liquid introduced from the liquid inlet channel with the gas introduced from the gas inlet channel. In the flow reactor, an oxidation catalyst is immobilized or packed. The gas-liquid mixing unit houses, in its channel, a mobile particle which is capable of rotating and/or moving to mix the liquid with the gas to thereby form a gas-liquid slug flow. The gas-liquid slug flow is introduced into the flow reactor.

  本发明提供了一种氧化反应器，能够以反应效率和能源效率氧化碳氢化合物。根据本发明，氧化反应器包括一个液体入口通道、一个气体入口通道、一个气液混合装置和一个流动反应器。通过液体入口通道，引入含有反应底物碳氢化合物的液体。通过气体入口通道，引入含有氧气和臭氧的气体。气液混合装置将从液体入口通道引入的液体与从气体入口通道引入的气体混合。在流动反应器中，固定或填充有氧化催化剂。气液混合装置的通道中装有一个移动颗粒，该颗粒能够旋转和/或移动，将液体与气体混合，从而形成气液蛞蝓流。气液蛞蝓流被引入流动反应器。
• PROCESS FOR PRODUCTION OF OXYGEN-CONTAINING ORGANIC COMPOUND
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP2248792B1

  公开（公告）日：2013-11-27