1-Deuteriooxybut-3-enylbenzene | 1269657-76-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Deuteriooxybut-3-enylbenzene
• 英文别名: 1-deuteriooxybut-3-enylbenzene
• CAS: 1269657-76-2
• 化学式: C₁₀H₁₂O
• 分子量: 149.197
• InChiKey: RGKVZBXSJFAZRE-WORMITQPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-苯基-3-丁烯-1-醇乙酸酯 在 molybdenum(VI) oxychloride 、 氘代甲醇 作用下， 反应 147.0h， 以92%的产率得到1-Deuteriooxybut-3-enylbenzene
  参考文献：
  名称：

  Chemoselective deacylation of functionalized esters catalyzed by dioxomolybdenum dichloride

  摘要：

  Among five different oxidometallic species and two Lewis acids investigated, MoO(2)Cl(2) shows the best catalytic and chemoselective activity for the deacylation of esters in methanol at ambient or elevated temperature. Both high efficiency and chemoselectivity were achieved for substrates bearing different ether or ester groups. Acylated mono and disaccharides can also be selectively deacetylated in good yields, leading to useful carbohydrate templates for further synthetic manipulations. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.12.024

文献信息

• Chemoselective deacylation of functionalized esters catalyzed by dioxomolybdenum dichloride
  作者：Cheng-Yuan Liu、Hui-Ling Chen、Chih-Min Ko、Chien-Tien Chen

  DOI：10.1016/j.tet.2010.12.024

  日期：2011.2

  Among five different oxidometallic species and two Lewis acids investigated, MoO(2)Cl(2) shows the best catalytic and chemoselective activity for the deacylation of esters in methanol at ambient or elevated temperature. Both high efficiency and chemoselectivity were achieved for substrates bearing different ether or ester groups. Acylated mono and disaccharides can also be selectively deacetylated in good yields, leading to useful carbohydrate templates for further synthetic manipulations. (C) 2010 Elsevier Ltd. All rights reserved.