2-Diethylaminoethylthionobenzoat | 3817-58-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Diethylaminoethylthionobenzoat
• 英文别名: Diethylaminoethylthionobenzoat；thiobenzoic acid O-(2-diethylamino-ethyl ester)；Thiobenzoesaeure-O-(2-diaethylamino-aethylester)；O-[2-(diethylamino)ethyl] benzenecarbothioate
• CAS: 3817-58-1
• 化学式: C₁₃H₁₉NOS
• 分子量: 237.366
• InChiKey: QXOKGYBQKJIXLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  44.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-Diethylaminoethylthionobenzoat 138.0 ℃ 、266.64 Pa 条件下， 生成 diethylaminoethylthio benzoate
  参考文献：
  名称：

  针对chugaev反应规则的重排和消除

  摘要：

  DOI：

  10.1016/s0040-4039(01)99531-0

文献信息

• TREAD RUBBER COMPOSITION AND PNEUMATIC TIRE
  申请人：Sumitomo Rubber Industries, Ltd.

  公开号：EP2857446A1

  公开（公告）日：2015-04-08

  Provided are a tread rubber composition that can achieve a balanced improvement in fuel economy, wet-grip performance, and abrasion resistance, and a pneumatic tire including the composition. The tread rubber composition includes: a rubber component; silica; and a silane-coupling agent containing a mercapto group, the rubber component including per 100% by mass thereof 5% by mass or more of a conjugated diene polymer (A), the polymer (A) including a monomer unit derived from a conjugated diene, a monomer unit derived from a compound of formula (1), and a monomer unit derived from a compound of formula (2), at least one end of the copolymer (A) being modified by the following compound (G) or an alkoxysilane compound, the composition including 5-150 parts by mass of the silica per 100 parts by mass of the rubber component, Compound (G): at least one compound selected from the group consisting of compounds containing an optionally-substituted amino group and a carbonyl group and compounds containing an optionally-substituted amino group and a thiocarbonyl group,         V1-S1     (1)         V2-A2     (2) wherein V1 and V2 each represent a hydrocarbyl group containing a polymerizable carbon-carbon double bond; S1 represents a substituted silyl group, and A2 represents a substituted amino group or a nitrogen-containing heterocyclic group.

  本文提供了一种可均衡改善燃油经济性、湿抓地性能和耐磨性的胎面橡胶组合物，以及一种包含该组合物的充气轮胎。胎面橡胶组合物包括橡胶成分；白炭黑和含有巯基的硅烷偶联剂，橡胶成分包括每 100% 质量中 5%（质量）或更多的共轭二烯聚合物 (A)，聚合物 (A) 包括衍生自共轭二烯的单体单元、衍生自式 (1) 化合物的单体单元和源自式（2）化合物的单体单元，共聚物（A）的至少一端由下列化合物（G）或烷氧基硅烷化合物改性，该组合物包括每 100 份（质量）橡胶成分中含 5-150 份（质量）二氧化硅的化合物（G）：至少一种选自以下组别的化合物：含有任选取代的氨基和羰基的化合物，以及含有任选取代的氨基和硫代羰基的化合物、 V1-S1 (1) V2-A2 (2) 其中 V1 和 V2 分别代表含有可聚合碳碳双键的烃基，S1 代表取代的硅烷基，A2 代表取代的氨基或含氮杂环基。
• CONJUGATED DIENE-BASED POLYMER, CONJUGATED DIENE-BASED POLYMER COMPOSITION, AND PROCESS FOR PRODUCING CONJUGATED DIENE-BASED POLYMER
  申请人：ITO Mana

  公开号：US20120041134A1

  公开（公告）日：2012-02-16

  Disclosed are a conjugated diene-based polymer from which a polymer composition excellent in fuel cost-saving properties and a tensile strength at break can be obtained. There is provided a conjugated diene-based polymer having a monomer unit based on a conjugated diene, a monomer unit based on a compound represented by the following formula (1), and a monomer unit based on a compound represented by the following formula (2), in which at least one end of the polymer is modified with the following compound (G). V 1 -S 1 (1) wherein V 1 represents a hydrocarbyl group having a polymerizable carbon-carbon double bond, and S 1 represents a substituted silyl group.) V 2 -A 2 (2) wherein V 2 represents a hydrocarbyl group having a polymerizable carbon-carbon double bond, and A 2 represents a substituted amino group, or a nitrogen-containing heterocyclic group. Compound (G): at least one kind of compound selected from the compound group consisting of a compound having an amino group optionally having a substituent and a carbonyl group, and a compound having an amino group optionally having a substituent and a thiocarbonyl group.
• US8334339B2
  申请人：——

  公开号：US8334339B2

  公开（公告）日：2012-12-18
• US9790359B2
  申请人：——

  公开号：US9790359B2

  公开（公告）日：2017-10-17
• Rearrangement and -elimination against the chugaev reaction rule
  作者：T. Taguchi、Y. Kawazoe、K. Yoshihira、H. Kanayama、M. Mori、K. Tabata、K. Harano

  DOI：10.1016/s0040-4039(01)99531-0

  日期：1965.1