(2-Methylphenyl)-di(piperidin-1-yl)phosphane | 289670-88-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-Methylphenyl)-di(piperidin-1-yl)phosphane
• CAS: 289670-88-8
• 化学式: C₁₇H₂₇N₂P
• 分子量: 290.389
• InChiKey: FYVVNTQILFEBQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  palladium diacetate 、 (2-Methylphenyl)-di(piperidin-1-yl)phosphane 以 甲苯 为溶剂， 以90-95的产率得到
  参考文献：
  名称：

  Highly Efficient Phosphapalladacyclic Catalysts for the Hydroarylation of Norbornene

  摘要：

  DOI：

  10.1002/1521-3773(20000602)39:11<1946::aid-anie1946>3.0.co;2-i
• 作为产物：
  描述：

  邻甲苯基溴化镁 以 四氢呋喃 、 甲苯 为溶剂， 反应 2.0h， 生成 (2-Methylphenyl)-di(piperidin-1-yl)phosphane
  参考文献：
  名称：

  Highly Efficient Phosphapalladacyclic Catalysts for the Hydroarylation of Norbornene

  摘要：

  DOI：

  10.1002/1521-3773(20000602)39:11<1946::aid-anie1946>3.0.co;2-i

文献信息

• METHOD FOR PRODUCING NORBORNENE DERIVATIVE
  申请人：Komatsu Shinichi

  公开号：US20100197970A1

  公开（公告）日：2010-08-05

  A method for producing a norbornene derivative wherein, in the presence of palladium and at least one selected from phosphorus compounds represented by the following General Formulae (1) and (2): [in Formula (1), R 1 , R 2 , R 3 and R 4 each independently represent a hydrogen atom or the like, and R 5 and R 6 each independently represent a branched chain saturated hydrocarbon group having 3 to 10 carbon atoms or the like], and [in Formula (2), R 7 represents a branched chain saturated hydrocarbon group having 3 to 10 carbon atoms], a norbornadiene derivative represented by the following General Formula (3): [in Formula (3), R 8 , R 9 , R 10 , R 11 and R 12 each independently represent a hydrogen atom or the like, l represents an integer of 0 or 1, m represents an integer of 0 or 1, and n represents an integer of 0 or 1], and a bromine compound represented by the following General Formula (4): [Chemical Formula 4] Br—Z—R 13 (4) [in Formula (4), Z represents a phenylene group or the like, and R 13 represents a hydrogen atom or the like] are reacted with each other, to thereby obtain a norbornene derivative represented by the following General Formula (5): [in Formula (5), R 14 , R 15 , R 16 , R 17 and R 18 each independently represent a hydrogen atom or the like, Z represents a phenylene group or the like, R 19 represents a hydrogen atom or the like, l represents an integer of 0 or 1, m represents an integer of 0 or 1, and n represents an integer of 0 or 1], the norbornene derivative having a configuration of a substituent represented by Z in General Formula (5) that is an exo configuration.
• US8487136B2
  申请人：——

  公开号：US8487136B2

  公开（公告）日：2013-07-16
• [EN] PHOSPHINE/PALLADIUM COMPLEX CATALYSTS FOR ARYLATION OF OLEFINS<br/>[FR] COMPLEXES DE PHOSPHINE/PALLADIUM CATALYSEURS POUR L'ARYLATION D'OLEFINES
  申请人：CENTRE NAT RECH SCIENT

  公开号：WO2001007449A1

  公开（公告）日：2001-02-01

  La présente invention concerne des phosphines et leur utilisation pour l'élaboration de complexes de palladium, utiles comme catalyseurs d'arylation ou d'hydroarylation d'oléfines. Les phosphines comprennent un atome de phosphore portant un groupe o-tolyle éventuellement substitué, et deux groupes amine secondaire ou tertiaire. Les substituants des amines sont choisis parmi l'hydrogène, un radical alkyle, un radical alcényle ou un radical aryle, au plus l'un des substituants R1 et R2 est un atome d'hydrogène, et au plus l'un des substituants R3 et R4 est un atome d'hydrogène; ou bien les substituants R1 et R2 d'une part, et/ou les substituants R3 et R4 d'autre part forment ensemble un biradical qui forme un hétérocycle avec l'atome d'azote qui les porte, ou bien l'un des substituants R1 ou R2 forme avec les substituants R3 et R4 un radical trivalent qui forme des hétérocycles condensés avec le segment -N-P-N-.
• Highly Efficient Phosphapalladacyclic Catalysts for the Hydroarylation of Norbornene
  作者：Jean Michel Brunel、Andreas Heumann、Gérard Buono

  DOI：10.1002/1521-3773(20000602)39:11<1946::aid-anie1946>3.0.co;2-i

  日期：2000.6.2