Glyoxal-bis-<2-mercapto-anil> | 1723-98-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: Glyoxal-bis-<2-mercapto-anil>
• 英文别名: glyoxal-bis(2-mercaptoanil)；glyoxal bis(mercaptoanil)；Benzenethiol, 2,2'-[1,2-ethanediylidenedinitrilo]bis-；2-[2-(2-sulfanylphenyl)iminoethylideneamino]benzenethiol
• CAS: 1723-98-4
• 化学式: C₁₄H₁₂N₂S₂
• 分子量: 272.395
• InChiKey: KEBPJFJLKWEINY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.7
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [ruthenium(II)(hydride)(chloride)(carbonyl)(triphenylarsine)3] 、 Glyoxal-bis-<2-mercapto-anil> 以 苯 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  含四齿席夫碱的钌(II)羰基配合物及其催化活性

  摘要：

  钌 (II) 配合物 [RuHX(CO) (EPh3)2(B)] [X=H 或 Cl; E=P 或 As；B=PPh3、AsPh3 或吡啶 (Py)] 与通过邻氨基苯酚或邻氨基苯硫酚与乙二醛或苯偶酰缩合衍生的四齿席夫碱配体进行了研究。新配合物已通过分析、IR、电子、1H NMR 光谱研究进行了表征，并被表述为 [Ru(CO)(B)(L)] [L=Schiff 碱阴离子；B=PPh3、AsPh3 或吡啶(Py)]。已经初步提出了新配合物的八面体结构。发现新的配合物是使用 N-甲基吗啉-N-氧化物作为助氧化剂将苯甲醇氧化成苯甲醛的有效催化剂。

  DOI：

  10.1080/15533170600732619
• 作为产物：
  描述：

  草酸醛 、 2-氨基苯硫醇 以 甲醇 为溶剂， 反应 10.0h， 以87%的产率得到Glyoxal-bis-<2-mercapto-anil>
  参考文献：
  名称：

  Pathak, Ashish K.; Ahmad, Nihal; Mittal, Anuj Kumar, Journal of the Indian Chemical Society, 1994, vol. 71, # 5, p. 239 - 244

  摘要：

  DOI：

文献信息

• Zr(IV) complexes of some sulphur donor ligands
  作者：R.K. Sharma、R.V. Singh、J.P. Tandon

  DOI：10.1016/0022-1902(80)80284-3

  日期：1980.1

  reported. These ligands with ÔN̂S and ŜN̂N̂S as the donor systems and represented by SBH2 and S′B′H2 respectively react with zirconiam isopropoxide isopropanolate to give monomeric [Zr(SB)2, Zr(OPrΓ)2(S′B′) and Zr (S′B′)2] and dimeric [Zr(OPri)2(SB)] products. The electronic, IR and proton magnetic resonance spectral studies indicate coordination of oxygen, azomethine nitrogen and sulphur to the zirconium

  已经报道了衍生自水杨醛，2-羟基苯乙酮，2-羟基-1-萘醛，乙二醛或二乙酰基的缩合反应的苯并噻唑啉与2-巯基苯胺和Zr（OPr i）4 ·Pr i OH的反应。这些配体与ONS和SNNS作为供体的系统和通过SBH表示2和S'B'H 2分别与反应zirconiam异丙醇异丙醇，得到单体[锆（SB）2，锆（OPR Γ）2（S'B'）和Zr（S'B'）2 ]和二聚体[Zr（OPr i）2（SB）]产品。电子，红外和质子磁共振光谱研究表明，氧，氮杂亚甲基氮和硫与锆原子配位。
• Transition-Metal Complexes with Sulfur Ligands. 112. Synthesis and Characterization of Ruthenium Complexes with [RuPS2N2] Cores. Substitution, Redox and Acid-Base Reactions of [RuII(L)(PR3)('S2N2H2')], (L = CO, PPr3, R = Pr or Cy) and Five-Coordinate [RuIV(PCy3)('S2N2')]
  作者：Dieter Sellmann、Richard Ruf、Falk Knoch、Matthias Moll

  DOI：10.1021/ic00123a006

  日期：1995.9

  In order to find new ruthenium complexes with [RuPS2N2] frameworks, [Ru(PPr3)(2)('S2N2H2')] (2), ('S2N2H2'(2-) = 1,2-ethanediamine-N,N'-bis(2-benzenethiolate)(2-)), [Ru(CO)(PPr3)('S2N2H2')] (7), [Ru(CO)(PCy(3))('S2N2H2')] (4), [Ru(PCy(3))('S2N2')] (5), ('S2N2'(4-) = 1,2-ethanediamide-N,N'-bis(2-benzenethiolate)(4-)), [Ru(Br)(PPh(3))-('Et(2)S(2)N(2)H(2)')]Br (8), ('Et(2)S(2)N(2)H(2)' = 1,10-diethyl-2,3,8,9-dibenzo-1,10-dithia-4,7-diazadecane) and [Ru(Br)-(PPh(3))('(PhCH(2))(2)S2N2H2)]Br (9) ('(PhCH(2))(2)S2N2H2' = 1,10-dibenzyl-2,3,8,9-dibenzo-1,10-dithia-4,7-diazadecane) were synthesized. The molecular structures of 2, 5 and 9 were elucidated by X-ray structure determination. (2: triclinic space group P $($) over bar$$ 1; a = 11.103(3) Angstrom, b = 11.720(2) Angstrom, c = 13.813(3) Angstrom; alpha = 79.43(2)degrees, beta = 85.73(2)degrees, gamma = 82.91(2)degrees; Z = 2; R/R(w) = 5.1/4.6%. 5: monoclinic space group P2(1)/n; a = 12.019(4) Angstrom, b = 15.132(6) Angstrom, c = 33.566(11) Angstrom; beta = 90.56(3)degrees; Z = 8; R/R(w) = 5.0/4.7%. 9: monoclinic space group Cc; a = 17.839(9) Angstrom, b = 15.846(8) Angstrom, C = 15.706(10) Angstrom; beta = 109.18(5)degrees; Z = 4; R/R(w) = 6.0/6.0%.) 2 and 9 exhibit pseudooctahedral six-coordinate Ru(II) centers. The five-coordinate Ru(IV) center contained in 5 has a distorted coordination polyhedron, which can be described as trigonal bipyramid or tetragonal pyramid. The Ru(IV) oxidation state of 5 is stabilized by strong pi donation of the thiolato and the amido groups. The reversible conversion of the Ru(IV) complex 5 into the Ru(II) complex [Ru(CO)(PCy(3))('S2N2H2)] (4) requires the simultaneous transfer of electrons, protons and CO and can be achieved by reaction with formic acid. In protic solvents, 2 yields the Schiff base complex [Ru(PPr3)(2)(gma)] (10) (gma(2-) = 1,2-diiminoethane-N,N'-bis(2-benzenethiolate)(2-)) upon reaction with CO which functions as proton and electron acceptor. The analogous [Ru(PMe(3))(2)(gma)] (11) is formed by the reaction of the Ru(IV) complex 5 with PMe(3). Mechanisms for the conversions of 2 into 10 and 5 into 11 are discussed.
• Agrawal, Mithlesh; Tandon, J. P.; Mehrotra, R. C., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1980, vol. 10, p. 9 - 28
  作者：Agrawal, Mithlesh、Tandon, J. P.、Mehrotra, R. C.

  DOI：——

  日期：——
• Agrawal, M.; Tandon, J. P.; Mehrotra, R. C., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1980, vol. 10, p. 305 - 318
  作者：Agrawal, M.、Tandon, J. P.、Mehrotra, R. C.

  DOI：——

  日期：——
• Bis(1,8-diazabicyclo[5.4.0]undec-7-en-8-ium)<i>trans</i>-Dichlorotetra(pyridine-<i>N</i>)iron(II) Dichloride
  作者：P. Karsten、J. Strähle

  DOI：10.1107/s0108270198005873

  日期：1998.10.15

  The title compound, (C9H17N2)(2)[FeCl2(C5H5N)(4)]Cl-2, consists of well separated [FeCl2(NC5H5)(4)] complex molecules, 1,8-diazabicyclo[5.4.0]undec-7-en-8-ium (HDBU+) cations and Cl- anions. The Fe atom, located at an inversion center, is octahedrally coordinated, with the two chloro ligands arranged trans. The Fe-Cl distance is 2.4067(8) Angstrom. The N atoms of the four pyridine ligands constitute the equatorial plane, with Fe-N distances in the range 2.273 (3)-2.279 (3) Angstrom.