2,2-di(4-hydroxyphenyl)propane | 32091-42-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-di(4-hydroxyphenyl)propane
• 英文别名: diglycidylether of bisphenol A methacrylate；bisphenol-A methacrylate；bisphenol A di(meth)acrylate；[4-[2-(4-Hydroxyphenyl)propan-2-yl]phenyl] 2-methylprop-2-enoate
• CAS: 32091-42-2
• 化学式: C₁₉H₂₀O₃
• 分子量: 296.366
• InChiKey: KMVCPSSUEJUKSS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  二乙二醇双氯甲酸酯 、 2,2-di(4-hydroxyphenyl)propane 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以93%的产率得到[4-[2-[4-[2-[2-[4-[2-[4-(2-Methylprop-2-enoyloxy)phenyl]propan-2-yl]phenoxy]carbonyloxyethoxy]ethoxycarbonyloxy]phenyl]propan-2-yl]phenyl] 2-methylprop-2-enoate
  参考文献：
  名称：

  Shashkova; Koval'chuk; Zapadinskii, Russian Journal of General Chemistry, 1999, vol. 69, # 2, p. 225 - 234

  摘要：

  DOI：

文献信息

• DENTAL MATERIALS WITH DEBONDING-ON-DEMAND PROPERTIES
  申请人：Ivoclar Vivadent AG

  公开号：US20170156993A1

  公开（公告）日：2017-06-08

  Radically polymerizable dental material, which contains at least one compound of Formula I: and at least one thermolabile radically polymerizable compound and/or at least one photolabile radically polymerizable compound. The materials are characterized by debonding-on-demand properties.

  具有至少一种I式化合物的根本可聚合牙科材料，以及至少一种热敏根本可聚合化合物和/或至少一种光敏根本可聚合化合物。这些材料具有按需脱粘特性。
• Dental Materials on the Basis of Highly Acidic Polymerizable Bisphosphonic Acids
  申请人：IVOCLAR VIVADENT AG

  公开号：US20140296364A1

  公开（公告）日：2014-10-02

  The invention relates to a dental material which comprises a polymerizable bisphosphonic acid of Formula I: The invention also relates to the use of a polymerizable bisphosphonic acid of Formula I for the preparation of a dental material and in particular for the preparation of an adhesive, cement or composite.

  这项发明涉及一种包括化学式I的可聚合双膦酸的牙科材料。该发明还涉及使用化学式I的可聚合双膦酸制备牙科材料，特别是用于制备粘合剂、水泥或复合材料。
• Dental Restorative Materials Based on Polymerizable Azides and Alkynes
  申请人：Ivoclar Vivadent AG

  公开号：US20150164750A1

  公开（公告）日：2015-06-18

  The invention relates to a dental restorative material on the basis of at least one compound of one of the Formulae The invention also relates to the use of the dental restorative materials according to the invention for preparing dental composites, preferably composite blanks, which are suitable in particular for mechanical processing by means of computer-aided processing techniques such as milling and grinding processes, and which are suitable above all for preparing dental restoration materials such as inlays, onlays, crowns, bridges or veneering materials.

  本发明涉及一种牙科修复材料，其基础是至少一种符合以下式之一的化合物。本发明还涉及根据本发明的牙科修复材料用于制备牙科复合材料，优选是适用于通过计算机辅助加工技术（如铣削和研磨过程）进行机械加工的复合坯料，特别适用于制备牙科修复材料，如嵌体、套体、冠、桥梁或贴面材料。
• Polymerizable bicyclic cyclopropane derivatives and their use for the preparation of dental materials
  申请人：——

  公开号：US20040077882A1

  公开（公告）日：2004-04-22

  Bicyclic cyclopropane derivatives of the general Formula (I) 1 in which n+m is 0 to 8; r is 1 to 4; R 1 is absent or is a C 1 -C 20 alkylene radical which can be interrupted by O or S, a cycloaliphatic C 4 -C 12 radical, a bicyclic C 4 -C 12 radical, a C 6 -C 14 arylene or C 7 -C 20 alkylenearylene radical; R 2 is for r=1 a C 1 -C 20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C 4 -C 12 radical, a bicyclic C 4 -C 12 radical, a C 6 -C 14 aryl or a C 7 -C 20 alkylaryl radical; is for r>1 an r-times substituted aliphatic C 1 to C 20 radical which can be interrupted by O or S, a cycloaliphatic C 4 -C 12 radical, an aromatic C 6 -C 14 radical or aliphatic-aromatic C 7 -C 20 radical; X is absent or is —CO—O—, —CO—NH— or —O—CO—NH—, and Y is CH 2 , O or S which is suitable in particular for the preparation of dental materials.

  环丙烷衍生的双环螺烷通式（I）中，其中n+m为0至8；r为1至4；R1不存在或为一个C1-C20烷基基团，其可被O或S中断，为一个环脂肪C4-C12基团，一个双环C4-C12基团，一个C6-C14芳基或C7-C20烷基芳基基团；对于r=1，R2为一个C1-C20烷基基团，其可被O或S中断，为一个环脂肪C4-C12基团，一个双环C4-C12基团，一个C6-C14芳基或一个C7-C20烷基芳基基团；对于r>1，为r次取代的脂肪烷基C1至C20基团，其可被O或S中断，为一个环脂肪C4-C12基团，一个芳香族C6-C14基团或脂肪-芳香族C7-C20基团；X不存在或为—CO—O—，—CO—NH—或—O—CO—NH—，Y为CH2，O或S，特别适用于制备牙科材料。
• DENTAL MATERIALS BASED ON MONOMERS HAVING DEBONDING-ON-DEMAND PROPERTIES
  申请人：Moszner Norbert

  公开号：US20140329929A1

  公开（公告）日：2014-11-06

  The invention relates to a dental restorative material which comprises a thermolabile or photolabile polymerizable compound of Formula I: [(Z 1 ) m -Q 1 -X)] k -T-[Y-Q 2 -(Z 2 ) n ] 1 Formula I, in which T represents a thermolabile or photolabile group, Z 1 and Z 2 in each case independently represent a polymerizable group selected from vinyl groups, CH 2 ═CR 1 —CO—O— and CH 2 ═CR 1 —CO—NR 2 — or an adhesive group selected from —Si(OR) 3 , —COOH, —O—PO(OH) 2 , —PO(OH) 2 , —SO 2 OH and —SH, wherein at least one Z 1 or Z 2 is a polymerizable group, Q 1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C 1 -C 20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR 3 —, —NR 3 —CO—, —O—CO—NR 3 —, —NR 3 —CO—O— or —NR 3 —CO—NR 3 —, Q 2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C 1 -C 20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR 3 —, —NR 3 —CO—, —O—CO—NR 3 —, —NR 3 —CO—O— or —NR 3 —CO—NR 3 —, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR 3 —, —NR 3 —CO—, —O—CO—NR 3 —, —NR 3 —CO—O— or —NR 3 —CO—NR 3 —, R, R 1 , R 2 and R 3 in each case independently represent H or a C 1 -C 7 alkyl radical and k, l, m and n in each case independently are 1, 2 or 3.

  该发明涉及一种牙科修复材料，包括具有以下化学式I的热敏性或光敏性可聚合化合物：[(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]1，在该式中，T代表热敏性或光敏性基团，Z1和Z2分别独立地代表从乙烯基、CH2═CR1—CO—O—和 ═CR1—CO—NR2—中选择的可聚合基团，或从—Si(OR)3、—COOH、—O—PO(OH)2、—PO(OH)2、—SO2OH和—SH中选择的粘附基团，其中至少一个Z1或Z2是可聚合基团，Q1分别独立地缺失或代表一个(m+1)-价的线性或支链脂肪族C1-C20基团，该基团可以通过—O—、—S—、—CO—O—、—O—CO—、—CO—NR3—、—NR3—CO—、—O—CO—NR3—、—NR3—CO—O—或—NR3—CO—NR3—中断，Q2分别独立地缺失或代表一个(n+1)-价的线性或支链脂肪族C1-C20基团，该基团可以通过—O—、—S—、—CO—O—、—O—CO—、—CO—NR3—、—NR3—CO—、—O—CO—NR3—、—NR3—CO—O—或—NR3—CO—NR3—中断，X和Y分别独立地缺失或代表—O—、—S—、CO—O—、—O—CO—、—CO—NR3—、—NR3—CO—、—O—CO—NR3—、—NR3—CO—O—或—NR3—CO—NR3—，R、R1、R2和R3分别独立地代表H或C1-C7烷基基团，k、l、m和n分别独立地为1、2或3。