1-[Butyl-(dibutylphosphinothioylamino)phosphinothioyl]butane | 227181-44-4

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 英文名称: 1-[Butyl-(dibutylphosphinothioylamino)phosphinothioyl]butane
• CAS: 227181-44-4
• 化学式: C₁₆H₃₇NP₂S₂
• 分子量: 369.556
• InChiKey: NAZDPWLTQKLKCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  21
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  76.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  [PdCl2(COD)] 、 1-[Butyl-(dibutylphosphinothioylamino)phosphinothioyl]butane 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 生成 dibutyl-dibutylphosphinothioylimino-sulfido-λ5-phosphane;palladium(2+)
  参考文献：
  名称：

  Synthesis and coordination chemistry of tetrabutyldithioimidodiphosphinates

  摘要：

  Butyl substituted imidodithiophosphinates R2P(S)NP(S)R'(2) (R=Bu-n,Bu-t, Bu-s; R'=Bu-n,Bu-i,Bu-s) have been synthesised via an HBr elimination reaction between R2P(S)NH, and R'P-2(S)Br. The compounds were characterised spectroscopically. Crystallographic and spectroscopic studies reveal (Bu2P)-Bu-n(S)NHP(S)Bu-n(2) and (Bu2P)-Bu-s(S)NHP(S)Bu-1(2) to be hydrogen bonded transoid dimers and (Bu2P)-Bu-1(S)NHP(S)Bu-1(2) to be a transoid hydrogen bonded chain. Reactions of the imidodithiophosphinates with ZnCl2 or MCl2COD gave the coordination complexes M[R2P(S)NP(S)R'(2)], (R=Bu-n,Bu-i, Bu-s; R'=Bu-n,Bu-i, Bu-s; M=Zn, Pd: R=Bu-n,Bu-i,Bu-s, Pt). (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00343-x

文献信息

• LUBRICATING COMPOSITION WITH SUPERIOR ANTI-WEAR PROPERTIES
  申请人：Shell Internationale Research Maatschappij B.V.

  公开号：EP2382289B1

  公开（公告）日：2016-10-26
• ANTI-WEAR AGENT AND LUBRICATING COMPOSITION WITH SUPERIOR ANTI-WEAR PROPERTIES CONTAINING SAME
  申请人：Nagatomi Eiji

  公开号：US20110294709A1

  公开（公告）日：2011-12-01

  The present invention provides an anti-wear compound selected from phosphorus compounds as represented by the following General Formula (2) or metal salts thereof as represented by the following General Formula (3).
• US8658577B2
  申请人：——

  公开号：US8658577B2

  公开（公告）日：2014-02-25
• [EN] ANTI-WEAR AGENT AND LUBRICATING COMPOSITION WITH SUPERIOR ANTI-WEAR PROPERTIES CONTAINING SAME<br/>[FR] AGENT ANTI-USURE ET COMPOSITION LUBRIFIANTE AYANT DES PROPRIÉTÉS ANTI-USURE SUPÉRIEURES LE CONTENANT
  申请人：SHELL INT RESEARCH

  公开号：WO2010086357A1

  公开（公告）日：2010-08-05

  The present invention provides an anti-wear compound selected from phosphorus compounds as represented by the following General Formula (2) or metal salts thereof as represented by the following General Formula (3).
• Synthesis and coordination chemistry of tetrabutyldithioimidodiphosphinates
  作者：Domineco C. Cupertino、Robin W. Keyte、Alexandra M.Z. Slawin、J.Derek Woollins

  DOI：10.1016/s0277-5387(98)00343-x

  日期：1999.1

  Butyl substituted imidodithiophosphinates R2P(S)NP(S)R'(2) (R=Bu-n,Bu-t, Bu-s; R'=Bu-n,Bu-i,Bu-s) have been synthesised via an HBr elimination reaction between R2P(S)NH, and R'P-2(S)Br. The compounds were characterised spectroscopically. Crystallographic and spectroscopic studies reveal (Bu2P)-Bu-n(S)NHP(S)Bu-n(2) and (Bu2P)-Bu-s(S)NHP(S)Bu-1(2) to be hydrogen bonded transoid dimers and (Bu2P)-Bu-1(S)NHP(S)Bu-1(2) to be a transoid hydrogen bonded chain. Reactions of the imidodithiophosphinates with ZnCl2 or MCl2COD gave the coordination complexes M[R2P(S)NP(S)R'(2)], (R=Bu-n,Bu-i, Bu-s; R'=Bu-n,Bu-i, Bu-s; M=Zn, Pd: R=Bu-n,Bu-i,Bu-s, Pt). (C) 1999 Elsevier Science Ltd. All rights reserved.